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12279-09-3,MFCD00013287
Catalog No.:AA000JEC

12279-09-3 | Chlorobis(cyclooctene)rhodium(i) dimer

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Purity
Availability
Price(USD)
Quantity
  
100mg
>96.0%(T)
in stock  
$128.00   $90.00
- +
500mg
98%
in stock  
$377.00   $264.00
- +
1g
98%
in stock  
$632.00   $443.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA000JEC
Chemical Name:
Chlorobis(cyclooctene)rhodium(i) dimer
CAS Number:
12279-09-3
Molecular Formula:
C32H56Cl2Rh2
Molecular Weight:
717.5040
MDL Number:
MFCD00013287
SMILES:
C1CCCC[CH]2=[CH](C1)[Rh+]132([Cl-][Rh+]24([Cl-]1)([CH]1=[CH]4CCCCCC1)[CH]1=[CH]2CCCCCC1)[CH]1=[CH]3CCCCCC1
Properties
Properties
 
Form:
Solid  
MP:
190 °C (dec.)(lit.)  
Stability:
air sensitive, store cold  
Storage:
Inert atmosphere;-20 ℃;  

Computed Properties
 
Complexity:
62.1  
Covalently-Bonded Unit Count:
8  
Defined Bond Stereocenter Count:
4  
Formal Charge:
-2  
Heavy Atom Count:
36  
Hydrogen Bond Acceptor Count:
2  

Downstream Synthesis Route
12279-09-3    108-88-3   
N-2,6-bis(propan-2-yl)phenyl-1-2-(diphenylphosphanyl)phenylmethanimine 
 
Rh(κ2-o-Ph2PC6H4CH=N-2,6-(i-Pr)2C6H3)(μ-Cl)2*2MePh 

[1]InorganicaChimicaActa,2006,vol.359,p.2771-2779

[1]JournaloftheAmericanChemicalSociety,2006,vol.128,p.2452-2462

102308-67-8    12279-09-3    2622-14-2    880267-10-7   
trans-(3-methyl-1,2,3,4-tetrahydroquinazolin-2-ylidene)(PCy3)2RhCl 

[1]JournaloftheAmericanChemicalSociety,2006,vol.128,p.2452-2462

102308-67-8    12279-09-3    2622-14-2   
trans-(3-methyl-1,2,3,4-tetrahydroquinazolin-2-ylidene)(PCy3)2RhCl 

[1]JournaloftheAmericanChemicalSociety,2006,vol.128,p.2452-2462

880267-14-1    880267-12-9    12279-09-3    2622-14-2   
trans-(3-methyl-1,2,3,4-tetrahydroquinazolin-2-ylidene)(PCy3)2RhCl 
 
trans-(3-methyl-1,2,3,4-tetrahydro-1H,2-(2)H-quinazolin-2-ylidene)(PCy3)2RhCl 
 
trans-(3-methyl-1,2,3,4-tetrahydro-1-(15)ND-quinazolin-2-ylidene)(PCy3)2RhCl 
 
trans-(3-methyl-1,2,3,4-tetrahydro-1-(15)NH-quinazolin-2-ylidene)(PCy3)2RhCl 

[1]JournaloftheAmericanChemicalSociety,2006,vol.128,p.2452-2462

Literature
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Tags:12279-09-3 Molecular Formula|12279-09-3 MDL|12279-09-3 SMILES|12279-09-3 Chlorobis(cyclooctene)rhodium(i) dimer