Home Other Building Blocks 15596-07-3
15596-07-3,MFCD00040613
Catalog No.:AA001OB6

15596-07-3 | Ethenone, 2-(triphenylphosphoranylidene)-

Pack Size
Purity
Availability
Price(USD)
Quantity
  
250mg
≥95%
in stock  
$113.00   $79.00
- +
1g
in stock  
$132.00   $92.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA001OB6
Chemical Name:
Ethenone, 2-(triphenylphosphoranylidene)-
CAS Number:
15596-07-3
Molecular Formula:
C20H15OP
Molecular Weight:
302.3063
MDL Number:
MFCD00040613
SMILES:
O=C=C=P(c1ccccc1)(c1ccccc1)c1ccccc1
NSC Number:
620573
Properties
Properties
 
Form:
Solid  
MP:
167-173℃  

Computed Properties
 
Complexity:
400  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
22  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
3  
XLogP3:
4.5  

Downstream Synthesis Route
15596-07-3    3619-17-8   
2-Isopropyl-5-methyl-1,3,4oxadiazole 

[1]Löffler,Jonas;Schobert,Rainer[Synlett,1997,vol.1997,#3,p.283-284]

[1]Locationinpatent:experimentalpartMarcos;Benéitez;Moro;Basabe;Díez;Urones[Tetrahedron,2010,vol.66,#45,p.8605-8614]

[2]CurrentPatentAssignee:ACADEMIASINICA-US2015/309041,2015,A1

[3]CurrentPatentAssignee:ACADEMIASINICA-WO2015/148915,2015,A1Locationinpatent:Paragraph00206;00207

[4]Shie,Jiun-Jie;Liu,Ying-Chih;Hsiao,Jye-Chian;Fang,Jim-Min;Wong,Chi-Huey[ChemicalCommunications,2017,vol.53,#9,p.1490-1493]

[1]Harras,Marina;Bauer,Tobias;Kempe,Rhett;Schobert,Rainer[Tetrahedron,2013,vol.69,#18,p.3677-3682]

[1]Harras,Marina;Bauer,Tobias;Kempe,Rhett;Schobert,Rainer[Tetrahedron,2013,vol.69,#18,p.3677-3682]

492-73-9    15596-07-3   
2-(pyridine-2-carbonyl)-2-(2-pyridyl)-4-(triphenyl-λ5-phosphanylidene)cyclobutane-1,3-dione 

[1]El-Hussieny;Abd-El-Maksoud;Maigali;Soliman;Soliman[Phosphorus,SulfurandSiliconandtheRelatedElements,2015,vol.190,#11,p.1845-1856]

Literature

Title: Anhydrous TEMPO-H: reactions of a good hydrogen atom donor with low-valent carbon centres.

Journal: Organic & biomolecular chemistry 20110521

Title: Tetramic and tetronic acids as scaffolds in bioinorganic and bioorganic chemistry.

Journal: Bioinorganic chemistry and applications 20100101

Title: Facile preparation and functionalization of chiral stabilized ylides from common chiral auxiliaries using triphenyl- phosphoranylideneketene (the Bestmann ylide) and their use in Wittig reactions.

Journal: The Journal of organic chemistry 20061110

Title: Cascade synthesis with (triphenylphosphoranylidene)-ethenone as a versatile reagent for fast synthesis of heterocycles and unsaturated amides under microwave dielectric heating.

Journal: Combinatorial chemistry & high throughput screening 20021101

Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Related Products of 15596-07-3
Tags:15596-07-3 Molecular Formula|15596-07-3 MDL|15596-07-3 SMILES|15596-07-3 Ethenone, 2-(triphenylphosphoranylidene)-