Home Imidazoles 693-98-1
693-98-1,MFCD00005190
Catalog No.:AA0033BG

693-98-1 | 2-Methylimidazole

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25g
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100g
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  • Technical Information
  • Properties
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Technical Information
Catalog Number:
AA0033BG
Chemical Name:
2-Methylimidazole
CAS Number:
693-98-1
Molecular Formula:
C4H6N2
Molecular Weight:
82.1038
MDL Number:
MFCD00005190
SMILES:
Cc1ncc[nH]1
NSC Number:
21394
Properties
Properties
 
BP:
267°C at 760 mmHg  
Form:
Solid  
MP:
142-143 °C(lit.)  
Refractive Index:
1.4970 (estimate)  
Solubility:
780g/l  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
44.8  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
1  
XLogP3:
0.2  

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Title: H/D isotopic recognition in hydrogen bonded systems: H/D isotopic self-organization effects in the IR spectra of the hydrogen bond in 2-methylimidazole crystals.

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Title: Two different hydrogen bond donor ligands together: a selectivity improvement in organometallic {Re(CO)3} anion hosts.

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Title: New insight into the formation mechanism of imidazolium-based halide salts.

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Title: Modulating the synthetase activity of penicillin G acylase in organic media by addition of N-methylimidazole: using vinyl acetate as activated acyl donor.

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Title: Determination of dihydroxyacetone and glycerol in fermentation process by GC after n-methylimidazole catalyzed acetylation.

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Title: Direct arylation of simple azoles catalyzed by 1,10-phenanthroline containing palladium complexes: an investigation of C4 arylation of azoles and the synthesis of triarylated azoles by sequential arylation.

Journal: The Journal of organic chemistry 20110415

Title: Investigation of non-covalent interaction of ANF promoter DNA and polyamides containing N-methylimidazole and N-methylpyrrole amino acids by electrospray ionization mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20110415

Title: N-heterocyclic carbene catalyzed reaction of phthalaldehydes: controllable stereoselective synthesis of polyhydroxylated spiro- and fused indenones dictated by the structure of NHC catalysts.

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Journal: Inorganic chemistry 20081117

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Title: Rhenium(I) compounds bound by tripodal ligands of pyridine and N-methylimidazole.

Journal: Dalton transactions (Cambridge, England : 2003) 20080721

Title: Reactions of the Re(CO)3(H2O)3(+) synthon with monodentate ligands under aqueous conditions.

Journal: Inorganic chemistry 20080707

Title: Lycopene production using Blakeslea trispora in the presence of 2-methyl imidazole: yield, selectivity, and safety aspects.

Journal: Journal of agricultural and food chemistry 20080625

Title: Induction of thyroid and liver tumors by chronic exposure to 2-methylimidazole in F344/N rats and B6C3F1 mice.

Journal: Archives of toxicology 20080601

Title: Synthesis of silver nanoparticles using hydroxyl functionalized ionic liquids and their antimicrobial activity.

Journal: International journal of molecular sciences 20080501

Title: Pyridine ring opening at room temperature at a rhenium tricarbonyl bipyridine complex.

Journal: Journal of the American Chemical Society 20080430

Title: Density functional theory calculations of the lowest energy quintet and triplet states of model hemes: role of functional, basis set, and zero-point energy corrections.

Journal: The journal of physical chemistry. A 20080424

Title: Discovery, synthesis and biological evaluation of isoquinolones as novel and highly selective JNK inhibitors (2).

Journal: Bioorganic & medicinal chemistry 20080415

Title: Stereospecific synthesis of sugar-1-phosphates and their conversion to sugar nucleotides.

Journal: Carbohydrate research 20080407

Title: Preparation and study of a family of dinuclear Ru(II) complexes that catalyze the decomposition of water.

Journal: Inorganic chemistry 20080317

Title: Synthesis and cytotoxicity studies of new morpholino-functionalised and N-heteroaryl-substituted titanocene anticancer drugs.

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Title: Second-sphere interaction of anions with a weakly binding metal complex host: probing the effect of counteranions.

Journal: Dalton transactions (Cambridge, England : 2003) 20080221

Title: Ru(II) complexes of tetradentate ligands related to 2,9-di(pyrid-2'-yl)-1,10-phenanthroline.

Journal: Inorganic chemistry 20080204

Title: Biochemical markers predictive for bone marrow involvement in systemic mastocytosis.

Journal: Haematologica 20080101

Title: [Determination of emamectin benzoate residue in vegetables by high performance liquid chromatography with fluorescence detection].

Journal: Se pu = Chinese journal of chromatography 20080101

Title: Low frequency spectral density of ferrous heme: perturbations induced by axial ligation and protein insertion.

Journal: Biophysical journal 20071215

Title: A ditopic calix[6]arene ligand with N-methylimidazole and 1,2,3-triazole substituents: synthesis and coordination with Zn(II) cations.

Journal: Organic letters 20071122

Title: Properties of a new 4-imidazolyl derivative of a 14-membered tetraazamacrocyclic chelating agent.

Journal: Dalton transactions (Cambridge, England : 2003) 20071028

Title: Imidazolium-based ionic liquids formed with dicyanamide anion: influence of cationic structure on ionic conductivity.

Journal: The journal of physical chemistry. B 20071025

Title: Analysis of abamectin residues in avocados by high-performance liquid chromatography with fluorescence detection.

Journal: Journal of chromatography. A 20070921

Title: Thermochemical studies of N-methylpyrazole and N-methylimidazole.

Journal: The journal of physical chemistry. A 20070906

Title: Absorption, metabolism, and excretion of [14C]imidafenacin, a new compound for treatment of overactive bladder, after oral administration to healthy male subjects.

Journal: Drug metabolism and disposition: the biological fate of chemicals 20070901

Title: Copper-catalyzed N-arylation of imidazoles and benzimidazoles.

Journal: The Journal of organic chemistry 20070803

Title: Model studies for the thiol-mediated methyl transfer to corrinoids.

Journal: Organic & biomolecular chemistry 20070707

Title: Effect of the N-terminus on heme cavity structure, ligand equilibrium, rate constants, and reduction potentials of nitrophorin 2 from Rhodnius prolixus.

Journal: Biochemistry 20070612

Title: Developing the chemistry of monovalent phosphorus.

Journal: Dalton transactions (Cambridge, England : 2003) 20070521

Title: Manganese(II) tri-tert-butoxysilanethiolate complexes with imidazole-based coligands: a neutral complex with four independent ligands and MNOS2 core (M=Mn) related to the liver alcohol dehydrogenase catalytic center (M=Zn).

Journal: Journal of inorganic biochemistry 20070401

Title: Synthesis and phytotoxicity of new ionic liquids incorporating chiral cations and/or chiral anions.

Journal: Journal of agricultural and food chemistry 20070307

Title: Identification of the reactive intermediates produced upon photolysis of p-azidoacetophenone and its tetrafluoro analogue in aqueous and organic solvents: implications for photoaffinity labeling.

Journal: Biochemistry 20070220

Title: Analytical procedure for determination of the time profile of eprinomectin excretion in sheep faeces.

Journal: Analytical and bioanalytical chemistry 20070201

Title: Tripodal borate ligands from tris(dimethylamino)borane: the first synthesis of a chiral tris(methimazolyl)borate ligand, and the crystal structure of a single diastereomer pseudo-C3-symmetric Ru(II) complex.

Journal: Dalton transactions (Cambridge, England : 2003) 20070128

Title: N-methylimidazole significantly improves lipase-catalysed acylation of ribavirin.

Journal: Chemical communications (Cambridge, England) 20070121

Title: Bile acid sequestrants and the treatment of type 2 diabetes mellitus.

Journal: Drugs 20070101

Title: Systematic regulation of the enzymatic activity of phenylacetaldoxime dehydratase by exogenous ligands.

Journal: Chembiochem : a European journal of chemical biology 20061201

Title: Synthesis and biological properties of sequence-specific DNA-alkylating pyrrole-imidazole polyamides.

Journal: Accounts of chemical research 20061201

Title: Studies on antimicrobial activity of cobalt(III) ethylenediamine complexes.

Journal: Canadian journal of microbiology 20061201

Title: Redox infrared markers of the heme and axial ligands in microperoxidase: Bases for the analysis of c-type cytochromes.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20061001

Title: Site-selective DNA cleavage by a novel complex of copper-conjugate of Phen and polyamide containing N-methylimidazole rings.

Journal: Bioorganic & medicinal chemistry letters 20061001

Title: Synthesis, characterization, and in vitro evaluation of novel ruthenium(II) eta6-arene imidazole complexes.

Journal: Journal of medicinal chemistry 20060907

Title: High-performance liquid chromatographic method for the determination of ivermectin in plasma.

Journal: The Southeast Asian journal of tropical medicine and public health 20060901

Title: Dynamic solvation in imidazolium-based ionic liquids on short time scales.

Journal: The journal of physical chemistry. A 20060810

Title: Pd(0) supported onto monolithic polymers containing IL-like moieties. Continuous flow catalysis for the Heck reaction in near-critical EtOH.

Journal: Chemical communications (Cambridge, England) 20060807

Title: Models of the cytochromes: crystal structures and EPR spectral characterization of low-spin bis-imidazole complexes of (OETPP)Fe(III) having intermediate ligand plane dihedral angles.

Journal: Inorganic chemistry 20060710

Title: Reaction of azole heterocycles with tris(dimethylamino)borane, a new method for the construction of tripodal borate-centred ligands.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060705

Title: DNA sequence recognition by an imidazole-containing isopropyl-substituted thiazole polyamide (thiazotropsin B).

Journal: Bioorganic & medicinal chemistry letters 20060701

Title: Catalytic C-H arylation of SEM-protected azoles with palladium complexes of NHCs and phosphines.

Journal: Organic letters 20060511

Title: Microsphere-based protease assays and screening application for lethal factor and factor Xa.

Journal: Cytometry. Part A : the journal of the International Society for Analytical Cytology 20060501

Title: A non-heme dinuclear iron(II) complex containing a single, unsupported hydroxo bridge.

Journal: Chemical communications (Cambridge, England) 20060428

Title: Liquid chromatographic assay of ivermectin in human plasma for application to clinical pharmacokinetic studies.

Journal: Journal of pharmaceutical and biomedical analysis 20060303

Title: Induction of thyroid lesions in 14-week toxicity studies of 2 and 4-methylimidazole in Fischer 344/N rats and B6C3F1 mice.

Journal: Archives of toxicology 20060301

Title: Synthesis and photo-induced DNA cleaving activities of conjugates of halophenyl derivative and polyamide containing N-methylimidazoles.

Journal: Journal of photochemistry and photobiology. B, Biology 20060301

Title: Syntheses and quadratic optical nonlinearities of ruthenium(II) complexes with ethynyl-connected N-methylpyridinium electron acceptors.

Journal: Inorganic chemistry 20060206

Title: Investigation of noncovalent complexes between beta-cyclodextrin and polyamide acids containing N-methylpyrrole and N-methylimidazole by electrospray ionization mass spectrometry.

Journal: Journal of the American Society for Mass Spectrometry 20060101

Title: Human serum albumin hybrid incorporating tailed porphyrinatoiron(II) in the alpha,alpha,alpha,beta-conformer as an O2-binding site.

Journal: Bioconjugate chemistry 20060101

Title: Amino-catalyzed fragmentation characteristics of polyamides containing N-methylpyrrole and N-methylimidazole by electrospray negative ionization mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20060101

Title: Letter: Influence of experimental conditions on electrospray ionization mass spectrometry of ferrocenylalkylazoles.

Journal: European journal of mass spectrometry (Chichester, England) 20060101

Title: Efficacy of topical cobalt chelate CTC-96 against adenovirus in a cell culture model and against adenovirus keratoconjunctivitis in a rabbit model.

Journal: BMC ophthalmology 20060101

Title: Spectroscopic characterization of hydroxide and aqua complexes of Fe(II)-protoheme, structural models for the axial coordination of the atypical heme of membrane cytochrome b6f complexes.

Journal: Journal of the American Chemical Society 20051221

Title: Catalytic reaction mechanism of homogentisate dioxygenase: a hybrid DFT study.

Journal: Journal of the American Chemical Society 20051214

Title: An improved method for the synthesis of nucleoside triphosphate analogues.

Journal: The Journal of organic chemistry 20051209

Title: Chiral zirconium catalysts using multidentate BINOL derivatives for catalytic enantioselective Mannich-type reactions; ligand optimization and approaches to elucidation of the catalyst structure.

Journal: Journal of the American Chemical Society 20051109

Title: Anti-thyroid drugs and thyroid hormone synthesis: effect of methimazole derivatives on peroxidase-catalyzed reactions.

Journal: Journal of the American Chemical Society 20051102

Title: Blue and near-UV phosphorescence from iridium complexes with cyclometalated pyrazolyl or N-heterocyclic carbene ligands.

Journal: Inorganic chemistry 20051031

Title: Catalytic conjugate additions of carbonyl anions under neutral aqueous conditions.

Journal: Journal of the American Chemical Society 20051026

Title: A regularized and renormalized electrostatic coupling Hamiltonian for hybrid quantum-mechanical-molecular-mechanical calculations.

Journal: The Journal of chemical physics 20051022

Title: Heme carbonyls: environmental effects on nu(C-O) and Fe-C/C-O bond length correlations.

Journal: Journal of the American Chemical Society 20051019

Title: Simple chip-based interfaces for on-line monitoring of supramolecular interactions by nano-ESI MS.

Journal: Lab on a chip 20051001

Title: NMR and theoretical study on the coordination and solution structures of the interaction between diperoxovanadate complexes and histidine-like ligands.

Journal: Inorganic chemistry 20050919

Title: Studies on electrochemical oxidation mechanisms of polyamides containing N-methylpyrrole and N-methylimidazole by electrospray ionization tandem mass spectrometry.

Journal: The journal of physical chemistry. B 20050915

Title: Dual catalyst control in the enantioselective intramolecular Morita-Baylis-Hillman reaction.

Journal: Organic letters 20050901

Title: Copper(II) complexes of tridentate pyridylmethylethylenediamines: role of ligand steric hindrance on DNA binding and cleavage.

Journal: Journal of inorganic biochemistry 20050801

Title: Ligand orientation control in low-spin six-coordinate (porphinato)iron(II) species.

Journal: Inorganic chemistry 20050613

Title: Electrospray negative ionization mass spectrometry of polyamides containing N-methylpyrrole and N-methylimidazole.

Journal: Journal of mass spectrometry : JMS 20050501

Title: Formation of a mutagenic heterocyclic aromatic amine from creatinine in urine of meat eaters and vegetarians.

Journal: Chemical research in toxicology 20050301

Title: Thermodynamic profiles for CO photodissociation from heme model compounds: effect of proximal ligands.

Journal: Inorganic chemistry 20050221

Title: [MnIII2 (5-Rsaltmen)2NiII(pao)2(L)]2+: an S(T)=3 building block for a single-chain magnet that behaves as a single-molecule magnet.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050218

Title: Analysis of noncovalent complexes between human telomeric DNA and polyamides containing N-methylpyrrole and N-methylimidazole by using electrospray ionization mass spectrometry.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050204

Title: Effect of MCI-196 (colestilan) as a phosphate binder on hyperphosphataemia in aemodialysis patients: a double-blind, placebo-controlled, short-term trial.

Journal: Nephrology, dialysis, transplantation : official publication of the European Dialysis and Transplant Association - European Renal Association 20050201

Title: Charge donation to and dearomatization of benzene attending complexation: DFT estimates of binding energies of TpMXO(L) with benzene, for Tp = hydridotris(pyrazolyl) borate, MXO = MoNO, ReCO, and WNO, and L = ammonia, N-methylimidazole, pyridine, phosphine, methyl isocyanide, and carbon monoxide.

Journal: Journal of computational chemistry 20050130

Title: From model compounds to protein binding: syntheses, characterizations and fluorescence studies of [RuII(bipy)(terpy)L]2+ complexes (bipy = 2,2'-bipyridine; terpy = 2,2':6',2''-terpyridine; L = imidazole, pyrazole and derivatives, cytochrome c).

Journal: Dalton transactions (Cambridge, England : 2003) 20050121

Title: Epididymal sperm granuloma induced by chronic administration of 2-methylimidazole in B6C3F1 mice.

Journal: Toxicologic pathology 20050101

Title: Synthesis and biological evaluation of 2',3'-didehydro-2',3'-dideoxy-9-deazaguanosine, a monophosphate prodrug and two analogues, 2',3'-dideoxy-9-deazaguanosine and 2',3'-didehydro-2',3'-dideoxy-9-deazainosine.

Journal: Nucleosides, nucleotides & nucleic acids 20050101

Title: [New therapy strategies in secondary hyperparathyroidism on dialysis (I): new concepts, new treatments].

Journal: Nefrologia : publicacion oficial de la Sociedad Espanola Nefrologia 20050101

Title: Colestilan, a new bile acid-sequestering resin, reduces bodyweight in postmenopausal women who have dieted unsuccessfully.

Journal: Drugs in R&D 20050101

Title: Toxicology and carcinogensis studies of 2-methylimidazole (Cas No. 693-98-1) in B6C3F1 mice (feed studies).

Journal: National Toxicology Program technical report series 20041201

Title: Stereoselective tandem 1,4-addition reactions for benzenes: a comparison of Os(II), Re(I), and W(0) systems.

Journal: Journal of the American Chemical Society 20041027

Title: The first Cu(I)-mediated nucleophilic trifluoromethylation reactions using (trifluoromethyl)trimethylsilane in ionic liquids.

Journal: Organic & biomolecular chemistry 20041007

Title: Iron(III) complexes of sterically hindered tetradentate monophenolate ligands as functional models for catechol 1,2-dioxygenases: the role of ligand stereoelectronic properties.

Journal: Inorganic chemistry 20041004

Title: Oligonucleotide--minor groove binder 1:2 conjugates: side by side parallel minor groove binder motif in stabilization of DNA duplex.

Journal: Nucleosides, nucleotides & nucleic acids 20041001

Title: Cyclohexene oxide/CO2 copolymerization catalyzed by chromium(III) salen complexes and N-methylimidazole: effects of varying salen ligand substituents and relative cocatalyst loading.

Journal: Inorganic chemistry 20040920

Title: Reactions of antimicrobial species to imidazole-microwave plasma reacted poly(dimethylsiloxane) surfaces.

Journal: Langmuir : the ACS journal of surfaces and colloids 20040914

Title: Rapid biomonitoring of heterocyclic aromatic amines in human urine by tandem solvent solid phase extraction liquid chromatography electrospray ionization mass spectrometry.

Journal: Chemical research in toxicology 20040801

Title: Study on reactions of 2-(dinitromethylene)-4,5-imidazolidinedione.

Journal: The Journal of organic chemistry 20040625

Title: Proximal and distal influences on ligand binding kinetics in microperoxidase and heme model compounds.

Journal: Biochemistry 20040608

Title: Oligonucleotide-minor groove binder conjugates and their complexes with complementary DNA: effect of conjugate structural factors on the thermal stability of duplexes.

Journal: Nucleosides, nucleotides & nucleic acids 20040501

Title: Adenosylcobinamide plus exogenous, sterically hindered, putative axial bases: a reinvestigation into the cause of record levels of Co-C heterolysis.

Journal: Inorganic chemistry 20040419

Title: Phase I and pharmacokinetic study of irinotecan in combination with R115777, a farnesyl protein transferase inhibitor.

Journal: British journal of cancer 20040419

Title: Formation and stability of N-heterocyclic carbenes in water: the carbon acid pKa of imidazolium cations in aqueous solution.

Journal: Journal of the American Chemical Society 20040407

Title: Biology of N-methylpyrrole-N-methylimidazole hairpin polyamide.

Journal: Biological & pharmaceutical bulletin 20040401

Title: NTP technical report on the toxicity studies of 2- and 4-Methylimidazole (CAS No. 693-98-1 and 822-36-6) administered in feed to F344/N rats and B6C3F1 mice.

Journal: Toxicity report series 20040401

Title: [Synthesis and spectral properties of tailed sercine tetraphenylporphyrin cobalt complex].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20040401

Title: (Salen)CrIIIX catalysts for the copolymerization of carbon dioxide and epoxides: role of the initiator and cocatalyst.

Journal: Inorganic chemistry 20040322

Title: Effect of methylimidazole-induced hypothyroidism in a model of low retinal neovascular incidence.

Journal: Investigative ophthalmology & visual science 20040301

Title: Creatinine determination in serum by capillary electrophoresis.

Journal: Electrophoresis 20040201

Title: Electrospray ionization mass spectral fragmentation mechanisms of DNA-recognizing polyamides containing N-methylpyrrole and N-methylimidazol.

Journal: Rapid communications in mass spectrometry : RCM 20040101

Title: Electrospray ionization mass spectrometric analysis of noncovalent complexes between DNA and polyamides containing N-methylpyrrole and N-methylimidazole.

Journal: Rapid communications in mass spectrometry : RCM 20040101

Title: Energy dissipation processes of singlet-excited 1-hydroxyfluorenone and its hydrogen-bonded complex with N-methylimidazole.

Journal: Photochemistry and photobiology 20040101

Title: Electrospray ionization mass spectral characteristics and fragmentation mechanisms of novel photoinduced DNA-cleaving agents formed as conjugates of haloarenes and polyamides containing N-methylimidazole.

Journal: Rapid communications in mass spectrometry : RCM 20040101

Title: Cross-species hybridisation of human and bovine orthologous genes on high density cDNA microarrays.

Journal: BMC genomics 20040101

Title: [Mn2(saltmen)2Ni(pao)2(L)2](A)2 with L=pyridine, 4-picoline, 4-tert-butylpyridine, N-methylimidazole and A=ClO4-, BF4-, PF6-, ReO4-: a family of single-chain magnets.

Journal: Inorganic chemistry 20031215

Title: Identification of human glutaminyl cyclase as a metalloenzyme. Potent inhibition by imidazole derivatives and heterocyclic chelators.

Journal: The Journal of biological chemistry 20031212

Title: A new family of spin crossover complexes with a tripod ligand containing three imidazoles: synthesis, characterization, and magnetic properties of [FeIIH3LMe](NO3)2.1.5H2O, [FeIIILMe].3.5H2O, [FeIIH3LMe][FeIILMe]NO3, and [FeIIH3LMe][FeIIILMe](NO3)2 (H3LMe) = Tris[2-(((2-methylimidazol-4-yl)methylidene)amino)ethyl]amine).

Journal: Inorganic chemistry 20031103

Title: Nonplanar distortions of bis-base low-spin iron(II)-porphyrinates: absorption and resonance Raman investigations of cross-trans-linked iron(II)-basket-handle porphyrin complexes.

Journal: Journal of the American Chemical Society 20030924

Title: Quaternary salts containing the pentafluorosulfanyl (SF5) group.

Journal: Inorganic chemistry 20030922

Title: Synthesis and in vitro pharmacology of novel heterocyclic muscarinic ligands.

Journal: Farmaco (Societa chimica italiana : 1989) 20030901

Title: Non-degradative dissolution and acetylation of ball-milled plant cell walls: high-resolution solution-state NMR.

Journal: The Plant journal : for cell and molecular biology 20030801

Title: DNA binding hairpin polyamides with antifungal activity.

Journal: Chemistry & biology 20030701

Title: Induced fit process in the selective distal binding of imidazoles in zinc(II) porphyrin receptors.

Journal: Inorganic chemistry 20030616

Title: Solid-State 67Zn NMR spectroscopic studies and ab initio molecular orbital calculations on a synthetic analogue of carbonic anhydrase.

Journal: Journal of the American Chemical Society 20030402

Title: Oxovanadium(IV) and -(V) complexes of dithiocarbazate-based tridentate Schiff base ligands: syntheses, structure, and photochemical reactivity of compounds involving imidazole derivatives as coligands.

Journal: Inorganic chemistry 20030310

Title: Reaction of (mu-oxo)diiron(III) core with CO2 in N-methylimidazole: formation of mono(mu-carboxylato)(mu-oxo)diiron(III) complexes with N-methylimidazole as ligands.

Journal: Inorganic chemistry 20030310

Title: Assignment of heme resonances and determination of the electronic structures of high- and low-spin nitrophorin 2 by 1H and 13C NMR spectroscopy: an explanation of the order of heme methyl resonances in high-spin ferriheme proteins.

Journal: Biochemistry 20030128

Title: Effects of a nonplanar porphyrin rings on the spin-spin interactions in low-spin ferric porphyrin radical cationst.

Journal: Chemical communications (Cambridge, England) 20030121

Title: Kinetic isotope effects for concerted multiple proton transfer: a direct dynamics study of an active-site model of carbonic anhydrase II.

Journal: Journal of the American Chemical Society 20030108

Title: Ultraviolet spectrophotometric characterization of copper(II) complexes with imidazole N-methyl derivatives of L-histidine in aqueous solution.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20030101

Title: Fragmentation mechanisms of polyamides containing N-methylpyrrole and N-methylimidazole by electrospray ionization tandem mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20030101

Title: Fmoc solid-phase synthesis and its application to pyrrole-imidazole polyamides.

Journal: Nucleic acids research. Supplement (2001) 20030101

Title: Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons.

Journal: Journal of the American Chemical Society 20021106

Title: Paramagnetic resonance in imidazolate-bridged homobinuclear (copper-copper) and heterobinuclear (copper-zinc) complexes.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20021101

Title: Treatment of children with familial hypercholesterolemia with colestilan, a newly developed bile acid-binding resin.

Journal: Atherosclerosis 20021001

Title: Synthesis of polyamides containing N-methylpyrrole and N-methylimidazole and their anticancer activity.

Journal: Archives of pharmacal research 20021001

Title: Ionic liquid-coated enzyme for biocatalysis in organic solvent.

Journal: The Journal of organic chemistry 20020920

Title: Biomimetic oxidation of 2-methylimidazole derivative with a chemical model system for cytochrome P-450.

Journal: Chemical & pharmaceutical bulletin 20020801

Title: Liquid chromatographic assay of moxidectin in human plasma for application to pharmacokinetic studies.

Journal: Journal of pharmaceutical and biomedical analysis 20020731

Title: Structure of a beta-alanine-linked polyamide bound to a full helical turn of purine tract DNA in the 1:1 motif.

Journal: Journal of molecular biology 20020628

Title: Toxicokinetics of 2-methylimidazole in male and female F344 rats.

Journal: Journal of toxicology and environmental health. Part A 20020628

Title: Cycloaddition reactions of dihapto-coordinated furans.

Journal: Journal of the American Chemical Society 20020626

Title: Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst.

Journal: Journal of the American Chemical Society 20020605

Title: Control of cytochrome C redox potential: axial ligation and protein environment effects.

Journal: Journal of the American Chemical Society 20020515

Title: Biomimetic studies of terminal oxidases: trisimidazole picket metalloporphyrins.

Journal: Inorganic chemistry 20020422

Title: Ligand-modulated stereo- and regioselective tandem addition reactions of rhenium-bound naphthalene.

Journal: Journal of the American Chemical Society 20020403

Title: Spectroscopic studies on human serum albumin and methemalbumin: optical, steady-state, and picosecond time-resolved fluorescence studies, and kinetics of substrate oxidation by methemalbumin.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20020301

Title: Crystal structure of F65A/Y131C-methylimidazole carbonic anhydrase V reveals architectural features of an engineered proton shuttle.

Journal: Biochemistry 20020226

Title: Electrospray ionization tandem mass spectrometric characteristics and fragmentation mechanisms of distamycin analogues.

Journal: Rapid communications in mass spectrometry : RCM 20020101

Title: Mapping nucleotide binding site of calcium ATPase with IR spectroscopy: effects of ATP gamma-phosphate binding.

Journal: Biopolymers 20020101

Title: Silacyclic derivatives of heteroaromatic sulfides as selective cholesterol level lowering and vasodilating agents.

Journal: Metal-based drugs 20020101

Title: Structure-spectroscopy correlation in distorted five-coordinate Cu(II) complexes: a case study with a set of closely related copper complexes of pyridine-2,6-dicarboxamide ligands.

Journal: Inorganic chemistry 20011231

Title: Kinetic study of the hydrolysis of phthalic anhydride and aryl hydrogen phthalates.

Journal: The Journal of organic chemistry 20011116

Title: Determination of emamectin residues in the tissues of Atlantic salmon (Salmo salar L.) using HPLC with fluorescence detection.

Journal: Journal of agricultural and food chemistry 20011101

Title: Extraction and isolation of avermectins and milbemycins from liver samples using unmodified supercritical CO2 with in-line trapping on basic alumina.

Journal: Journal of chromatography. B, Biomedical sciences and applications 20010915

Title: Chromium(III)-promoted C(2) isotopic H-exchange in coordinated N-methylimidazole: exceptionally rapid or slow and normal?

Journal: Journal of the American Chemical Society 20010822

Title: Molecular structures and magnetic resonance spectroscopic investigations of highly distorted six-coordinate low-spin iron(III) porphyrinate complexes.

Journal: Journal of the American Chemical Society 20010711

Title: Autoxidation of substituted phenols catalyzed by cobalt Schiff base complexes in supercritical carbon dioxide.

Journal: Inorganic chemistry 20010702

Title: Cavitand zn(II)-porphyrin capsules with high affinities for pyridines and N-methylimidazole.

Journal: The Journal of organic chemistry 20010601

Title: Development and optimisation of an improved derivatisation procedure for the determination of avermectins and milbemycins in bovine liver.

Journal: The Analyst 20010501

Title: Fmoc solid phase synthesis of polyamides containing pyrrole and imidazole amino acids.

Journal: Organic letters 20010419

Title: Thermodynamic and kinetic studies on the reaction between the vitamin B12 derivative beta-(N-methylimidazolyl)cobalamin and N-methylimidazole: ligand displacement at the alpha axial site of cobalamins.

Journal: Inorganic chemistry 20010326

Title: RNase activity of a DNA minor groove binder with a minimalist catalytic motif from RNase A.

Journal: Biochemical and biophysical research communications 20010301

Title: Amplification of bleomycin-induced DNA cleavage at cytosine residues 3' to GGG sequences by pyrrole triamide.

Journal: Biochemical pharmacology 20010201

Title: Kinetic consequences of covalent linkage of DNA binding polyamides.

Journal: Biochemistry 20010109

Title: Alternative heterocycles for DNA recognition: an N-methylpyrazole/N-methylpyrrole pair specifies for A.T/T.A base pairs.

Journal: Bioorganic & medicinal chemistry 20010101

Title: Determination of selamectin in dog plasma by high performance liquid chromatography with automated solid phase extraction and fluorescence detection.

Journal: Veterinary research 20010101

Title: Improved method for determination of abamectin and ivermectin in cattle plasma.

Journal: Journal of AOAC International 20010101

Title: [Synthesis of cholesterol-containing cationic amphiphiles with heterocyclic bases].

Journal: Bioorganicheskaia khimiia 20010101

Application
2-Methylimidazole serves as a versatile compound with diverse applications in materials synthesis and catalysis. Its roles include functioning as a coordination regulator in the fabrication of 2D metal-organic framework-5 (MOF-5) nanosheets, which exhibit efficient catalytic activity in Knoevenagel condensation reactions. Additionally, it acts as an alkaline inducer in the synthesis of amorphous FeCoNi ternary hydroxide nanosheets, serving as active electrocatalysts for the oxygen evolution reaction. Furthermore, it is utilized as a solvent system, often combined with water, in the synthesis of zeolitic imidazolate frameworks-8 (ZIF-8) membranes, demonstrating potential applications in gas separation processes. Overall, 2-methylimidazole's multifunctional properties contribute significantly to advancements in various fields, ranging from catalysis to materials science.
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Tags:693-98-1 Molecular Formula|693-98-1 MDL|693-98-1 SMILES|693-98-1 2-Methylimidazole |Organic_Building_Blocks