Home Fluorides 13081-18-0
13081-18-0,MFCD00114935
Catalog No.:AA0034U8

13081-18-0 | Ethyl trifluoropyruvate

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5g
98%
in stock  
$6.00   $4.00
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10g
98%
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$7.00   $5.00
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25g
98%
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$16.00   $11.00
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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0034U8
Chemical Name:
Ethyl trifluoropyruvate
CAS Number:
13081-18-0
Molecular Formula:
C5H5F3O3
Molecular Weight:
170.0866
MDL Number:
MFCD00114935
SMILES:
CCOC(=O)C(=O)C(F)(F)F
Properties
Properties
 
BP:
58.5°C at 760 mmHg  
Form:
Liquid  
Refractive Index:
n20/D 1.341(lit.)  
Solubility:
Miscible with dichloromethane.  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
172  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
11  
Hydrogen Bond Acceptor Count:
6  
Rotatable Bond Count:
3  
XLogP3:
1.5  

Literature

Title: Asymmetric synthesis of the carbon-14-labeled selective glucocorticoid receptor modulator using cinchona alkaloid catalyzed addition of 6-bromoindole to ethyl trifluoropyruvate.

Journal: Molecules (Basel, Switzerland) 20120530

Title: Ethyl 3,3,3-trifluoro-2-hy-droxy-2-(5-meth-oxy-1H-indol-3-yl)propionate.

Journal: Acta crystallographica. Section E, Structure reports online 20110701

Title: Straightforward synthesis of enantiopure (R)- and (S)-trifluoroalaninol.

Journal: Organic & biomolecular chemistry 20101021

Title: Joint experimental and DFT study of the gas-phase unimolecular elimination kinetic of methyl trifluoropyruvate.

Journal: The journal of physical chemistry. A 20100805

Title: Catalytic asymmetric synthesis of 3-(alpha-hydroxy-beta-carbonyl) oxindoles by a Sc(III)-catalyzed direct aldol-type reaction.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100322

Title: The first organocatalytic carbonyl-ene reaction: isomerisation-free C-C bond formations catalysed by H-bonding thio-ureas.

Journal: Beilstein journal of organic chemistry 20070101

Title: Cinchona-alkaloid-catalyzed enantioselective direct aldol-type reaction of oxindoles with ethyl trifluoropyruvate.

Journal: Angewandte Chemie (International ed. in English) 20070101

Title: Asymmetric platinum group metal-catalyzed carbonyl-ene reactions: carbon-carbon bond formation versus isomerization.

Journal: The Journal of organic chemistry 20061222

Title: Straightforward synthesis of (S)- and (R)-alpha-trifluoromethyl proline from chiral oxazolidines derived from ethyl trifluoropyruvate.

Journal: Organic letters 20061221

Title: Highly enantioselective organocatalytic hydroxyalkylation of indoles with ethyl trifluoropyruvate.

Journal: Angewandte Chemie (International ed. in English) 20050513

Title: Regioselectively nucleus and/or side-chain fluorinated 2-(Phenanthryl)propionic acids by an effective combination of radical and organometallic chemistry.

Journal: The Journal of organic chemistry 20050121

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Tags:13081-18-0 Molecular Formula|13081-18-0 MDL|13081-18-0 SMILES|13081-18-0 Ethyl trifluoropyruvate |Fluorinated_Building_Blocks