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1159-54-2,MFCD00013639
Catalog No.:AA000H0G

1159-54-2 | Tris(4-chlorophenyl)phosphine

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1g
97%
in stock  
$8.00   $6.00
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5g
97%
in stock  
$11.00   $8.00
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10g
97%
in stock  
$13.00   $9.00
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100g
97%
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$120.00   $84.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA000H0G
Chemical Name:
Tris(4-chlorophenyl)phosphine
CAS Number:
1159-54-2
Molecular Formula:
C18H12Cl3P
Molecular Weight:
365.6206
MDL Number:
MFCD00013639
SMILES:
Clc1ccc(cc1)P(c1ccc(cc1)Cl)c1ccc(cc1)Cl
NSC Number:
136459
Properties
Properties
 
BP:
427.6°C at 760 mmHg  
Form:
Solid  
MP:
100-103 °C(lit.);  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
275  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
22  
Rotatable Bond Count:
3  
XLogP3:
6.5  

Upstream Synthesis Route

[1]Patent:WO2011/123037,2011,A1,.Locationinpatent:Page/Pagecolumn23-24

[2]JournalofOrganicChemistry,2008,vol.73,#4,p.1524-1531

[3]ChineseChemicalLetters,2014,vol.25,#1,p.176-178

[4]RussianJournalofGeneralChemistry,2015,vol.85,#5,p.1156-1160

[5]Zh.Obshch.Khim.,

[1]AdvancedSynthesisandCatalysis,2015,vol.357,#18,p.4069-4081

[2]Chemistry-AEuropeanJournal,2013,vol.19,#30,p.10024-10029

[3]CanadianJournalofChemistry,1982,vol.60,p.716-722

[4]Macromolecules,2012,vol.45,#7,p.2981-2988

[1]Synlett,2006,#6,p.954-956

[1]Polyhedron,

[2]Polyhedron,1989,vol.8,p.167-174

[1]Polyhedron,

[2]Polyhedron,1989,vol.8,p.167-174

Downstream Synthesis Route

[1]JournalofOrganicChemistry,1983,vol.48,p.1760-1762

[2]Chemistry-AEuropeanJournal,2013,vol.19,p.10024-10029

[3]RSCAdvances,2019,vol.9,p.1509-1516

[4]TetrahedronLetters,2018,vol.59,p.3880-3883

[5]RSCAdvances,2017,vol.7,p.13240-13243

[6]JournalofOrganicChemistry,2008,vol.73,p.1524-1531

[7]JournalofOrganometallicChemistry,2020,vol.914

[8]JournaloftheAmericanChemicalSociety,1995,vol.117,p.272-280

[9]JournaloftheChemicalSociety,1945,p.151

[10]JournaloftheAmericanChemicalSociety,1967,vol.89,p.5235-5246

[11]JournalofOrganicChemistry,1991,vol.56,p.2762-2769

[12]RussianJournalofGeneralChemistry,2001,vol.71,p.888-892

[13]JournalofOrganicChemistry,2005,vol.70,p.1276-1280

[14]JournaloftheAmericanChemicalSociety,2005,vol.127,p.3413-3422

[15]Tetrahedron,2006,vol.62,p.10729-10733

[16]Tetrahedron,2006,vol.62,p.10729-10733

[17]OrganicandBiomolecularChemistry,2006,vol.4,p.2969-2973

[18]ChemischeBerichte,1967,vol.100,p.1144-1164

[19]InorganicChemistry,2013,vol.52,p.5418-5427

[20]JournalofOrganicChemistry,2013,vol.78,p.8098-8104

[21]Chemistry-AEuropeanJournal,2014,vol.20,p.12421-12425

[22]InorganicChemistry,2016,vol.55,p.8646-8660

[23]ChemicalCommunications,2017,vol.53,p.9352-9355

[24]Chemistry-AEuropeanJournal,2018,vol.24,p.18618-18622

[1]AdvancedSynthesisandCatalysis,2015,vol.357,p.4069-4081

[2]Chemistry-AEuropeanJournal,2013,vol.19,p.10024-10029

[3]CanadianJournalofChemistry,1982,vol.60,p.716-722

[4]Macromolecules,2012,vol.45,p.2981-2988

[1]Synthesis,1984,p.754-757

591-50-4    1159-54-2   
Tris-(4-chloro-phenyl)-phenyl-phosphonium;iodide 

[1]BulletinoftheChemicalSocietyofJapan,1983,vol.56,p.2869-2870

696-62-8    1159-54-2   
Tris-(4-chloro-phenyl)-(4-methoxy-phenyl)-phosphonium;iodide 

[1]BulletinoftheChemicalSocietyofJapan,1983,vol.56,p.2869-2870

Literature

Title: cis-Dichloridobis[tris-(4-chloro-phen-yl)phosphane-κP]platinum(II) acetonitrile monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20120901

Title: Bis{[μ-bis-(diphenyl-arsino)methane-1:2κAs:As']nona-carbonyl-1κC,2κC,3κC-[tris-(4-chloro-phen-yl)phosphine-3κP]-triangulo-triruthenium(0)} chloro-form monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20100101

Title: Synthesis of stable C-phosphonate analogues of Neisseria meningitidis group A capsular polysaccharide structures using modified Mitsunobu reaction conditions.

Journal: Organic & biomolecular chemistry 20061221

Title: Palladium-catalyzed synthesis of 1-alkylphosphonium salts from 1-alkenes.

Journal: Journal of the American Chemical Society 20060111

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SDS
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