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Home Boronic Acids 196207-58-6
196207-58-6,MFCD16294554
Catalog No.:AA0034C7

196207-58-6 | 9,9-Di-n-octylfluorene-2,7-diboronic acid bis(pinacol) ester

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
97%
in stock  
$9.00   $7.00
- +
5g
97%
in stock  
$39.00   $28.00
- +
10g
97%
in stock  
$77.00   $54.00
- +
25g
97%
in stock  
$191.00   $134.00
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100g
97%
in stock  
$757.00   $530.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA0034C7
Chemical Name:
9,9-Di-n-octylfluorene-2,7-diboronic acid bis(pinacol) ester
CAS Number:
196207-58-6
Molecular Formula:
C41H64B2O4
Molecular Weight:
642.5665
MDL Number:
MFCD16294554
SMILES:
CCCCCCCCC1(CCCCCCCC)c2cc(ccc2c2c1cc(cc2)B1OC(C(O1)(C)C)(C)C)B1OC(C(O1)(C)C)(C)C
Properties
Properties
 
BP:
701.6°C at 760 mmHg  
Form:
Solid  
MP:
129 °C  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
884  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
47  
Hydrogen Bond Acceptor Count:
4  
Rotatable Bond Count:
16  

Upstream Synthesis Route

[1]JournalofMaterialsChemistry,2003,vol.13,#4,p.807-813

[2]Patent:CN106588869,2017,A,.Locationinpatent:Paragraph0053;0054;0055;0056

[3]Patent:KR101495152,2015,B1,.Locationinpatent:Paragraph0152;0159-0160

[4]Patent:CN106366067,2017,A,.Locationinpatent:Paragraph0053;0054;0055;0056

[5]Macromolecules,2004,vol.37,#4,p.1211-1218

[6]SoftMatter,2011,vol.7,#21,p.10025-10031

[7]JournalofNanoscienceandNanotechnology,2014,vol.14,#8,p.6331-6336

[8]Patent:CN106187908,2016,A,.Locationinpatent:Paragraph0084;0085

[9]Patent:CN106946878,2017,A,.Locationinpatent:Paragraph0080;0084-0085

[10]Patent:CN106866679,2017,A,.Locationinpatent:Paragraph0048;0049;0050;0051

[11]Patent:CN106866542,2017,A,.Locationinpatent:Paragraph0055;0056;0057;0058;0059

[12]Patent:CN107162984,2017,A,.Locationinpatent:Paragraph0055-0059

[13]Patent:CN105001233,2017,B,.Locationinpatent:Paragraph0082;0084;0087

[14]Patent:CN107011269,2017,A,.Locationinpatent:Paragraph0060;0061

[15]Patent:CN107573299,2018,A,.Locationinpatent:Paragraph0052-0056

[16]JournalofMaterialsChemistry,2005,vol.15,#25,p.2499-2507

[17]Macromolecules,2004,vol.37,#3,p.709-715

[18]ChemicalCommunications,1997,#17,p.1597-1598

[19]Patent:EP2657226,2013,A1,.Locationinpatent:Paragraph0047;0048;0049;0050;0051

[20]Patent:EP2657239,2013,A1,.Locationinpatent:Paragraph0049;0050

[21]Macromolecules,2004,vol.37,#14,p.5265-5273

[22]JournaloftheAmericanChemicalSociety,2007,vol.129,#39,p.11910-11911

[23]Macromolecules,2003,vol.36,#12,p.4288-4293

[24]Macromolecules,2005,vol.38,#15,p.6336-6345

[25]MolecularCrystalsandLiquidCrystals,2010,vol.530,p.64-73

[26]JournalofPolymerScience,PartA:PolymerChemistry,2010,vol.48,#18,p.3942-3949

[27]JournalofMaterialsChemistry,2002,vol.12,#10,p.2887-2892

[28]JournalofMaterialsChemistry,2003,vol.13,#6,p.1351-1355

[29]Macromolecules,2003,vol.36,#20,p.7453-7460

[30]JournaloftheAmericanChemicalSociety,2018,vol.140,#5,p.1622-1626

[31]JournalofMaterialsChemistry,2012,vol.22,#15,p.7515-7528

[32]Macromolecules,2004,vol.37,#11,p.4087-4098

[33]Macromolecules,2010,vol.43,#3,p.1253-1260

[34]JournalofPolymerScience,PartA:PolymerChemistry,2011,vol.49,#17,p.3874-3881

[35]JournalofPolymerScience,PartA:PolymerChemistry,2011,vol.49,#5,p.1248-1255

[36]DyesandPigments,2013,vol.99,#3,p.895-902

[37]Patent:US8779204,2014,B2,.Locationinpatent:Page/Pagecolumn18

[38]JournalofNanoscienceandNanotechnology,2014,vol.14,#8,p.6038-6042

[39]OrganicElectronics:physics,materials,applications,2014,vol.15,#11,p.2942-2949

[40]OrganicElectronics:physics,materials,applications,2014,vol.15,#11,p.2942-2949

[41]DyesandPigments,2017,vol.145,p.110-115

[1]Patent:CN105348308,2016,A,.Locationinpatent:Paragraph0057;0058

[2]OrganicLetters,2017,vol.19,#3,p.600-603

[3]Patent:CN108530387,2018,A,.Locationinpatent:Paragraph0063;0065

[4]RSCAdvances,2018,vol.8,#53,p.30468-30480

[5]Patent:CN107879968,2018,A,.Locationinpatent:Paragraph0101-0103

[6]DyesandPigments,2012,vol.94,#3,p.380-385

[7]Polymer,2012,vol.53,#7,p.1529-1534

[8]TetrahedronLetters,2015,vol.56,#52,p.7145-7149

[9]RSCAdvances,2017,vol.7,#30,p.18384-18391

[1]Patent:EP2520576,2012,A1,.Locationinpatent:Page/Pagecolumn77-78

[1]Macromolecules,2005,vol.38,#2,p.244-253

[1]Macromolecules,2004,vol.37,#11,p.4087-4098

[2]Macromolecules,2005,vol.38,#2,p.244-253

[3]Macromolecules,2004,vol.37,#4,p.1211-1218

[4]JournalofPolymerScience,PartA:PolymerChemistry,2010,vol.48,#18,p.3942-3949

[5]DyesandPigments,2012,vol.94,#3,p.380-385

[6]Polymer,2012,vol.53,#7,p.1529-1534

[7]OrganicElectronics:physics,materials,applications,2014,vol.15,#11,p.2942-2949

[8]OrganicElectronics:physics,materials,applications,2014,vol.15,#11,p.2942-2949

[9]Patent:CN105348308,2016,A,

[10]Patent:KR101495152,2015,B1,

[11]Patent:CN106366067,2017,A,

[12]Patent:CN106588869,2017,A,

[13]Patent:CN106866679,2017,A,

[14]Patent:CN106866542,2017,A,

[15]Patent:CN107162984,2017,A,

[16]Patent:CN105001233,2017,B,

[17]Patent:CN107573299,2018,A,

[18]RSCAdvances,2018,vol.8,#53,p.30468-30480

Downstream Synthesis Route

[1]JournalofMaterialsChemistry,2003,vol.13,p.807-813

[2]Patent:CN106588869,2017,A.Locationinpatent:Paragraph0053;0054;0055;0056

[3]Patent:CN105017302,2019,B.Locationinpatent:Paragraph0035-0037;0040

[4]Patent:KR101495152,2015,B1.Locationinpatent:Paragraph0152;0159-0160

[5]Patent:CN106366067,2017,A.Locationinpatent:Paragraph0053;0054;0055;0056

[6]Macromolecules,2004,vol.37,p.1211-1218

[7]SoftMatter,2011,vol.7,p.10025-10031

[8]JournalofNanoscienceandNanotechnology,2014,vol.14,p.6331-6336

[9]Patent:CN106187908,2016,A.Locationinpatent:Paragraph0084;0085

[10]Patent:CN106946878,2017,A.Locationinpatent:Paragraph0080;0084-0085

[11]Patent:CN106866679,2017,A.Locationinpatent:Paragraph0048;0049;0050;0051

[12]Patent:CN106866542,2017,A.Locationinpatent:Paragraph0055;0056;0057;0058;0059

[13]Patent:CN107162984,2017,A.Locationinpatent:Paragraph0055-0059

[14]Patent:CN105001233,2017,B.Locationinpatent:Paragraph0082;0084;0087

[15]Patent:CN107011269,2017,A.Locationinpatent:Paragraph0060;0061

[16]Patent:CN107573299,2018,A.Locationinpatent:Paragraph0052-0056

[17]Patent:CN106675554,2019,B.Locationinpatent:Paragraph0071-0072;0075-0076

[18]Patent:CN106675551,2020,B.Locationinpatent:Paragraph0094;0098-0099

[19]JournalofMaterialsChemistry,2005,vol.15,p.2499-2507

[20]JournalofMaterialsChemistryA,2020,vol.8,p.5315-5322

[21]Macromolecules,2004,vol.37,p.709-715

[22]ChemicalCommunications,1997,p.1597-1598

[23]Patent:EP2657226,2013,A1.Locationinpatent:Paragraph0047;0048;0049;0050;0051

[24]Patent:EP2657239,2013,A1.Locationinpatent:Paragraph0049;0050

[25]Macromolecules,2004,vol.37,p.5265-5273

[26]JournaloftheAmericanChemicalSociety,2007,vol.129,p.11910-11911

[27]Macromolecules,2003,vol.36,p.4288-4293

[28]Macromolecules,2005,vol.38,p.6336-6345

[29]MolecularCrystalsandLiquidCrystals,2010,vol.530,p.64-73

[30]JournalofPolymerScience,PartA:PolymerChemistry,2010,vol.48,p.3942-3949

[31]JournalofMaterialsChemistry,2002,vol.12,p.2887-2892

[32]JournalofMaterialsChemistry,2003,vol.13,p.1351-1355

[33]Macromolecules,2003,vol.36,p.7453-7460

[34]JournaloftheAmericanChemicalSociety,2018,vol.140,p.1622-1626

[35]JournalofMaterialsChemistry,2012,vol.22,p.7515-7528

[36]Macromolecules,2004,vol.37,p.4087-4098

[37]Macromolecules,2010,vol.43,p.1253-1260

[38]JournalofPolymerScience,PartA:PolymerChemistry,2011,vol.49,p.3874-3881

[39]JournalofPolymerScience,PartA:PolymerChemistry,2011,vol.49,p.1248-1255

[40]DyesandPigments,2013,vol.99,p.895-902

[41]Patent:US8779204,2014,B2.Locationinpatent:Page/Pagecolumn18

[42]JournalofNanoscienceandNanotechnology,2014,vol.14,p.6038-6042

[43]Organicelectronics,2014,vol.15,p.2942-2949

[44]Organicelectronics,2014,vol.15,p.2942-2949

[45]DyesandPigments,2017,vol.145,p.110-115

[46]JournalofMaterialsChemistryC,2018,vol.6,p.12355-12363

108-86-1    67665-47-8    196207-58-6    98-80-6   
poly(9,9-dioctylfluorene)-alt-co-(9,9\-spirobifluorene),Mn=14000,Mw/Mn=1.5;monomer(s):2,2\-dibromo-9,9\-spirobifluorene;2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene;phenylboronicacid;bromobenzene 

[1]JournalofMaterialsChemistry,2002,vol.12,p.2893-2897

25121-87-3    196207-58-6   
poly(9,9-dioctylfluorene-2,7-diyl)-alt-(thieno3,2-bthiophene-2,5-diyl),productofSuzukicoupling,Mw=24.5kDa,PDI=1.80;monomer(s):2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene;2,5-dibromothieno3,2-bthiophene 

[1]Macromolecules,2003,vol.36,p.4288-4293

15155-41-6    196207-58-6    673474-73-2   
polymer,Mn11000,Mw24500;monomer(s):2,7-dibromo-9,9-bis(3\-(N,N-dimethylamino)propyl)fluorene,0.495eq.;4,7-dibromo-2,1,3-benzothiadiazole,0.005eq.;2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene,0.50eq. 

[1]Huang,Fei;Hou,Lintao;Wu,Hongbin;Wang,Xiaohui;Shen,Huilin;Cao,Wei;Yang,Wei;Cao,Yong[JournaloftheAmericanChemicalSociety,2004,vol.126,#31,p.9845-9853]

15155-41-6    196207-58-6    673474-73-2   
polymer,Mn10000,Mw18300;monomer(s):2,7-dibromo-9,9-bis(3\-(N,N-dimethylamino)propyl)fluorene,0.49eq.;4,7-dibromo-2,1,3-benzothiadiazole,0.01eq.;2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dioctylfluorene,0.50eq. 

[1]Huang,Fei;Hou,Lintao;Wu,Hongbin;Wang,Xiaohui;Shen,Huilin;Cao,Wei;Yang,Wei;Cao,Yong[JournaloftheAmericanChemicalSociety,2004,vol.126,#31,p.9845-9853]

Literature

Title: 2,2'-(9,9-Dioctyl-9H-fluorene-2,7-di-yl)bis-(4,4,5,5-tetra-methyl-1,3,2-dioxaborolane).

Journal: Acta crystallographica. Section E, Structure reports online 20111201

Title: 9,9-Dioctyl-2,7-bis-(4,4,5,5-tetra-methyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene.

Journal: Acta crystallographica. Section E, Structure reports online 20080801

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Tags:196207-58-6 Molecular Formula|196207-58-6 MDL|196207-58-6 SMILES|196207-58-6 9,9-Di-n-octylfluorene-2,7-diboronic acid bis(pinacol) ester