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16858-01-8,MFCD14708176
Catalog No.:AA001Y2P

16858-01-8 | Tris(2-pyridylmethyl)amine

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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA001Y2P
Chemical Name:
Tris(2-pyridylmethyl)amine
CAS Number:
16858-01-8
Molecular Formula:
C18H18N4
Molecular Weight:
290.3623
MDL Number:
MFCD14708176
SMILES:
c1ccc(nc1)CN(Cc1ccccn1)Cc1ccccn1
NSC Number:
663674
Properties
Properties
 
Form:
Solid  
MP:
85-89℃  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
262  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
22  
Hydrogen Bond Acceptor Count:
4  
Rotatable Bond Count:
6  
XLogP3:
1.6  

Literature

Title: Kinetic and mechanistic aspects of atom transfer radical addition (ATRA) catalyzed by copper complexes with tris(2-pyridylmethyl)amine.

Journal: Inorganic chemistry 20121105

Title: Characterization of cobalt(III) hydroxamic acid complexes based on a tris(2-pyridylmethyl)amine scaffold: reactivity toward cysteine methyl ester.

Journal: Inorganic chemistry 20120903

Title: Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex.

Journal: Physical chemistry chemical physics : PCCP 20120721

Title: Capped-tetrahedrally coordinated Fe(II) and Co(II) complexes using a 'Click'-derived tripodal ligand: geometric and electronic structures.

Journal: Inorganic chemistry 20120716

Title: Synthesis, spectroscopic analysis and photolabilization of water-soluble ruthenium(III)-nitrosyl complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20120714

Title: Nonprecious metal catalysts for fuel cell applications: electrochemical dioxygen activation by a series of first row transition metal tris(2-pyridylmethyl)amine complexes.

Journal: Inorganic chemistry 20120416

Title: KLF10, transforming growth factor-β-inducible early gene 1, acts as a tumor suppressor.

Journal: Biochemical and biophysical research communications 20120309

Title: Evaluating the identity and diiron core transformations of a (μ-oxo)diiron(III) complex supported by electron-rich tris(pyridyl-2-methyl)amine ligands.

Journal: Inorganic chemistry 20120220

Title: 100 picosecond diffraction catches structural transients of laser-pulse triggered switching in a spin-crossover crystal.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120213

Title: Discrete complexes immobilized onto click-SBA-15 silica: controllable loadings and the impact of surface coverage on catalysis.

Journal: Journal of the American Chemical Society 20120208

Title: Transient infrared spectroscopy: a new approach to investigate valence tautomerism.

Journal: Physical chemistry chemical physics : PCCP 20120114

Title: Effect of berberine on p53 expression by TPA in breast cancer cells.

Journal: Oncology reports 20120101

Title: π Back-bonding of iron(II) complexes supported by tris(pyrid-2-ylmethyl)amine and its nitro-substituted derivatives.

Journal: The journal of physical chemistry. A 20111124

Title: Water oxidation by mononuclear ruthenium complexes with TPA-based ligands.

Journal: Inorganic chemistry 20111107

Title: Reactivity of copper(II)-alkylperoxo complexes.

Journal: Dalton transactions (Cambridge, England : 2003) 20111028

Title: Nickel(II) complexes of tripodal 4N ligands as catalysts for alkane oxidation using m-CPBA as oxidant: ligand stereoelectronic effects on catalysis.

Journal: Dalton transactions (Cambridge, England : 2003) 20111007

Title: Galvanic zinc-copper microparticles produce electrical stimulation that reduces the inflammatory and immune responses in skin.

Journal: Archives of dermatological research 20111001

Title: Synthesis and properties of oxo-carboxylato- and dioxo-bridged diosmium complexes of tris(2-pyridylmethyl)amine.

Journal: Inorganic chemistry 20110919

Title: Theoretical study of oxidation of cyclohexane diol to adipic anhydride by [Ru(IV)(O)(tpa)(H2O)]2+ complex (tpa ═ tris(2-pyridylmethyl)amine).

Journal: Inorganic chemistry 20110704

Title: (Naphthalene-2,3-diolato-κO,O')[tris-(2-pyridyl-meth-yl)amine-κN]cobalt(III) hexa-fluoridophosphate hemihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20110701

Title: Syntheses, emission properties and intramolecular ligand exchange of zinc complexes with ligands belonging to the tmpa family.

Journal: Dalton transactions (Cambridge, England : 2003) 20110514

Title: Dicyanido[tris-(2-pyridyl-meth-yl)amine]-cobalt(III) hexa-fluorido-phosphate.

Journal: Acta crystallographica. Section E, Structure reports online 20110501

Title: Mice lacking MSK1 and MSK2 show reduced skin tumor development in a two-stage chemical carcinogenesis model.

Journal: Cancer investigation 20110301

Title: A theoretical study on the exciton circular dichroism of propeller-like metal complexes of bipyridine and tripodal tris(2-pyridylmethyl)amine derivatives.

Journal: Chirality 20110201

Title: Tuning the conversion of cyclohexane into cyclohexanol/one by molecular dioxygen, protons and reducing agents at a single non-porphyrinic iron centre and chemical versatility of the tris(2-pyridylmethyl)amine TPAFe(II)Cl2 complex in mild oxidation chemistry.

Journal: Dalton transactions (Cambridge, England : 2003) 20110107

Title: Structural comparison of copper(I) and copper(II) complexes with tris(2-pyridylmethyl)amine ligand.

Journal: Inorganic chemistry 20101115

Title: Regulation of differentiation by a PHD domain in the NUP98-PHF23 fusion protein.

Journal: Leukemia research 20100801

Title: Evaluation of diuron (3-[3,4-dichlorophenyl]-1,1-dimethyl urea) in a two-stage mouse skin carcinogenesis assay.

Journal: Toxicologic pathology 20100801

Title: A novel imaging approach for early detection of prostate cancer based on endogenous zinc sensing.

Journal: Cancer research 20100801

Title: Development of highly sensitive fluorescent probes for detection of intracellular copper(I) in living systems.

Journal: Journal of the American Chemical Society 20100505

Title: Synthesis and characterization of ruthenium(II)-pyridylamine complexes with catechol pendants as metal binding sites.

Journal: Inorganic chemistry 20100419

Title: Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes.

Journal: Inorganic chemistry 20100215

Title: Investigation and improvement of DNA cleavage models of polyamide + Cu(II) nuclease + OOH- ligands bound to DNA.

Journal: BMC structural biology 20100101

Title: (Mu-eta2:eta2-disulfido)dinickel(II) complexes supported by 6-methyl-TPA ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20091121

Title: Biomimetic interaction between Fe(II) and O2: effect of the second coordination sphere on O2 binding to Fe(II) complexes: evidence of coordination at the metal centre by a dissociative mechanism in the formation of mu-oxo diferric complexes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20091012

Title: Observed enhancement of the reactivity of a biomimetic diiron complex by the addition of water - mechanistic insights from theoretical modeling.

Journal: Dalton transactions (Cambridge, England : 2003) 20090914

Title: A [4+2] mixed ligand approach to ruthenium DNA metallointercalators [Ru(tpa)(N-N)](PF(6))(2) using a tris(2-pyridylmethyl)amine (tpa) capping ligand.

Journal: Journal of inorganic biochemistry 20090801

Title: Polymorphism in the spin-crossover ferric complexes [(TPA)Fe(III)(TCC)]PF6.

Journal: Acta crystallographica. Section B, Structural science 20090801

Title: Bis(thio-cyanato-κN)[tris-(2-pyridylmeth-yl)amine-κN,N',N'',N''']nickel(II) methanol hemisolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20090701

Title: Regiospecific intramolecular O-demethylation of the ligand by action of molecular dioxygen on a ferrous complex: versatile coordination chemistry of dioxygen in FeCl(2) complexes with (2,3-dimethoxyphenyl) alpha-substituted tripods in the tris(2-pyridylmethyl)amine series.

Journal: Inorganic chemistry 20090601

Title: Surface-initiated activators generated by electron transfer for atom transfer radical polymerization in detection of DNA point mutation.

Journal: Analytical chemistry 20090601

Title: Observation of redox-induced electron transfer and spin crossover for dinuclear cobalt and iron complexes with the 2,5-di-tert-butyl-3,6-dihydroxy-1,4-benzoquinonate bridging ligand.

Journal: Journal of the American Chemical Society 20090506

Title: Polynuclear spin crossover complexes: synthesis, structure, and magnetic behavior of [Fe4(mu-CN)4(phen)4(L)2)]4+ squares.

Journal: Inorganic chemistry 20090420

Title: Possible steric control of the relative strength of chelation enhanced fluorescence for zinc(II) compared to cadmium(II): metal ion complexing properties of tris(2-quinolylmethyl)amine, a crystallographic, UV-visible, and fluorometric study.

Journal: Inorganic chemistry 20090216

Title: Two transition metal coordination polymers of the 7,7,8,8-tetracyanoquinodimethane dianion (TCNQ2-).

Journal: Acta crystallographica. Section C, Crystal structure communications 20090101

Title: Anti-inflammatory and arthritic effects of thiacremonone, a novel sulfur compound isolated from garlic via inhibition of NF-kappaB.

Journal: Arthritis research & therapy 20090101

Title: The preparation and full characterization of dichloroferrous complexes of mono-, bis- and tris-alpha-methyl substituted tris(2-pyridylmethyl)amine (TPA) ligands. Structural bases of stability of the complexes in solution.

Journal: Dalton transactions (Cambridge, England : 2003) 20081228

Title: The effect and influence of cis-ligands on the electronic and oxidizing properties of nonheme oxoiron biomimetics. A density functional study.

Journal: The journal of physical chemistry. A 20081218

Title: H2O2-reactivity of copper(II) complexes supported by tris[(pyridin-2-yl)methyl]amine ligands with 6-phenyl substituents.

Journal: Inorganic chemistry 20081215

Title: Synthesis and characterization of mononuclear hydroxamato and hydroximato complexes of iron(III) based on the tris-(2-pyridylmethyl)amine ligand.

Journal: Dalton transactions (Cambridge, England : 2003) 20081207

Title: The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes.

Journal: Chemical communications (Cambridge, England) 20081207

Title: 2,2',2''-[Nitrilo-tris(methyl-ene-p-phenyl-ene)]tribenzonitrile.

Journal: Acta crystallographica. Section E, Structure reports online 20081001

Title: Quantitative proliferation dynamics and random chromosome segregation of hair follicle stem cells.

Journal: The EMBO journal 20080507

Title: Berberine inhibits TPA-induced MMP-9 and IL-6 expression in normal human keratinocytes.

Journal: Phytomedicine : international journal of phytotherapy and phytopharmacology 20080501

Title: Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety.

Journal: Journal of the American Chemical Society 20080430

Title: Iron(II) complexes of sterically bulky alpha-ketocarboxylates. structural models for alpha-ketoacid-dependent nonheme iron halogenases.

Journal: Inorganic chemistry 20080218

Title: A dinuclear iron(II) complex, [(TPyA)FeII(THBQ(2-))FeII(TPyA)](BF4)2 [TPyA = tris(2-pyridylmethyl)amine; THBQ(2-) = 2,3,5,6-tetrahydroxy-1,4-benzoquinonate] exhibiting both spin crossover with hysteresis and ferromagnetic exchange.

Journal: Chemical communications (Cambridge, England) 20080121

Title: Proton-coupled electron transfer in ruthenium(II)-pterin complexes: formation of ruthenium-coordinated pterin radicals and their electronic structures.

Journal: Inorganic chemistry 20080107

Title: Contrasting cis and trans effects on the reactivity of nonheme oxoiron(IV) complexes.

Journal: Angewandte Chemie (International ed. in English) 20080101

Title: Reactivity of molecular dioxygen towards a series of isostructural dichloroiron(III) complexes with tripodal tetraamine ligands: general access to mu-oxodiiron(III) complexes and effect of alpha-fluorination on the reaction kinetics.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: μ-Oxido-bis-{chlorido[tris-(2-pyridylmeth-yl)amine]chromium(III)} bis(hexafluoridophosphate).

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: μ-Oxido-bis-{chlorido[tris-(2-pyridylmethyl)amine]manganese(III)} bis-(hexa-fluorido-phosphate).

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues.

Journal: Inorganic chemistry 20070723

Title: Atom transfer radical addition in the presence of catalytic amounts of copper(I/II) complexes with tris(2-pyridylmethyl)amine.

Journal: Inorganic chemistry 20070723

Title: Ligand effects on dioxygen activation by copper and nickel complexes: reactivity and intermediates.

Journal: Accounts of chemical research 20070701

Title: Aryl hydroxylation from a mononuclear copper-hydroperoxo species.

Journal: Journal of the American Chemical Society 20070606

Title: Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry.

Journal: Journal of the American Chemical Society 20070530

Title: Generation and characterization of [(P)M-(X)-Co(TMPA)]n+ assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O2(2-), and TMPA = tris(2-pyridylmethyl)amine.

Journal: Inorganic chemistry 20070416

Title: Kinetic analysis of the conversion of nonheme (alkylperoxo)iron(III) species to iron(IV) complexes.

Journal: Inorganic chemistry 20070402

Title: Ligand effects on Ni(II)-catalysed alkane-hydroxylation with m-CPBA.

Journal: Dalton transactions (Cambridge, England : 2003) 20070321

Title: Synthesis, pharmacological evaluation and electrochemical studies of novel 6-nitro-3,4-methylenedioxyphenyl-N-acylhydrazone derivatives: Discovery of LASSBio-881, a new ligand of cannabinoid receptors.

Journal: Bioorganic & medicinal chemistry 20070315

Title: Synthesis, structure, and magnetic properties of valence ambiguous dinuclear antiferromagnetically coupled cobalt and ferromagnetically coupled iron complexes containing the chloranilate(2-) and the significantly stronger coupling chloranilate(*3-) radical trianion.

Journal: Journal of the American Chemical Society 20070227

Title: Room-temperature spin crossover observed for [(TPyA)FeII(DBQ(2-))Fe(II)(TPyA)](2+) [TPyA = Tris(2-pyridylmethyl)amine; DBQ(2-) = 2,5-Di-tert-butyl-3,6-dihydroxy-1,4-benzoquinonate].

Journal: Inorganic chemistry 20070219

Title: Synthesis and characterization of mononuclear ruthenium(III) pyridylamine complexes and mechanistic insights into their catalytic alkane functionalization with m-chloroperbenzoic acid.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

Title: Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation.

Journal: Inorganic chemistry 20061211

Title: Syntheses, characterization, and catalytic ability in alkane oxygenation of chloro(dimethyl sulfoxide)ruthenium(II) complexes with tris(2-pyridylmethyl)amine and its derivatives.

Journal: Inorganic chemistry 20061002

Title: Rapid induction of skin tumors in human but not mouse c-Ha-ras proto-oncogene transgenic mice by chemical carcinogenesis.

Journal: Cancer science 20060901

Title: The coordination chemistry of FeCl3 and FeCl2 to bis[2-(2,3-dihydroxyphenyl)-6-pyridylmethyl](2-pyridylmethyl)amine: access to a diiron(III) compound with an unusual pentagonal-bipyramidal/square-pyramidal environment.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060825

Title: Rhodium, palladium and platinum complexes of tris(pyridylalkyl)amine and tris(benzimidazolylmethyl)amine N4-tripodal ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20060821

Title: Efficient synthesis of calix[6]tmpa: a new calix[6]azacryptand with unique conformational and host-guest properties.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060816

Title: Nonheme oxoiron(IV) complexes of tris(2-pyridylmethyl)amine with cis-monoanionic ligands.

Journal: Inorganic chemistry 20060807

Title: Oxoiron(IV) complexes of the tris(2-pyridylmethyl)amine ligand family: effect of pyridine alpha-substituents.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20060401

Title: A sensitive probe for the detection of Zn(II) by time-resolved fluorescence.

Journal: Journal of the American Chemical Society 20060329

Title: Evidence for Cu-O2 intermediates in superoxide oxidations by biomimetic copper(II) complexes.

Journal: Journal of the American Chemical Society 20060322

Title: Stabilization of coordinated carbonate in aqueous acidic solution: steric inhibition of protonation in Co(III) complexes containing chelated carbonate.

Journal: Inorganic chemistry 20060320

Title: Density functional study of the O2 binding to [CuI(TPAR)]+ (TPA = tris(2-pyridylmethyl)amine) in THF and EtCN.

Journal: Inorganic chemistry 20060220

Title: Protein kinase C delta overexpressing transgenic mice are resistant to chemically but not to UV radiation-induced development of squamous cell carcinomas: a possible link to specific cytokines and cyclooxygenase-2.

Journal: Cancer research 20060115

Title: Tris(chloranilato)ferrate(III) anionic building block containing the (Dihydroxo)oxodiiron(III) dimer cation: synthesis and characterization of [(TPA)(OH)FeIIIOFeIII(OH)(TPA)][Fe(CA)3]0.5(BF4)0.5.1.5MeOH.H2O [TPA = tris(2-pyridylmethyl)amine; CA = chloranilate].

Journal: Journal of the American Chemical Society 20060111

Title: Correlation of spin states and spin delocalization with the dioxygen reactivity of catecholatoiron(III) complexes.

Journal: Inorganic chemistry 20051128

Title: EMX homeobox genes regulate microphthalmia and alter melanocyte biology.

Journal: Experimental cell research 20051115

Title: A diiron center stabilized by a bis-TPA ligand as a model of soluble methane monooxygenase: predominant alkene epoxidation with H2O2.

Journal: Angewandte Chemie (International ed. in English) 20051104

Title: Chelate ring size variations and their effects on coordination chemistry and catechol dioxygenase reactivity of iron(III) complexes.

Journal: Inorganic chemistry 20051017

Title: Activity-dependent subcellular localization of NAC1.

Journal: The European journal of neuroscience 20050701

Title: Controlled hydrolysis of lanthanide complexes of the N-donor tripod tris(2-pyridylmethyl)amine versus bisligand complex formation.

Journal: Inorganic chemistry 20050627

Title: Spin crossover of ferric complexes with catecholate derivatives. Single-crystal X-ray structure, magnetic and Mössbauer investigations.

Journal: Dalton transactions (Cambridge, England : 2003) 20050505

Title: Src homology domains in phospholipase C-gamma1 mediate its anti-apoptotic action through regulating the enzymatic activity.

Journal: Journal of neurochemistry 20050501

Title: Mononuclear oxovanadium complexes of tris(2-pyridylmethyl)amine.

Journal: Dalton transactions (Cambridge, England : 2003) 20050421

Title: Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase.

Journal: Journal of the American Chemical Society 20050316

Title: Electronic, vibrational, and structural properties of a spin-crossover catecholato-iron system in the solid state: theoretical study of the electronic nature of the doublet and sextet states.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050304

Title: A linear correlation between energy of LMCT band and oxygenation reaction rate of a series of catecholatoiron(III) complexes: initial oxygen binding during intradiol catechol oxygenation.

Journal: Journal of inorganic biochemistry 20050301

Title: Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O2(2-))-CuII]+.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20050101

Title: Rigidified tripodal chiral ligands in the asymmetric recognition of amino compounds.

Journal: Chirality 20050101

Title: Preparation, structure characterization, and oxidation activity of ruthenium complexes with tripodal ligands bearing noncovalent interaction sites.

Journal: Inorganic chemistry 20041213

Title: Glycoprotein isolated from Solanum nigrum L. inhibits the DNA-binding activities of NF-kappaB and AP-1, and increases the production of nitric oxide in TPA-stimulated MCF-7 cells.

Journal: Toxicology in vitro : an international journal published in association with BIBRA 20041201

Title: Designing dinuclear iron(II) spin crossover complexes. Structure and magnetism of dinitrile-, dicyanamido-, tricyanomethanide-, bipyrimidine- and tetrazine-bridged compounds.

Journal: Dalton transactions (Cambridge, England : 2003) 20041021

Title: Glutamate-dependent transcriptional regulation of GLAST: role of PKC.

Journal: Journal of neurochemistry 20041001

Title: Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform.

Journal: Inorganic chemistry 20040920

Title: TIS21/BTG2/PC3 is expressed through PKC-delta pathway and inhibits binding of cyclin B1-Cdc2 and its activity, independent of p53 expression.

Journal: Experimental cell research 20040910

Title: Epidermal growth factor upregulates matrix metalloproteinase-7 expression through activation of PEA3 transcription factors.

Journal: International journal of oncology 20040601

Title: Photoassisted oxygenation of alkane catalyzed by ruthenium complexes using 2,6-dichloropyridine N-oxide under visible light irradiation.

Journal: Chemical communications (Cambridge, England) 20040407

Title: Toward a photochemical and thermal molecular machine: reversible ligand dissociation and binding in a ruthenium(II)-2,2'-bipyridine complex with tris(2-pyridylmethyl)amine.

Journal: Inorganic chemistry 20040405

Title: Geometry-dependent phosphodiester hydrolysis catalyzed by binuclear copper complexes.

Journal: Inorganic chemistry 20031201

Title: Chromium(II) and chromium(III) complexes supported by tris(2-pyridylmethyl)amine: synthesis, structures, and reactivity.

Journal: Inorganic chemistry 20031020

Title: The rate of O2 and CO binding to a copper complex, determined by a 'flash-and-trap' technique, exceeds that for hemes.

Journal: Journal of the American Chemical Society 20031001

Title: Protein kinase C inhibition induces DNA fragmentation in COLO 205 cells which is blocked by cysteine protease inhibition but not mediated through caspase-3.

Journal: Experimental cell research 20030910

Title: A dramatic push effect on the homolysis of FeIII(OOR) intermediates to form non-heme FeIV=O complexes.

Journal: Angewandte Chemie (International ed. in English) 20030811

Title: Atypical protein kinase C mediates activation of NF-E2-related factor 2 in response to oxidative stress.

Journal: American journal of physiology. Cell physiology 20030801

Title: Inhibition of caspase-9 through phosphorylation at Thr 125 by ERK MAPK.

Journal: Nature cell biology 20030701

Title: Spectroscopic study of [Fe2O2(5-Et3-TPA)2]3+: nature of the Fe2O2 diamond core and its possible relevance to high-valent binuclear non-heme enzyme intermediates.

Journal: Journal of the American Chemical Society 20030618

Title: Synthesis and characterization of reduced heme and heme/copper carbonmonoxy species.

Journal: Inorganic chemistry 20030505

Title: Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations.

Journal: Inorganic chemistry 20030324

Title: Biomimetic aryl hydroxylation derived from alkyl hydroperoxide at a nonheme iron center. Evidence for an Fe(IV)=O oxidant.

Journal: Journal of the American Chemical Society 20030226

Title: Electronic structure and reactivity of high-spin iron--alkyl- and--pterinperoxo complexes.

Journal: Inorganic chemistry 20030127

Title: Could redox-switched binding of a redox-active ligand to a copper(II) centre drive a conformational proton pump gate? A synthetic model study.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20030103

Title: Overexpression of telomerase confers a survival advantage through suppression of TRF1 gene expression while maintaining differentiation characteristics in K562 cells.

Journal: Cell transplantation 20030101

Title: Trigonal bipyramidal geometry and tridentate coordination mode of the tripod in FeCl(2) complexes with tris(2-pyridylmethyl)amine derivatives bis-alpha-substituted with bulky groups. structures and spectroscopic comparative studies.

Journal: Inorganic chemistry 20021021

Title: A density functional study of O-O bond cleavage for a biomimetic non-heme iron complex demonstrating an Fe(v)-intermediate.

Journal: Journal of the American Chemical Society 20020918

Title: Electronic structure and reactivity of low-spin Fe(III)-hydroperoxo complexes: comparison to activated bleomycin.

Journal: Journal of the American Chemical Society 20020911

Title: Oxidative strand scission of nucleic acids by a multinuclear copper(II) complex.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20020901

Title: Anion sensing with luminescent lanthanide complexes of tris(2-pyridylmethyl)amines: pronounced effects of lanthanide center and ligand chirality on anion selectivity and sensitivity.

Journal: Chemical communications (Cambridge, England) 20020607

Title: Human Krüppel-like factor5/KLF5: synergy with NF-kappaB/Rel factors and expression in human skin and hair follicles.

Journal: European journal of cell biology 20020601

Title: Efficient and specific strand scission of DNA by a dinuclear copper complex: comparative reactivity of complexes with linked tris(2-pyridylmethyl)amine moieties.

Journal: Journal of the American Chemical Society 20020529

Title: Synthesis, structures, and magnetic properties of heterodimetal bis(mu-hydroxo)chromium(III)nickel(II) complexes with Tpa derivatives having sterically bulky substituents.

Journal: Inorganic chemistry 20020325

Title: Electronic structure of high-spin iron(III)-alkylperoxo complexes and its relation to low-spin analogues: reaction coordinate of O-O bond homolysis.

Journal: Journal of the American Chemical Society 20011226

Title: Spectroscopic properties and electronic structure of low-spin Fe(III)-alkylperoxo complexes: homolytic cleavage of the O-O bond.

Journal: Journal of the American Chemical Society 20010829

Title: Tridentate coordination of monosubstituted derivatives of the tris(2-pyridylmethyl)amine ligand to FeCl3: structures and spectroscopic properties of ((2-bromopyridyl)methyl)bis-(2-pyridylmethyl)amine Fe(III)Cl3 and (((2-p-methoxyphenyl)pyridyl)methyl)bis(2-pyridyl-methyl)]amine Fe(III)Cl3 and comparison with the bis(2-pyridylmethyl)]amine Fe(III)Cl3 complex.

Journal: Inorganic chemistry 20010827

Title: Stereospecific alkane hydroxylation by non-heme iron catalysts: mechanistic evidence for an Fe(V)=O active species.

Journal: Journal of the American Chemical Society 20010704

Title: Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands.

Journal: Inorganic chemistry 20010507

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Tags:16858-01-8 Molecular Formula|16858-01-8 MDL|16858-01-8 SMILES|16858-01-8 Tris(2-pyridylmethyl)amine