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Home Other Building Blocks 5683-31-8
5683-31-8,MFCD00190216
Catalog No.:AA003I8L

5683-31-8 | 3-(Trimethylsilyl)propiolic acid

Pack Size
Purity
Availability
Price(USD)
Quantity
  
100mg
95%
in stock  
$14.00   $10.00
- +
250mg
95%
in stock  
$17.00   $12.00
- +
1g
97%
in stock  
$28.00   $19.00
- +
5g
95%
in stock  
$100.00   $70.00
- +
25g
95%
in stock  
$495.00   $347.00
- +
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003I8L
Chemical Name:
3-(Trimethylsilyl)propiolic acid
CAS Number:
5683-31-8
Molecular Formula:
C6H10O2Si
Molecular Weight:
142.2279
MDL Number:
MFCD00190216
SMILES:
OC(=O)C#C[Si](C)(C)C
Properties
Properties
 
BP:
219.1±9.0°C at 760 mmHg  
Form:
Solid  
MP:
47-49 °C(lit.)  
Solubility:
Soluble in methanol.  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
176  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
1  

Upstream Synthesis Route

[1]ChemistryLetters,2016,vol.45,#2,p.188-190

[1]ChemicalCommunications,2014,vol.50,#10,p.1195-1197

[2]NewJournalofChemistry,2017,vol.41,#23,p.14145-14151

[3]DaltonTransactions,2015,vol.44,#48,p.20874-20882

[4]AdvancedSynthesisandCatalysis,2013,vol.355,#11-12,p.2353-2360

[5]JournaloftheChemicalSociety,PerkinTransactions1:OrganicandBio-OrganicChemistry(1972-1999),1992,#24,p.3351-3362

[1]JournaloftheChemicalSociety,ChemicalCommunications,1985,#7,p.421

[2]ChemischeBerichte,1988,vol.121,p.1151-1158

[3]JournalofChemicalResearch,2004,#2,p.107-110

[4]JournalofChemicalResearch,Miniprint,1981,#9,p.3261-3278

[5]JournaloftheAmericanChemicalSociety,2016,vol.138,#27,p.8344-8347

[1]JournaloftheChemicalSociety,PerkinTransactions2:PhysicalOrganicChemistry(1972-1999),1981,p.1341-1343

Downstream Synthesis Route

[1]Patent:US2887371,1954,

[1]JournaloftheAmericanChemicalSociety,1977,vol.99,p.7613-7622

[1]BulletinoftheAcademyofSciencesoftheUSSRDivisionofChemicalScience,1967,p.2403-2405    IzvestiyaAkademiiNaukSSSR,SeriyaKhimicheskaya,1967,p.2526-2530

[1]JournaloftheChemicalSociety.PerkintransactionsII,1981,p.1341-1343

[1]JournaloftheChemicalSociety.Chemicalcommunications,1991,p.425-426

Literature

Title: [Development of a new method for consecutive activation of conjugated alkynes based on intramolecular silyl migration].

Journal: Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20070801

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SDS
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