Home Other Building Blocks 7688-25-7
7688-25-7,MFCD00003051
Catalog No.:AA0032JI
7688-25-7 | 1,4-Bis(diphenylphosphino)butane
Pack Size
Purity
Availability
Price(USD)
Quantity
  
5g
95%
in stock  
$9.00   $6.00
- +
25g
97%
in stock  
$28.00   $20.00
- +
100g
97%
in stock  
$100.00   $70.00
- +
500g
97%
in stock  
$445.00   $311.00
- +
  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
  • Q & A
  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0032JI
Chemical Name:
1,4-Bis(diphenylphosphino)butane
CAS Number:
7688-25-7
Molecular Formula:
C28H28P2
Molecular Weight:
426.4694
MDL Number:
MFCD00003051
IUPAC Name:
4-diphenylphosphanylbutyl(diphenyl)phosphane
InChI:
InChI=1S/C28H28P2/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-12,15-22H,13-14,23-24H2
InChI Key:
BCJVBDBJSMFBRW-UHFFFAOYSA-N
SMILES:
C(CP(c1ccccc1)c1ccccc1)CCP(c1ccccc1)c1ccccc1
EC Number:
231-698-7
UNII:
35HP6LTD2D
Properties
Computed Properties
 
Complexity:
362  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
426.167g/mol
Formal Charge:
0
Heavy Atom Count:
30  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
426.48g/mol
Monoisotopic Mass:
426.167g/mol
Rotatable Bond Count:
9  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
6.6  

Synonyms
 
1,4-Bis(diphenylphosphino)butane 
7688-25-7 
4-diphenylphosphanylbutyl(diphenyl)phosphane 
B1246 
BUTANE-1,4-DIYLBIS[DIPHENYLPHOSPHINE] 
1,4-Bis(diphenylphosphino)butane, 98% - 1G 1g 
812-01-1 
BCJVBDBJSMFBRW-UHFFFAOYSA-N 
1,4-bis-(diphenylphosphino)butane 
Butane-1,4-diylbis(diphenylphosphine) 
Phosphine, 1,4-butanediylbis(diphenyl- 
1,4-BIS(DIPHENYLPHOSPHINE)BUTANE 
1,4-Bis(diphenylphosphino)butane, 98% 
1,4-Bis(diphenylphosphino)butane (DPPB) 
1,4-BUTYLENEBIS(DIPHENYLPHOSPHINE) 
1,4-BUTANEDIYLBIS[DIPHENYLPHOSPHINE] 
dppb 
4-di(phenyl)phosphanylbutyl-di(phenyl)phosphane 
Phosphine, 1,1'-(1,4-butanediyl)bis(1,1-diphenyl- 
Phosphine, 1,1'-(1,4-butanediyl)bis[1,1-diphenyl- 
EINECS 231-698-7 
PubChem6481 
AC1Q7DPI 
AC1L32SP 
AC1Q28UA 
ACMC-1BC63 
SCHEMBL29179 
Phosphine, 1,4-butanediylbis[diphenyl- 
KSC372Q3D 
CHEMBL71648 
1,4-bisdiphenylphosphinobutane 
1,4-bis(diphenylphospino)butane 
DTXSID4064769 
BCJVBDBJSMFBRW-UHFFFAOYSA- 
KS-00000EPJ 
Bis(1,4-diphenylphosphino)butane 
1,4-bis(diphenylphosphanyl)butane 
1,4-bis(di-phenylphosphino)butane 
1,4-Bis[diphenylphosphino]butane 
1,4-bis(diphenyl phosphino)butane 
1,4-Bis(diphenyl-phosphino)butane 
ACN-S004491 
ACT02855 
BCP22582 
ZINC2140922 
1,4-bis-(diphenylphosphino) butane 
1,4-bis-(diphenylphosphino)-butane 
ANW-36908 
CB-614 
UNII-35HP6LTD2D 
RW2167 
AKOS004908986 
AC-4222 
CS-W007569 
GC10108 
GS-3096 
LS41023 
RP17238 
RTC-040033 
1,4-Bis(diphenylphosphino)butane(DPPB) 
[4-(diphenylphosphanyl)butyl]diphenylphosphane 
AK-73015 
AN-12205 
BC219559 
BP-10035 
BR-73015 
K886 
SC-44936 
SY009758 
AB0007434 
DB-009458 
MFCD00003051 
TC-040033 
FT-0606800 
ST24026774 
M-5160 
36607-EP2269993A1 
36607-EP2299785A1 
36607-EP2306788A1 
36607-EP2306789A1 
36607-EP2308857A1 
36607-EP2308926A1 
Tetramethylenebis(diphenylphosphine) 
36607-EP2311801A1 
36607-EP2311802A1 
36607-EP2311803A1 
36607-EP2371814A1 
36607-EP2377841A1 
MFCD00003051 (97+%) 
[4-(Diphenylphosphino)butyl](diphenyl)phosphine # 
688B257 
W-104340 
InChI=1/C28H28P2/c1-5-15-25(16-6-1)29(26-17-7-2-8-18-26)23-13-14-24-30(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-12,15-22H,13-14,23-24H2 
35HP6LTD2D 
1,4-bis butane 
C28H28P2 
KST-1B8731 
1, 4-Bis(diphenylphosphino)butane 
CID82124 
AR-1B7621 
Phosphine, tetramethylenebis[diphenyl- 
ACN-031927 
C28-H28-P2 
1,4-Bis(diphenylphosphino)butane, 98% 1g 
Literature

Title: Mechanism of the Pd-catalyzed decarboxylative allylation of α-imino esters: decarboxylation via free carboxylate ion.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20121105

Title: Direct substitution of primary allylic amines with sulfinate salts.

Journal: Journal of the American Chemical Society 20120912

Title: Synthesis, spectral, thermal, X-ray single crystal of new RuCl₂(dppb)diamine complexes and their application in hydrogenation of Cinnamic aldehyde.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120901

Title: Correlation between photophysical parameters and gold-gold distances in gold(I) (4-pyridyl)ethynyl complexes.

Journal: Inorganic chemistry 20120716

Title: cis-[1,4-Bis(diphenyl-phosphan-yl)butane-κ(2)P,P']dichlorido(cyclo-hexane-1,2-diamine-κ(2)N,N')ruthenium(II) dichloro-methane monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: Ruthenium(II) phosphine/diimine/picolinate complexes: inorganic compounds as agents against tuberculosis.

Journal: European journal of medicinal chemistry 20111001

Title: Gold(I) complexes bearing mixed-donor ligands derived from N-heterocyclic carbenes.

Journal: Dalton transactions (Cambridge, England : 2003) 20110707

Title: Syntheses and structures of ruthenium(II) N,S-heterocyclic carbene diphosphine complexes and their catalytic activity towards transfer hydrogenation.

Journal: Chemistry, an Asian journal 20110606

Title: [1,4-Bis(diphenyl-phosphan-yl)butane-κP,P']chlorido(η-inden-yl)ruthenium(II).

Journal: Acta crystallographica. Section E, Structure reports online 20110501

Title: Reactions of a gold(I) thiolate complex [Au(Tab)(2)](2)(PF(6))(2) (Tab = 4-(trimethylammonio)benzenethiolate) with diphosphine ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20110121

Title: Synthesis of symmetrical and unsymmetrical diarylalkynes from propiolic acid using palladium-catalyzed decarboxylative coupling.

Journal: The Journal of organic chemistry 20100917

Title: Ruthenium-catalyzed oxidation of alcohols into amides.

Journal: Organic letters 20090618

Title: Palladium-catalyzed decarboxylative coupling of alkynyl carboxylic acids and aryl halides.

Journal: The Journal of organic chemistry 20090206

Title: μ-1,4-Bis(diphenyl-phosphino-yl)butane-κO:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-κO)tin(IV).

Journal: Acta crystallographica. Section E, Structure reports online 20080601

Title: Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates.

Journal: Dalton transactions (Cambridge, England : 2003) 20071221

Title: Mixed-ligand organometallic polymers containing the 'Pd(2)(dmb)2(2+)' fragment: properties of the [Pd2(dmb)2(diphos)2+](n) polymers/oligomers in solution and in the solid state.

Journal: Inorganic chemistry 20040823

Title: Preparation and solid-state characterization of mixed-ligand coordination/organometallic oligomers and polymers of copper(I) and silver(I) using diphosphine and mono- and diisocyanide ligands.

Journal: Inorganic chemistry 20040517

Title: A trichloro-bridged binuclear ruthenium complex with 1,1,1-tris(diphenylphosphinomethyl)ethane.

Journal: Acta crystallographica. Section C, Crystal structure communications 20031101

Title: Progress in the palladium-catalyzed cyanation of aryl chlorides.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20030414

Title: Gold(I) macrocycles and topologically chiral [2]catenanes.

Journal: Journal of the American Chemical Society 20020417

Title: Self-assembly of rings, catenanes, and a doubly braided catenane containing gold(I): the hinge-group effect in diacetylide ligands.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20010817

Title: Rate and mechanism of the reversible formation of cationic (eta3-allyl)-palladium complexes in the oxidative addition of allylic acetate to palladium(0) complexes ligated by diphosphanes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20010316

Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Additional Info:
Q & A