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7688-25-7,MFCD00003051
Catalog No.:AA0032JI

7688-25-7 | 1,4-Bis(diphenylphosphino)butane

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5g
97%
in stock  
$6.00   $4.00
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10g
97%
in stock  
$7.00   $5.00
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25g
97%
in stock  
$14.00   $10.00
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100g
98%
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$28.00   $19.00
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  • Technical Information
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0032JI
Chemical Name:
1,4-Bis(diphenylphosphino)butane
CAS Number:
7688-25-7
Molecular Formula:
C28H28P2
Molecular Weight:
426.4694
MDL Number:
MFCD00003051
SMILES:
C(CP(c1ccccc1)c1ccccc1)CCP(c1ccccc1)c1ccccc1
Properties
Properties
 
Form:
Solid  
MP:
132-136 °C(lit.)  
Storage:
Room Temperature;  

Computed Properties
 
Complexity:
362  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
30  
Rotatable Bond Count:
9  
XLogP3:
6.6  

Literature

Title: Mechanism of the Pd-catalyzed decarboxylative allylation of α-imino esters: decarboxylation via free carboxylate ion.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20121105

Title: Direct substitution of primary allylic amines with sulfinate salts.

Journal: Journal of the American Chemical Society 20120912

Title: Synthesis, spectral, thermal, X-ray single crystal of new RuCl₂(dppb)diamine complexes and their application in hydrogenation of Cinnamic aldehyde.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120901

Title: Correlation between photophysical parameters and gold-gold distances in gold(I) (4-pyridyl)ethynyl complexes.

Journal: Inorganic chemistry 20120716

Title: cis-[1,4-Bis(diphenyl-phosphan-yl)butane-κ(2)P,P']dichlorido(cyclo-hexane-1,2-diamine-κ(2)N,N')ruthenium(II) dichloro-methane monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: Ruthenium(II) phosphine/diimine/picolinate complexes: inorganic compounds as agents against tuberculosis.

Journal: European journal of medicinal chemistry 20111001

Title: Gold(I) complexes bearing mixed-donor ligands derived from N-heterocyclic carbenes.

Journal: Dalton transactions (Cambridge, England : 2003) 20110707

Title: Syntheses and structures of ruthenium(II) N,S-heterocyclic carbene diphosphine complexes and their catalytic activity towards transfer hydrogenation.

Journal: Chemistry, an Asian journal 20110606

Title: [1,4-Bis(diphenyl-phosphan-yl)butane-κP,P']chlorido(η-inden-yl)ruthenium(II).

Journal: Acta crystallographica. Section E, Structure reports online 20110501

Title: Reactions of a gold(I) thiolate complex [Au(Tab)(2)](2)(PF(6))(2) (Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20110121

Title: Synthesis of symmetrical and unsymmetrical diarylalkynes from propiolic acid using palladium-catalyzed decarboxylative coupling.

Journal: The Journal of organic chemistry 20100917

Title: Ruthenium-catalyzed oxidation of alcohols into amides.

Journal: Organic letters 20090618

Title: Palladium-catalyzed decarboxylative coupling of alkynyl carboxylic acids and aryl halides.

Journal: The Journal of organic chemistry 20090206

Title: μ-1,4-Bis(diphenyl-phosphino-yl)butane-κO:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-κO)tin(IV).

Journal: Acta crystallographica. Section E, Structure reports online 20080601

Title: Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates.

Journal: Dalton transactions (Cambridge, England : 2003) 20071221

Title: Mixed-ligand organometallic polymers containing the 'Pd(2)(dmb)2(2+)' fragment: properties of the [Pd2(dmb)2(diphos)2+](n) polymers/oligomers in solution and in the solid state.

Journal: Inorganic chemistry 20040823

Title: Preparation and solid-state characterization of mixed-ligand coordination/organometallic oligomers and polymers of copper(I) and silver(I) using diphosphine and mono- and diisocyanide ligands.

Journal: Inorganic chemistry 20040517

Title: A trichloro-bridged binuclear ruthenium complex with 1,1,1-tris(diphenylphosphinomethyl)ethane.

Journal: Acta crystallographica. Section C, Crystal structure communications 20031101

Title: Progress in the palladium-catalyzed cyanation of aryl chlorides.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20030414

Title: Gold(I) macrocycles and topologically chiral [2]catenanes.

Journal: Journal of the American Chemical Society 20020417

Title: Self-assembly of rings, catenanes, and a doubly braided catenane containing gold(I): the hinge-group effect in diacetylide ligands.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20010817

Title: Rate and mechanism of the reversible formation of cationic (eta3-allyl)-palladium complexes in the oxidative addition of allylic acetate to palladium(0) complexes ligated by diphosphanes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20010316

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