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Home Other Building Blocks 285-69-8
285-69-8,MFCD00800639
Catalog No.:AA002VGS

285-69-8 | 3,4-Epoxytetrahydrofuran

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
97%
in stock  
$6.00   $4.00
- +
5g
97%
in stock  
$14.00   $10.00
- +
10g
97%
in stock  
$22.00   $15.00
- +
25g
97%
in stock  
$48.00   $34.00
- +
500g
98%
in stock  
$926.00   $648.00
- +
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA002VGS
Chemical Name:
3,4-Epoxytetrahydrofuran
CAS Number:
285-69-8
Molecular Formula:
C4H6O2
Molecular Weight:
86.0892
MDL Number:
MFCD00800639
SMILES:
O1CC2C(C1)O2
NSC Number:
196231
Properties
Computed Properties
 
Complexity:
63.9  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
2  
Undefined Atom Stereocenter Count:
2  
XLogP3:
-0.4  

Upstream Synthesis Route

[1]JournaloftheChemicalSociety,1959,p.248,254

[1]Patent:WO2008/33562,2008,A2,.Locationinpatent:Page/Pagecolumn53

[2]Patent:US2009/76005,2009,A1,.Locationinpatent:Page/Pagecolumn23

[3]BioorganicandMedicinalChemistry,2006,vol.14,#24,p.8467-8487

[4]Patent:US5374416,1994,A,

[5]Patent:US2009/30212,2009,A1,.Locationinpatent:Page/Pagecolumn15-16

[6]Patent:US6362343,2002,B1,.Locationinpatent:Example3

[7]OrganicandBiomolecularChemistry,2009,vol.7,#9,p.1921-1930

[8]AngewandteChemie-InternationalEdition,2014,vol.53,#31,p.8142-8145

[9]Angew.Chem.,2014,vol.126,#31,p.8280-8283,4

[10]Patent:WO2016/44770,2016,A1,.Locationinpatent:Page/Pagecolumn726

[11]JournaloftheChemicalSociety,1959,p.248,254

[12]Tetrahedron,1993,vol.49,#28,p.6263-6276

[13]SyntheticCommunications,2004,vol.34,#11,p.1981-1987

[14]Patent:US5420343,1995,A,

[15]Patent:US5602118,1997,A,

[16]Patent:WO2012/101654,2012,A2,.Locationinpatent:Page/Pagecolumn66

[17]Patent:WO2013/138210,2013,A1,.Locationinpatent:Paragraph0173

[18]Patent:WO2015/52264,2015,A1,.Locationinpatent:Paragraph01202;01203

[1]Patent:WO2016/44770,2016,A1,.Locationinpatent:Page/Pagecolumn726

[2]Patent:WO2008/33562,2008,A2,.Locationinpatent:Page/Pagecolumn53

[3]Patent:US2009/76005,2009,A1,.Locationinpatent:Page/Pagecolumn23

Downstream Synthesis Route

[1]JustusLiebigsAnnalenderChemie,1955,vol.596,p.1,100,139

[1]JournaloftheChemicalSociety,1959,p.248,254

[2]JustusLiebigsAnnalenderChemie,1955,vol.596,p.1,100,139

[3]Patent:DE734474,1941,    DRP/DRBPOrg.Chem.,

[1]JustusLiebigsAnnalenderChemie,1955,vol.596,p.1,139

[2]Patent:DE734474,1941,    DRP/DRBPOrg.Chem.,

[1]JournaloftheChemicalSociety,1959,p.248,254

[1]BioorganicandMedicinalChemistry,2006,vol.14,p.8467-8487

[2]ChemicalCommunications,2004,p.2234-2235

[3]JournalofOrganicChemistry,2006,vol.71,p.8510-8515

[4]JustusLiebigsAnnalenderChemie,1955,vol.596,p.1,139

Literature

Title: A stereocontrolled method for the synthesis of D- and L-2-deoxy-C-nucleosides using an intramolecular Sakurai-type cyclisation reaction.

Journal: Chemical communications (Cambridge, England) 20100707

Title: Enantioselective alkylative double ring-opening of epoxides derived from cyclic allylic ethers: synthesis of enantioenriched unsaturated diols.

Journal: Organic & biomolecular chemistry 20030407

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SDS
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