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15206-55-0,MFCD00008443
Catalog No.:AA003RWO

15206-55-0 | Methyl benzoylformate

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10g
97%
in stock  
$6.00   $4.00
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25g
97%
in stock  
$13.00   $9.00
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100g
97%
in stock  
$46.00   $32.00
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500g
97%
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$56.00   $39.00
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  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA003RWO
Chemical Name:
Methyl benzoylformate
CAS Number:
15206-55-0
Molecular Formula:
C9H8O3
Molecular Weight:
164.1580
MDL Number:
MFCD00008443
SMILES:
COC(=O)C(=O)c1ccccc1
Properties
Properties
 
BP:
247°C at 760 mmHg  
Form:
Liquid  
MP:
16 °C  
Refractive Index:
n20/D 1.528  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
180  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
12  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
3  
XLogP3:
1.7  

Literature

Title: The first case of competitive heterogeneously catalyzed enantioselective hydrogenation of ketones.

Journal: Chemical communications (Cambridge, England) 20110207

Title: Integration of newly isolated biocatalyst and resin-based in situ product removal technique for the asymmetric synthesis of (R)-methyl mandelate.

Journal: Bioprocess and biosystems engineering 20100901

Title: Mechanistic insights on the magnesium(II) ion-activated reduction of methyl benzoylformate with chelated NADH peptide beta-lactam models.

Journal: The Journal of organic chemistry 20090904

Title: [Overview of 40 years' chemical study].

Journal: Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20090101

Title: Exploiting nanospace for asymmetric catalysis: confinement of immobilized, single-site chiral catalysts enhances enantioselectivity.

Journal: Accounts of chemical research 20080601

Title: N-methyl-(R)-3-(tert-butyl)-sulfinyl-1,4-dihydropyridine: a novel NADH model compound.

Journal: Molecules (Basel, Switzerland) 20070312

Title: Unusual temperature dependence of enantioselectivity in asymmetric reductions by chiral NADH models.

Journal: Organic letters 20060511

Title: Amine degradation by 4,5-epoxy-2-decenal in model systems.

Journal: Journal of agricultural and food chemistry 20060322

Title: Synthesis, properties, and oxidizing ability of areno-annulated 1,3-dimethyl-10-phenylcyclohepta[4,5]pyrrolo[2,3-d]pyrimidine- 2,4(1,3H)-dionylium ions.

Journal: The Journal of organic chemistry 20060106

Title: Ru-Catalyzed asymmetric hydrogenation of alpha-ketoesters with CeCl3.7H2O as additive.

Journal: Organic letters 20051124

Title: Stereoselective generation of vicinal stereogenic quaternary centers by photocycloaddition of 5-methoxy oxazoles to alpha-keto esters: synthesis of erythro beta-hydroxy dimethyl aspartates.

Journal: Organic & biomolecular chemistry 20040421

Title: Constraining asymmetric organometallic catalysts within mesoporous supports boosts their enantioselectivity.

Journal: Journal of the American Chemical Society 20031210

Title: Atropoisomeric quinolinium salt promoting the access to both enantiomeric forms of methyl mandelate: a versatile NADH mimic.

Journal: Chemical communications (Cambridge, England) 20021007

Title: The [2+2]-photocycloaddition of aromatic aldehydes and ketones to 3,4-dihydro-2-pyridones: regioselectivity, diastereoselectivity, and reductive ring opening of the product oxetanes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20011015

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