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14694-95-2,MFCD00010016
Catalog No.:AA001EE9

14694-95-2 | Tris(triphenylphosphine)rhodium(I) chloride

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Purity
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Price(USD)
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100mg
98%
in stock  
$17.00   $12.00
- +
250mg
98%
in stock  
$28.00   $20.00
- +
1g
98%
in stock  
$91.00   $64.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA001EE9
Chemical Name:
Tris(triphenylphosphine)rhodium(I) chloride
CAS Number:
14694-95-2
Molecular Formula:
C54H45ClP3Rh
Molecular Weight:
925.2149
MDL Number:
MFCD00010016
SMILES:
c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Rh]Cl
Properties
Properties
 
BP:
>170°C  
Form:
Solid  
MP:
245-250 °C (dec.)  
Solubility:
Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution  
Stability:
air sensitive  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
202  
Covalently-Bonded Unit Count:
5  
Formal Charge:
-1  
Heavy Atom Count:
59  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
9  

Upstream Synthesis Route

[1]CatalysisToday,2013,vol.200,#1,p.54-62

[1]Patent:JP2015/120642,2015,A,.Locationinpatent:Paragraph0186

[2]AppliedCatalysisA:General,2013,vol.457,p.62-68

[3]AppliedCatalysisA:General,2013,vol.457,p.62-68

[1]OrganicLetters,2017,vol.19,#17,p.4628-4631

[2]CatalysisToday,2013,vol.200,#1,p.54-62

[3]NewJournalofChemistry,2015,vol.39,#3,p.1583-1586

[4]Patent:CN105669769,2016,A,.Locationinpatent:Paragraph0017

[1]InorganicChemistry,1993,vol.32,p.1866-1867

[1]JournalofOrganometallicChemistry,1989,vol.359,p.C22-C26

[2]JournaloftheAmericanChemicalSociety,1992,vol.114,#24,p.9350-9359

Downstream Synthesis Route

[1]Andrews,MarkA.[Organometallics,1989,vol.8,#11,p.2703-2708]

[1]Organometallics,1989,vol.8,p.2703-2708

[2]Organometallics,1989,vol.8,p.2703-2708

[3]Organometallics,1989,vol.8,p.2703-2708

[4]Organometallics,1989,vol.8,p.2703-2708

[5]Organometallics,1989,vol.8,p.2703-2708

[6]Organometallics,1989,vol.8,p.2703-2708

[7]Organometallics,1989,vol.8,p.2703-2708

[8]Organometallics,1989,vol.8,p.2703-2708

[9]Organometallics,1989,vol.8,p.2703-2708

[10]Organometallics,1989,vol.8,p.2703-2708

[11]Organometallics,1989,vol.8,p.2703-2708

[1]JournaloftheAmericanChemicalSociety,1966,vol.88,p.4537-4538

[2]GmelinHandbuchderAnorganischenChemie,GmelinHandbook:Rh:SVol.B3,4.24.3.1,page131-132

[1]JournaloftheAmericanChemicalSociety,1981,vol.103,p.1478-1485

[1]JournaloftheAmericanChemicalSociety,1981,vol.103,p.1478-1485

[2]JournaloftheAmericanChemicalSociety,1981,vol.103,p.1478-1485

[3]JournaloftheAmericanChemicalSociety,1981,vol.103,p.1478-1485

[4]JournaloftheAmericanChemicalSociety,1981,vol.103,p.1478-1485

[5]JournaloftheAmericanChemicalSociety,1981,vol.103,p.1478-1485

Literature
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SDS
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