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395116-70-8,MFCD05861603
Catalog No.:AA003P7Q

395116-70-8 | Di(1-adamantyl)benzylphosphine

Pack Size
Purity
Availability
Price(USD)
Quantity
  
500mg
min. 85% [cataCXium® ABn]
in stock  
$237.00   $166.00
- +
1g
95%
in stock  
$291.00   $204.00
- +
5g
95%
in stock  
$1,059.00   $742.00
- +
25g
95%
in stock  
$4,563.00   $3,194.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003P7Q
Chemical Name:
Di(1-adamantyl)benzylphosphine
CAS Number:
395116-70-8
Molecular Formula:
C27H37P
Molecular Weight:
392.5564
MDL Number:
MFCD05861603
SMILES:
C1C2CC3CC1CC(C2)(C3)P(C12CC3CC(C2)CC(C1)C3)Cc1ccccc1
Properties
Properties
 
Form:
Solid  
MP:
183°C  
Stability:
air sensitive  
Storage:
-20 ℃;Inert atmosphere;  

Computed Properties
 
Complexity:
487  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
28  
Rotatable Bond Count:
4  
XLogP3:
6.8  

Downstream Synthesis Route

[1]Synthesis,2004,p.935-941

[2]Patent:US2004/68131,2004,A1

112579-52-9    395116-70-8   
CASUnavailable 

[1]Datta,Anupama;Koellhofer,Axel;Plenio,Herbert[ChemicalCommunications,2004,#13,p.1508-1509]

39929-21-0    395116-70-8   
CASUnavailable 

[1]Monkowius,Uwe;Zabel,Manfred;Yersin,Hartmut[InorganicChemistryCommunications,2008,vol.11,#4,p.409-412]

CASUnavailable 
  395116-70-8   
CASUnavailable 

[1]Kaspi,ArielaW.;Goldberg,Israel;Vigalok,Arkadi[JournaloftheAmericanChemicalSociety,2010,vol.132,#31,p.10626-10627]

[1]Li,Yuehui;Das,Shoubhik;Zhou,Shaolin;Junge,Kathrin;Beller,Matthias[JournaloftheAmericanChemicalSociety,2012,vol.134,#23,p.9727-9732]

Literature

Title: Homogeneous catalysts supported on soluble polymers: biphasic Suzuki-Miyaura coupling of aryl chlorides using phase-tagged palladium-phosphine catalysts.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20040402

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SDS
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