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140681-55-6,MFCD00142607
Catalog No.:AA001CLE

140681-55-6 | 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)

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250mg
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500mg
98%
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$9.00   $6.00
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1g
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$12.00   $8.00
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5g
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$15.00   $10.00
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25g
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250g
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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA001CLE
Chemical Name:
1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)
CAS Number:
140681-55-6
Molecular Formula:
C7H14B2ClF9N2++++
Molecular Weight:
354.2601
MDL Number:
MFCD00142607
SMILES:
F[B+](F)(F)F.F[B+](F)(F)F.ClC[N+]12CC[N+](CC1)(CC2)F
Properties
Properties
 
Form:
Solid  
MP:
260 °C  
Stability:
Moisture Sensitive  
Storage:
2-8℃;  

Computed Properties
 
Complexity:
168  
Covalently-Bonded Unit Count:
3  
Heavy Atom Count:
21  
Hydrogen Bond Acceptor Count:
11  
Rotatable Bond Count:
1  

Literature

Title: Gold-catalyzed simultaneous formation of C-C, C═O, and C-F bonds in the presence of Selectfluor: a synthesis of fluoroindenes from allene esters.

Journal: The Journal of organic chemistry 20120615

Title: Radiosynthesis and evaluation of [18F]Selectfluor bis(triflate).

Journal: Angewandte Chemie (International ed. in English) 20100910

Title: Study on the selectivity in the electrophilic monofluorination of 2,3-allenoates with Selectfluor: an efficient synthesis of 4-fluoro-2(5H)-furanones and 3-fluoro-4-oxo-2(E)-alkenoates.

Journal: Organic & biomolecular chemistry 20100107

Title: Transformations of organic molecules with F-TEDA-BF4 in ionic liquid media.

Journal: Molecules (Basel, Switzerland) 20090706

Title: An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with Selectfluor.

Journal: Organic letters 20080221

Title: Enantioselective alpha-fluorination of carbonyl compounds: organocatalysis or metal catalysis?

Journal: Angewandte Chemie (International ed. in English) 20060116

Title: Quinine/selectfluor combination induced asymmetric semipinacol rearrangement of allylic alcohols: an effective and enantioselective approach to alpha-quaternary beta-fluoro aldehydes.

Journal: Chemical communications (Cambridge, England) 20051128

Title: gem-Difluorination of 2,2-diaryl-1,3-dithiolanes by Selectfluor and pyridinium polyhydrogen fluoride.

Journal: Chemical communications (Cambridge, England) 20050207

Title: Recent highlights in electrophilic fluorination with 1-chloromethyl-4-fluoro- 1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate).

Journal: Accounts of chemical research 20040101

Title: The synthesis and characterization of BMS-204352 (MaxiPost) and related 3-fluorooxindoles as openers of maxi-K potassium channels.

Journal: Bioorganic & medicinal chemistry letters 20020408

Title: Selectfluor F-TEDA-BF4 mediated and solvent directed iodination of aryl alkyl ketones using elemental iodine.

Journal: Chemical communications (Cambridge, England) 20020307

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Tags:140681-55-6 Molecular Formula|140681-55-6 MDL|140681-55-6 SMILES|140681-55-6 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) |Fluorinated_Building_Blocks