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616-38-6,MFCD00008420
Catalog No.:AA0034OB

616-38-6 | Dimethyl carbonate

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  • Technical Information
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0034OB
Chemical Name:
Dimethyl carbonate
CAS Number:
616-38-6
Molecular Formula:
C3H6O3
Molecular Weight:
90.0779
MDL Number:
MFCD00008420
SMILES:
COC(=O)OC
NSC Number:
9371
UN Number:
1161
Properties
Properties
 
BP:
90.5°C  
Form:
Solid  
MP:
2-4 °C(lit.)  
Refractive Index:
n20/D 1.368(lit.)  
Solubility:
139g/l  
Stability:
Moisture Sensitive  
Storage:
Room Temperature;  

Computed Properties
 
Complexity:
44  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
2  
XLogP3:
0.5  

Literature

Title: Covalent triazine frameworks as heterogeneous catalysts for the synthesis of cyclic and linear carbonates from carbon dioxide and epoxides.

Journal: ChemSusChem 20120901

Title: Evaluation of interactive effects on the ionic conduction properties of polymer gel electrolytes.

Journal: The journal of physical chemistry. B 20120823

Title: Enzymatic production of glycerol carbonate from by-product after biodiesel manufacturing process.

Journal: Enzyme and microbial technology 20120810

Title: Synthesis of five-membered cyclic ethers by reaction of 1,4-diols with dimethyl carbonate.

Journal: ChemSusChem 20120801

Title: Thiocarbamide and microwave-accelerated green methylation of cassava starch with dimethyl carbonate.

Journal: Carbohydrate research 20120701

Title: Free-energy and structural analysis of ion solvation and contact ion-pair formation of Li(+) with BF4(-) and PF6(-) in water and carbonate solvents.

Journal: The journal of physical chemistry. B 20120607

Title: On the density scaling of pVT data and transport properties for molecular and ionic liquids.

Journal: The Journal of chemical physics 20120607

Title: Initial solid electrolyte interphase formation process of graphite anode in LiPF6 electrolyte: an in situ ECSTM investigation.

Journal: Physical chemistry chemical physics : PCCP 20120528

Title: Computational mechanistic study of the hydrogenation of carbonate to methanol catalyzed by the Ru(II)PNN complex.

Journal: Inorganic chemistry 20120521

Title: Automated microfluidic platform for studies of carbon dioxide dissolution and solubility in physical solvents.

Journal: Lab on a chip 20120507

Title: 1,3-Dimethyl-1H-indazol-6-amine.

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: A density functional theory investigation on the mechanism and kinetics of dimethyl carbonate formation on Cu2 O catalyst.

Journal: Journal of computational chemistry 20120430

Title: New ruthenium metathesis catalysts with chelating indenylidene ligands: synthesis, characterization and reactivity.

Journal: Dalton transactions (Cambridge, England : 2003) 20120407

Title: Use of dimethyl carbonate as a solvent greatly enhances the biaryl coupling of aryl iodides and organoboron reagents without adding any transition metal catalysts.

Journal: Chemical communications (Cambridge, England) 20120318

Title: Mechanistic investigations on dimethyl carbonate formation by oxidative carbonylation of methanol over a CuY zeolite: an operando SSITKA/DRIFTS/MS study.

Journal: Physical chemistry chemical physics : PCCP 20120221

Title: Impact of sodium polyacrylate on the amorphous calcium carbonate formation from supersaturated solution.

Journal: Langmuir : the ACS journal of surfaces and colloids 20120221

Title: Influence of solute-solvent coordination on the orientational relaxation of ion assemblies in polar solvents.

Journal: The Journal of chemical physics 20120107

Title: Electrochemical performance of NixCo1-xMoO4 (0 ≤ x ≤ 1) nanowire anodes for lithium-ion batteries.

Journal: Nanoscale research letters 20120101

Title: Patterned Si thin film electrodes for enhancing structural stability.

Journal: Nanoscale research letters 20120101

Title: Synthesis and characterization of integrated layered nanocomposites for lithium ion batteries.

Journal: Nanoscale research letters 20120101

Title: Facile synthesis of nano-Li4 Ti5O12 for high-rate Li-ion battery anodes.

Journal: Nanoscale research letters 20120101

Title: Low-temperature synthesis of LiFePO4 nanocrystals by solvothermal route.

Journal: Nanoscale research letters 20120101

Title: Methyl 6-chloro-nicotinate.

Journal: Acta crystallographica. Section E, Structure reports online 20120101

Title: Effect of the leaving group and solvent combination on the LFER reaction constants.

Journal: International journal of molecular sciences 20120101

Title: Activated metallic gold as an agent for direct methoxycarbonylation.

Journal: Journal of the American Chemical Society 20111221

Title: Microscopic structure and dynamics of LiBF4 solutions in cyclic and linear carbonates.

Journal: The journal of physical chemistry. B 20111215

Title: Heat capacities and asymmetric criticality of coexistence curves for benzonitrile + alkanes and dimethyl carbonate + alkanes.

Journal: The journal of physical chemistry. B 20111124

Title: Interdependence of conformational and chemical reaction dynamics during ion assembly in polar solvents.

Journal: The journal of physical chemistry. B 20111006

Title: Tin-based mesoporous silica for the conversion of CO2 into dimethyl carbonate.

Journal: ChemSusChem 20110919

Title: Lipase-catalyzed simultaneous biosynthesis of biodiesel and glycerol carbonate from corn oil in dimethyl carbonate.

Journal: Biotechnology letters 20110901

Title: Microwave-assisted methylation of cassava starch with dimethyl carbonate.

Journal: Carbohydrate research 20110701

Title: Enzymatic coproduction of biodiesel and glycerol carbonate from soybean oil and dimethyl carbonate.

Journal: Enzyme and microbial technology 20110506

Title: Lithium difluoro-(oxalato)borate tetra-methyl-ene sulfone disolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20110501

Title: Protecting group free synthesis of 6-substituted naphthols and binols.

Journal: The Journal of organic chemistry 20110401

Title: [Spectralsignatures of nickel and vanadium supported photocatalysts and their photocatalytic properties].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20110401

Title: Optimizing the weight loss-on-ignition methodology to quantify organic and carbonate carbon of sediments from diverse sources.

Journal: Environmental monitoring and assessment 20110301

Title: N-rich salts of 2-methyl-5-nitraminotetrazole: secondary explosives with low sensitivities.

Journal: Inorganic chemistry 20110221

Title: A novel preparation of methyl-β-cyclodextrin from dimethyl carbonate and β-cyclodextrin.

Journal: Carbohydrate research 20110215

Title: From CO2 to dimethyl carbonate with dialkyldimethoxystannanes: the key role of monomeric species.

Journal: Physical chemistry chemical physics : PCCP 20110214

Title: A convenient and safe O-methylation of flavonoids with dimethyl carbonate (DMC).

Journal: Molecules (Basel, Switzerland) 20110209

Title: Lanthanum(III) isopropoxide catalyzed chemoselective transesterification of dimethyl carbonate and methyl carbamates.

Journal: Organic letters 20110204

Title: Size-differentiated chemical characteristics of Asian paleo dust: records from aeolian deposition on Chinese Loess Plateau.

Journal: Journal of the Air & Waste Management Association (1995) 20110201

Title: Benzodicarbomethoxytetrathiafulvalene derivatives as soluble organic semiconductors.

Journal: The Journal of organic chemistry 20110107

Title: Investigation on the gaseous and particulate emissions of a compression ignition engine fueled with diesel-dimethyl carbonate blends.

Journal: The Science of the total environment 20110101

Title: Low-temperature synthesis of CuO-interlaced nanodiscs for lithium ion battery electrodes.

Journal: Nanoscale research letters 20110101

Title: Investigation on two abnormal phenomena about thermal conductivity enhancement of BN/EG nanofluids.

Journal: Nanoscale research letters 20110101

Title: Sedimentary environment influences the effect of an infaunal suspension feeding bivalve on estuarine ecosystem function.

Journal: PloS one 20110101

Title: Improving sustainability in ene-yne cross-metathesis for transformation of unsaturated fatty esters.

Journal: ChemSusChem 20101122

Title: Biosynthesis of glycerol carbonate from glycerol by lipase in dimethyl carbonate as the solvent.

Journal: Bioprocess and biosystems engineering 20101101

Title: Kinetics of transesterification of palm oil and dimethyl carbonate for biodiesel production at the catalysis of heterogeneous base catalyst.

Journal: Bioresource technology 20101101

Title: [Determination of dimethyl carbonate in air of working places with gas chromatography-mass spectrometry].

Journal: Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases 20100801

Title: Dendritic chain reaction: responsive release of hydrogen peroxide upon generation and enzymatic oxidation of methanol.

Journal: Bioorganic & medicinal chemistry 20100601

Title: Transesterification of cyclic carbonates to dimethyl carbonate using solid oxide catalyst at ambient conditions: environmentally benign synthesis.

Journal: ChemSusChem 20100525

Title: Green synthesis of dimethyl isosorbide.

Journal: ChemSusChem 20100525

Title: Catalytic properties of [Pd(COOMe)(n)X(2-n)(PPh(3))(2)] (n = 0, 1, 2; X = Cl, NO(2), ONO(2), OAc and OTs) in the oxidative carbonylation of MeOH.

Journal: Inorganic chemistry 20100419

Title: Two-step supercritical dimethyl carbonate method for biodiesel production from Jatropha curcas oil.

Journal: Bioresource technology 20100401

Title: 2-Butyl-11-phenyl-5,10-dihydro-1H-benzo[e]imidazo[1,5-a][1,4]diazepine-1,3(2H)-dione.

Journal: Acta crystallographica. Section E, Structure reports online 20100301

Title: Environmentally benign methanolysis of polycarbonate to recover bisphenol A and dimethyl carbonate in ionic liquids.

Journal: Journal of hazardous materials 20100215

Title: 7Li NMR chemical shift titration and theoretical DFT calculation studies: solvent and anion effects on second-order complexation of 12-crown-4 and 1-aza-12-crown-4 with lithium cation in several aprotic solvents.

Journal: Magnetic resonance in chemistry : MRC 20100201

Title: Layered double hydroxide-supported L-methionine-catalyzed chemoselective O-methylation of phenols and esterification of carboxylic acids with dimethyl carbonate: a 'green' protocol.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100125

Title: Gas-phase synthesis of dimethyl carbonate from methanol and carbon dioxide over Co(1.5)PW(12)O(40) Keggin-type heteropolyanion.

Journal: International journal of molecular sciences 20100101

Title: Synthesis and Characterization of Cobalt-Doped WS2 Nanorods for Lithium Battery Applications.

Journal: Nanoscale research letters 20100101

Title: Reactivity of heteropolytungstate and heteropolymolybdate metal transition salts in the synthesis of dimethyl carbonate from methanol and CO₂.

Journal: International journal of molecular sciences 20100101

Title: Theoretical investigations on oxidative stability of solvents and oxidative decomposition mechanism of ethylene carbonate for lithium ion battery use.

Journal: The journal of physical chemistry. B 20091231

Title: An energy dispersive x-ray scattering and molecular dynamics study of liquid dimethyl carbonate.

Journal: The Journal of chemical physics 20091228

Title: Ionic liquids made with dimethyl carbonate: solvents as well as boosted basic catalysts for the michael reaction.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20091116

Title: A molecular dynamics simulation study of LiFePO4/electrolyte interfaces: structure and Li+ transport in carbonate and ionic liquid electrolytes.

Journal: Physical chemistry chemical physics : PCCP 20091114

Title: Kinetics of lithium ion transfer at the interface between graphite and liquid electrolytes: effects of solvent and surface film.

Journal: Langmuir : the ACS journal of surfaces and colloids 20091103

Title: Polarizable force field development and molecular dynamics simulations of ionic liquids.

Journal: The journal of physical chemistry. B 20090820

Title: Low pressure CO(2) to dimethyl carbonate by the reaction with methanol promoted by acetonitrile hydration.

Journal: Chemical communications (Cambridge, England) 20090814

Title: Novel application of thermally expanded graphite as the support of catalysts for direct synthesis of DMC from CH3OH and CO2.

Journal: Journal of colloid and interface science 20090601

Title: Dimethyl carbonate as potential reactant in non-catalytic biodiesel production by supercritical method.

Journal: Bioresource technology 20090301

Title: Quantum chemistry and molecular dynamics simulation study of dimethyl carbonate: ethylene carbonate electrolytes doped with LiPF6.

Journal: The journal of physical chemistry. B 20090212

Title: [Application of IR spectrum to the research on mechanism of synthesis of 2,4-toluene dicarbamate catalyzed by zinc acetate].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20090201

Title: Effects of dimethyl or diethyl carbonate as an additive on volatility and flash point of an aviation fuel.

Journal: Journal of hazardous materials 20090130

Title: Synthesis of dimethyl carbonate by transesterification of ethylene carbonate over activated dawsonites.

Journal: ChemSusChem 20090101

Title: Measurements of OC and EC in coarse particulate matter in the southeastern United States.

Journal: Journal of the Air & Waste Management Association (1995) 20090101

Title: New approaches in the management of chronic hepatitis B: role of tenofovir.

Journal: Infection and drug resistance 20090101

Title: Solid state gas sensor research in Germany - a status report.

Journal: Sensors (Basel, Switzerland) 20090101

Title: Insight into the hard-soft acid-base properties of differently substituted phenylhydrazines in reactions with dimethyl carbonate.

Journal: The journal of physical chemistry. B 20081120

Title: Convenient synthesis of hydroxytyrosol and its lipophilic derivatives from tyrosol or homovanillyl alcohol.

Journal: Journal of agricultural and food chemistry 20081008

Title: In situ observation of the internal structure and composition of biomineralized Emiliania huxleyi calcite by solid-state NMR Spectroscopy.

Journal: Journal of the American Chemical Society 20081008

Title: NMR spectroscopy of citrate in solids: cross-polarization kinetics in weakly coupled systems.

Journal: Magnetic resonance in chemistry : MRC 20080501

Title: Three new polyketide-terpenoid hybrids from Penicillium sp.

Journal: Organic letters 20080306

Title: Reaction of the ambident electrophile dimethyl carbonate with the ambident nucleophile phenylhydrazine.

Journal: The Journal of organic chemistry 20080215

Title: Synthesis of dimethyl carbonate from carbon dioxide catalyzed by titanium alkoxides with polyether-type ligands.

Journal: ChemSusChem 20080101

Title: Dimethyl carbonate: an eco-friendly solvent in ruthenium-catalyzed olefin metathesis transformations.

Journal: ChemSusChem 20080101

Title: Recovery of enlarged olefin metathesis catalysts by nanofiltration in an eco-friendly solvent.

Journal: ChemSusChem 20080101

Title: Composite hybrid membrane of chitosan-silica in pervaporation separation of MeOH/DMC mixtures.

Journal: Journal of colloid and interface science 20071215

Title: Mineralization of CaCO3 in the presence of egg white lysozyme.

Journal: Langmuir : the ACS journal of surfaces and colloids 20071120

Title: Nucleofugality of phenyl and methyl carbonates.

Journal: The Journal of organic chemistry 20071026

Title: Immunotoxicity of carbaryl in chicken.

Journal: Indian journal of experimental biology 20071001

Title: Predicting the reactivity of ambidentate nucleophiles and electrophiles using a single, general-purpose, reactivity indicator.

Journal: Physical chemistry chemical physics : PCCP 20070521

Title: Development of potential manufacturing routes for substituted thiophenes--preparation of halogenated 2-thiophenecarboxylic acid derivatives as building blocks for a new family of 2,6-dihaloaryl 1,2,4-triazole insecticides.

Journal: Beilstein journal of organic chemistry 20070101

Title: Catalysis over zinc-incorporated berlinite (ZnAlPO4) of the methoxycarbonylation of 1,6-hexanediamine with dimethyl carbonate to form dimethylhexane-1,6-dicarbamate.

Journal: Chemistry Central journal 20070101

Title: Synthesis from caffeine of a mixed N-heterocyclic carbene-silver acetate complex active against resistant respiratory pathogens.

Journal: Journal of medicinal chemistry 20061116

Title: The local environment of Cu+ in Cu-Y zeolite and its relationship to the synthesis of dimethyl carbonate.

Journal: The journal of physical chemistry. B 20060622

Title: Mass spectrometry investigations on electrolyte degradation products for the development of nanocomposite electrodes in lithium ion batteries.

Journal: Analytical chemistry 20060601

Title: [Preparation and quantitative analysis of methyl phenyl carbonate standard sample].

Journal: Se pu = Chinese journal of chromatography 20060501

Title: Development of many-body polarizable force fields for Li-battery applications: 2. LiTFSI-doped Oligoether, polyether, and carbonate-based electrolytes.

Journal: The journal of physical chemistry. B 20060330

Title: Correlation of in vitro cytokine responses with the chemical composition of soil-derived particulate matter.

Journal: Environmental health perspectives 20060301

Title: Highly chemoselective methylation and esterification reactions with dimethyl carbonate in the presence of NaY faujasite. The case of mercaptophenols, mercaptobenzoic acids, and carboxylic acids bearing OH substituents.

Journal: The Journal of organic chemistry 20060217

Title: Nanosized amorphous calcium carbonate stabilized by poly(ethylene oxide)-b-poly(acrylic acid) block copolymers.

Journal: Langmuir : the ACS journal of surfaces and colloids 20060214

Title: Development and optimization of a method for analysis of the products from the transesterification of dimethyl carbonate and phenol.

Journal: Analytical and bioanalytical chemistry 20060101

Title: Profiling fatty acids in vegetable oils by reactive pyrolysis-gas chromatography with dimethyl carbonate and titanium silicate.

Journal: Journal of chromatography. A 20051230

Title: New insight into the solid electrolyte interphase with use of a focused ion beam.

Journal: The journal of physical chemistry. B 20051201

Title: Dimethyl carbonate in the supercages of NaY zeolite: the role of local fields in promoting methylation and carboxymethylation activity.

Journal: Angewandte Chemie (International ed. in English) 20050725

Title: Active control of methanol carbonylation selectivity over Au/carbon anode by electrochemical potential.

Journal: The journal of physical chemistry. B 20050512

Title: U-Pb ages from the neoproterozoic Doushantuo Formation, China.

Journal: Science (New York, N.Y.) 20050401

Title: Synthesis of methyl carbamates from primary aliphatic amines and dimethyl carbonate in supercritical CO2: effects of pressure and cosolvents and chemoselectivity.

Journal: The Journal of organic chemistry 20050401

Title: Dimethyl carbonate as an ambident electrophile.

Journal: The Journal of organic chemistry 20050318

Title: Dimethyl carbonate as a novel methylating reagent for fatty acids in analytical pyrolysis.

Journal: Journal of chromatography. A 20050218

Title: [Determination of twenty one elements in lithium hexafluorophosphate by ICP-AES].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20050201

Title: The effect of acidification on the determination of organic carbon, total nitrogen and their stable isotopic composition in algae and marine sediment.

Journal: Rapid communications in mass spectrometry : RCM 20050101

Title: In vivo characterisation of a novel bioresorbable poly(lactide-co-glycolide) tubular foam scaffold for tissue engineering applications.

Journal: Journal of materials science. Materials in medicine 20040601

Title: Selectivity control of carbonylation of methanol to dimethyl oxalate and dimethyl carbonate over gold anode by electrochemical potential.

Journal: Journal of the American Chemical Society 20040505

Title: Reaction of functionalized anilines with dimethyl carbonate over NaY faujasite. 3. chemoselectivity toward mono-N-methylation.

Journal: The Journal of organic chemistry 20030919

Title: Preparation of macroporous biodegradable poly(L-lactide-co-epsilon-caprolactone) foams and characterization by mercury intrusion porosimetry, image analysis, and impedance spectroscopy.

Journal: Journal of biomedical materials research. Part A 20030801

Title: New process for the preparation of methyl carbonates.

Journal: Organic letters 20030501

Title: Synthesis and stability of reactive salts of dodecafluoro-closo-dodecaborate(2-).

Journal: Journal of the American Chemical Society 20030423

Title: CuCl catalyst heterogenized on diamide immobilized SBA-15 for efficient oxidative carbonylation of methanol to dimethylcarbonate.

Journal: Chemical communications (Cambridge, England) 20030407

Title: Reaction of (mu-oxo)diiron(III) core with CO2 in N-methylimidazole: formation of mono(mu-carboxylato)(mu-oxo)diiron(III) complexes with N-methylimidazole as ligands.

Journal: Inorganic chemistry 20030310

Title: Dual nucleophilic catalysis with DABCO for the N-methylation of indoles.

Journal: The Journal of organic chemistry 20030307

Title: 1,3-dimethylimidazolium-2-carboxylate: the unexpected synthesis of an ionic liquid precursor and carbene-CO2 adduct.

Journal: Chemical communications (Cambridge, England) 20030107

Title: The 13C chemical shift tensor principal values and orientations in dialkyl carbonates and trithiocarbonates.

Journal: Solid state nuclear magnetic resonance 20021201

Title: The unusual role of CO transfer in molybdenum-catalyzed asymmetric alkylations.

Journal: Journal of the American Chemical Society 20021030

Title: Direct formation of Ge-C bonds from GeO(2).

Journal: Journal of the American Chemical Society 20021002

Title: [Study on three kinds of gasoline oxygenates-induced DNA damage in mice fibroblasts].

Journal: Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases 20021001

Title: The chemistry of dimethyl carbonate.

Journal: Accounts of chemical research 20020901

Title: Reaction of silicate minerals to form tetramethoxysilane.

Journal: Inorganic chemistry 20020506

Title: Nucleophilic catalysis with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) for the esterification of carboxylic acids with dimethyl carbonate.

Journal: The Journal of organic chemistry 20020405

Title: Carboxylate and alkyl carbonate coordination at the hydrophobic binding site of redox-active dicobalt amine thiophenolate complexes.

Journal: Inorganic chemistry 20020311

Title: Selective mono-C-methylations of arylacetonitriles and arylacetates with dimethylcarbonate: a mechanistic investigation.

Journal: The Journal of organic chemistry 20020222

Title: [Dynamics of microbial processes in the stratal waters of the Romashkinskoe oil field].

Journal: Mikrobiologiia 20020101

Title: 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) and microwave-accelerated green chemistry in methylation of phenols, indoles, and benzimidazoles with dimethyl carbonate.

Journal: Organic letters 20011227

Title: Deoligomerization of siloxanes with dimethyl carbonate over solid-base catalysts.

Journal: Chemical communications (Cambridge, England) 20010921

Title: Dimethylcarbonate for eco-friendly methylation reactions.

Journal: Chemosphere 20010401

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