Home Fluorides 82113-65-3
82113-65-3,MFCD00214154
Catalog No.:AA0034GE

82113-65-3 | Trifluoromethanesulfonimide

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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0034GE
Chemical Name:
Trifluoromethanesulfonimide
CAS Number:
82113-65-3
Molecular Formula:
C2HF6NO4S2
Molecular Weight:
281.1541
MDL Number:
MFCD00214154
SMILES:
FC(S(=O)(=O)NS(=O)(=O)C(F)(F)F)(F)F
Properties
Properties
 
BP:
190.5°C at 760 mmHg  
Form:
Solid  
MP:
52-56 °C  
Solubility:
800g/l Risk of violent reaction.  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
374  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
15  
Hydrogen Bond Acceptor Count:
11  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
2  
XLogP3:
1.3  

Literature

Title: Characterization of conducting cellulose acetate based polymer electrolytes doped with 'green' ionic mixture.

Journal: Carbohydrate polymers 20130102

Title: Trimethylaluminum-triflimide complexes for the catalysis of highly hindered Diels-Alder reactions.

Journal: Organic letters 20121019

Title: Extraction of cupric ions with ionic liquids containing polypyridine-type small molecules or peripherally pyridine-modified dendrimers.

Journal: Chemistry, an Asian journal 20121001

Title: Synthesis of highly substituted oxazoles through iodine(III)-mediated reactions of ketones with nitriles.

Journal: Molecules (Basel, Switzerland) 20120913

Title: Triflimide-catalyzed allyl-allyl cross-coupling: a metal-free allylic alkylation.

Journal: Chemical communications (Cambridge, England) 20120907

Title: Structure-based tuning of T(m) in lipid-like ionic liquids. Insights from Tf2N- salts of gene transfection agents.

Journal: Chemical communications (Cambridge, England) 20120804

Title: Photodetachment and electron reactivity in 1-methyl-1-butyl-pyrrolidinium bis(trifluoromethylsulfonyl)amide.

Journal: The Journal of chemical physics 20120721

Title: Effect of ionic liquid on the determination of aromatic amines as contaminants in hair dyes by liquid chromatography coupled to electrochemical detection.

Journal: Molecules (Basel, Switzerland) 20120702

Title: In situ electrochemical SFG/DFG study of CN- and nitrile adsorption at Au from 1-butyl-1-methyl-pyrrolidinium bis(trifluoromethylsulfonyl) amide ionic liquid([BMP][TFSA]) containing 4-{2-[1-(2-cyanoethyl)-1,2,3,4-tetrahydroquinolin-6-yl]diazenyl} benzonitrile (CTDB) and K[Au(CN)₂].

Journal: Molecules (Basel, Switzerland) 20120625

Title: Effects of lithium salts on shear relaxation spectra of pyrrolidinium-based ionic liquids.

Journal: The journal of physical chemistry. B 20120621

Title: Click ionic liquids: a family of promising tunable solvents and application in Suzuki-Miyaura cross-coupling.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120618

Title: A comparison of phosphorus and fluorine containing IL lubricants for steel on aluminium.

Journal: Physical chemistry chemical physics : PCCP 20120614

Title: High efficiency graphene solar cells by chemical doping.

Journal: Nano letters 20120613

Title: Polymeric imidazolium ionic liquids as valuable stationary phases in gas chromatography: chemical synthesis and full characterization.

Journal: Analytica chimica acta 20120406

Title: The effect of different interfaces and confinement on the structure of the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide entrapped in cationic and anionic reverse micelles.

Journal: Physical chemistry chemical physics : PCCP 20120314

Title: Cage lifetimes of ionic liquids as studied by the magnetic field effect probe.

Journal: Physical chemistry chemical physics : PCCP 20120314

Title: Thermal behaviour and electrochemical properties of bis(trifluoromethanesulfonyl)amide and dodecatungstosilicate viologen dimers.

Journal: Physical chemistry chemical physics : PCCP 20120227

Title: Comparison between cycloalkyl- and n-alkyl-substituted imidazolium-based ionic liquids in physicochemical properties and reorientational dynamics.

Journal: The journal of physical chemistry. B 20120223

Title: Molecular dynamics simulation studies of the interactions between ionic liquids and amino acids in aqueous solution.

Journal: The journal of physical chemistry. B 20120216

Title: Phase-transfer behavior of cross-linked poly(acrylic acid) particles prepared by dispersion polymerization from ionic liquid to water.

Journal: Langmuir : the ACS journal of surfaces and colloids 20120207

Title: Mechanisms and rules of anion partition into ionic liquids: phenolate ions in ionic liquid/water biphasic systems.

Journal: The journal of physical chemistry. B 20120119

Title: Electron solvation dynamics and reactivity in ionic liquids observed by picosecond radiolysis techniques.

Journal: Faraday discussions 20120101

Title: Physicochemical and acid-base properties of a series of 2-hydroxyethylammonium-based protic ionic liquids.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20120101

Title: Facile isomerization of silyl enol ethers catalyzed by triflic imide and its application to one-pot isomerization-(2 + 2) cycloaddition.

Journal: Beilstein journal of organic chemistry 20120101

Title: Thermal properties of ionic systems near the liquid-liquid critical point.

Journal: The Journal of chemical physics 20111207

Title: Ionic liquids as internal phase for non-aqueous polyHIPEs.

Journal: Macromolecular rapid communications 20111201

Title: Temperature- and pH-triggered reversible transfer of doubly responsive hairy particles between water and a hydrophobic ionic liquid.

Journal: Langmuir : the ACS journal of surfaces and colloids 20111101

Title: Liquid structure of and Li+ ion solvation in bis(trifluoromethanesulfonyl)amide based ionic liquids composed of 1-ethyl-3-methylimidazolium and N-methyl-N-propylpyrrolidinium cations.

Journal: The journal of physical chemistry. B 20111027

Title: Evaluation of a medium-polarity ionic liquid stationary phase in the analysis of flavor and fragrance compounds.

Journal: Analytical chemistry 20111015

Title: High-accuracy vapor pressure data of the extended [C(n)C1im][Ntf2] ionic liquid series: trend changes and structural shifts.

Journal: The journal of physical chemistry. B 20110922

Title: Microscopic aspects in dicationic ionic liquids through the low-frequency spectra by femtosecond Raman-induced Kerr effect spectroscopy.

Journal: The journal of physical chemistry. B 20110922

Title: Nuclear magnetic resonance studies on the rotational and translational motions of ionic liquids composed of 1-ethyl-3-methylimidazolium cation and bis(trifluoromethanesulfonyl)amide and bis(fluorosulfonyl)amide anions and their binary systems including lithium salts.

Journal: The Journal of chemical physics 20110828

Title: Improved classical united-atom force field for imidazolium-based ionic liquids: tetrafluoroborate, hexafluorophosphate, methylsulfate, trifluoromethylsulfonate, acetate, trifluoroacetate, and bis(trifluoromethylsulfonyl)amide.

Journal: The journal of physical chemistry. B 20110825

Title: Oxidative-stability enhancement and charge transport mechanism in glyme-lithium salt equimolar complexes.

Journal: Journal of the American Chemical Society 20110824

Title: The effect of neat ionic liquid on the folding of short peptides.

Journal: Chemical communications (Cambridge, England) 20110728

Title: Anisotropic proton-conductive materials formed by the self-organization of phosphonium-type zwitterions.

Journal: Advanced materials (Deerfield Beach, Fla.) 20110719

Title: Properties of ionic liquids containing silver(I) or protic alkylethylenediamine cations with a bis(trifluoromethanesulfonyl)amide anion.

Journal: Journal of colloid and interface science 20110415

Title: Low-melting zwitterion: effect of oxyethylene units on thermal properties and conductivity.

Journal: Chemical communications (Cambridge, England) 20110227

Title: Temperature-dependent structure of methyltributylammonium bis(trifluoromethylsulfonyl)amide: X ray scattering and simulations.

Journal: The Journal of chemical physics 20110214

Title: High-performance supercapacitors based on poly(ionic liquid)-modified graphene electrodes.

Journal: ACS nano 20110125

Title: Molecular assembly-assisted biocatalytic reactions in ionic liquids.

Journal: Methods in molecular biology (Clifton, N.J.) 20110101

Title: Formal (3+3) cycloaddition of silyl enol ethers catalyzed by trifric imide: domino Michael addition-claisen condensation accompanied with isomerization of silyl enol ethers.

Journal: Chemical & pharmaceutical bulletin 20110101

Title: Nitrile functionalized methimazole-based ionic liquids.

Journal: The Journal of organic chemistry 20101217

Title: The structure of geminal imidazolium bis(trifluoromethylsulfonyl)amide ionic liquids: a theoretical study of the gas phase ionic complexes.

Journal: The journal of physical chemistry. A 20101202

Title: Molecular simulations of CO2 and H2 sorption into ionic liquid 1-n-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([hmim][Tf2N]) confined in carbon nanotubes.

Journal: The journal of physical chemistry. B 20101125

Title: Transparent organic p-dopant in carbon nanotubes: bis(trifluoromethanesulfonyl)imide.

Journal: ACS nano 20101123

Title: Auto-tandem catalysis: facile synthesis of substituted alkylidenecyclohexanones by domino (4+2) cycloaddition-elimination reaction.

Journal: Chemical communications (Cambridge, England) 20101121

Title: Studies on the translational and rotational motions of ionic liquids composed of N-methyl-N-propyl-pyrrolidinium (P13) cation and bis(trifluoromethanesulfonyl)amide and bis(fluorosulfonyl)amide anions and their binary systems including lithium salts.

Journal: The Journal of chemical physics 20101121

Title: Preparation, properties, and crystal structures of organometallic ionic liquids comprising 1-ferrocenyl-3-alkylimidazolium-based salts of bis(trifluoromethanesulfonyl)amide and hexafluorophosphate.

Journal: Inorganic chemistry 20101101

Title: Effects of the alkyl-chain length on the mixing state of imidazolium-based ionic liquid-methanol solutions.

Journal: Physical chemistry chemical physics : PCCP 20101014

Title: Mass spectrometric characterization of metal triflates and triflimides (Lewis superacid catalysts) by electrospray ionization and tandem mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20100915

Title: Enzymatic synthesis of caffeic acid phenethyl ester analogues in ionic liquid.

Journal: Journal of biotechnology 20100720

Title: Shear relaxation of imidazolium-based room-temperature ionic liquids.

Journal: The journal of physical chemistry. B 20100624

Title: Role of cation symmetry in intermolecular structure and dynamics of room temperature ionic liquids: simulation studies.

Journal: The journal of physical chemistry. B 20100520

Title: Molecular simulations and experimental studies of solubility and diffusivity for pure and mixed gases of H2, CO2, and Ar absorbed in the ionic liquid 1-n-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([hmim][Tf2N]).

Journal: The journal of physical chemistry. B 20100520

Title: Microscopic study of ionic liquid-H2O systems: alkyl-group dependence of 1-alkyl-3-methylimidazolium cation.

Journal: The journal of physical chemistry. B 20100520

Title: Raman spectroscopic studies and ab initio calculations on conformational isomerism of 1-butyl-3-methylimidazolium bis-(trifluoromethanesulfonyl)amide solvated to a lithium ion in ionic liquids: effects of the second solvation sphere of the lithium ion.

Journal: The journal of physical chemistry. B 20100520

Title: Preparation of poly(acrylic acid) particles by dispersion polymerization in an ionic liquid.

Journal: Langmuir : the ACS journal of surfaces and colloids 20100504

Title: Do solvation layers of ionic liquids influence electrochemical reactions?

Journal: Physical chemistry chemical physics : PCCP 20100227

Title: Plasma electrochemistry in ionic liquids: deposition of copper nanoparticles.

Journal: Physical chemistry chemical physics : PCCP 20100227

Title: On the electrodeposition of tantalum from three different ionic liquids with the bis(trifluoromethyl sulfonyl) amide anion.

Journal: Physical chemistry chemical physics : PCCP 20100227

Title: Reactions of excited-state benzophenone ketyl radical in a room-temperature ionic liquid.

Journal: Physical chemistry chemical physics : PCCP 20100227

Title: The solubility parameters of ionic liquids.

Journal: International journal of molecular sciences 20100101

Title: Stability of a Ag/AgCl reference electrode equipped with an ionic liquid salt bridge composed of 1-methyl-3-octylimidazolium bis(trifluoromethanesulfonyl)-amide in potentiometry of pH standard buffers.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20100101

Title: Comparison of interionic/intermolecular vibrational dynamics between ionic liquids and concentrated electrolyte solutions.

Journal: The Journal of chemical physics 20091228

Title: In situ STM investigation of the lithium underpotential deposition on Au(111) in the air- and water-stable ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide.

Journal: Physical chemistry chemical physics : PCCP 20091221

Title: Thermal and transport properties of ionic liquids based on benzyl-substituted phosphonium cations.

Journal: The journal of physical chemistry. B 20091203

Title: Slightly viscous amino acid ionic liquids: synthesis, properties, and calculations.

Journal: The journal of physical chemistry. B 20091119

Title: Molecular dynamics simulations of the liquid surface of the ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide: structure and surface tension.

Journal: The journal of physical chemistry. B 20091105

Title: Physical and electrochemical properties of thioether-functionalized ionic liquids.

Journal: The journal of physical chemistry. B 20090813

Title: New insight into the nanostructure of ionic liquids: a small angle X-ray scattering (SAXS) study on liquid tri-alkyl-methyl-ammonium bis(trifluoromethanesulfonyl)amides and their mixtures.

Journal: Physical chemistry chemical physics : PCCP 20090714

Title: Crystal structure, vibrational spectroscopy and ab initio density functional theory calculations on the ionic liquid forming 1,1,3,3-tetramethylguanidinium bis{(trifluoromethyl)sulfonyl}amide.

Journal: The journal of physical chemistry. B 20090702

Title: Direct measurements of ionic mobility of ionic liquids using the electric field applying pulsed gradient spin-echo NMR.

Journal: The journal of physical chemistry. B 20090625

Title: Relationships between center atom species (N, P) and ionic conductivity, viscosity, density, self-diffusion coefficient of quaternary cation room-temperature ionic liquids.

Journal: Physical chemistry chemical physics : PCCP 20090514

Title: New insights into the fundamental chemical nature of ionic liquid film formation on magnesium alloy surfaces.

Journal: ACS applied materials & interfaces 20090501

Title: Is bis(trifluoromethylsulfonyl)amide an innocent anion? X-ray structure data and DFT calculations.

Journal: Dalton transactions (Cambridge, England : 2003) 20090421

Title: Cryogenic neon matrix-isolation FTIR spectroscopy of evaporated ionic liquids: geometrical structure of cation-anion 1:1 pair in the gas phase.

Journal: The journal of physical chemistry. B 20090409

Title: Bridging the gap between ionic liquids and molten salts: group 1 metal salts of the bistriflamide anion in the gas phase.

Journal: The journal of physical chemistry. B 20090319

Title: Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20090221

Title: Biocatalysis in water-in-ionic liquid microemulsions: a case study with horseradish peroxidase.

Journal: Langmuir : the ACS journal of surfaces and colloids 20090120

Title: A catalytic method for the preparation of polysubstituted cyclopentanes: [3+2] cycloaddition of vinylidenecyclopropanes with activated olefins catalyzed by triflic imide.

Journal: The Journal of organic chemistry 20090116

Title: An experimental and theoretical study of the aluminium species present in mixtures of AlCl3 with the ionic liquids [BMP]Tf2N and [EMIm]Tf2N.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20090101

Title: Zinc-mediated formation of trifluoromethyl ethers from alcohols and hypervalent iodine trifluoromethylation reagents.

Journal: Angewandte Chemie (International ed. in English) 20090101

Title: Molecular simulation and regular solution theory modeling of pure and mixed gas absorption in the ionic liquid 1-n-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([hmim][Tf2N]).

Journal: The journal of physical chemistry. B 20081225

Title: Aggregation behavior of octyl viologen di[bis(trifluoromethanesulfonyl)amide] in nonpolar solvents.

Journal: The journal of physical chemistry. B 20081225

Title: Molecular motions and ion diffusions of the room-temperature ionic liquid 1,2-dimethyl-3-propylimidazolium bis(trifluoromethylsulfonyl)amide (DMPImTFSA) studied by 1H, 13C, and 19F NMR.

Journal: The journal of physical chemistry. A 20081127

Title: Distribution of 1-alkyl-3-methylimidazolium ions and their ion pairs between dichloromethane and water.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20081001

Title: Solvation of lithium ion in N,N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl)-amide using Raman and multinuclear NMR spectroscopy.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20081001

Title: Raman spectroscopic study on alkaline metal ion solvation in 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ionic liquid.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20081001

Title: Solvation structures of some transition metal(II) ions in a room-temperature ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20081001

Title: Isothermogravimetric determination of the enthalpies of vaporization of 1-alkyl-3-methylimidazolium ionic liquids.

Journal: The journal of physical chemistry. B 20080821

Title: Quaternary ammonium room-temperature ionic liquid including an oxygen atom in side chain/lithium salt binary electrolytes: ab initio molecular orbital calculations of interactions between ions.

Journal: The journal of physical chemistry. B 20080814

Title: (2+2) cycloaddition reaction of alkyl enol ethers with acrylates by in situ generated silyl triflic imide catalyst.

Journal: Chemical & pharmaceutical bulletin 20080801

Title: Lewis super-acid catalyzed cyclizations: a new route to fragrance compounds.

Journal: Chemistry & biodiversity 20080601

Title: Application of mutually immiscible ionic liquids to the separation of aromatic and aliphatic hydrocarbons by liquid extraction: a preliminary approach.

Journal: Physical chemistry chemical physics : PCCP 20080514

Title: On the electrodeposition of titanium in ionic liquids.

Journal: Physical chemistry chemical physics : PCCP 20080428

Title: Exploring 12'-apo-beta-carotenoic-12'-acid as an ultrafast polarity probe for ionic liquids.

Journal: The journal of physical chemistry. B 20080313

Title: Solubility of tetrafluoromethane in the ionic liquid [hmim][Tf2N].

Journal: The journal of physical chemistry. B 20080313

Title: A tale of two ions: the conformational landscapes of bis(trifluoromethanesulfonyl)amide and N,N-dialkylpyrrolidinium.

Journal: The journal of physical chemistry. B 20080207

Title: Quaternary ammonium room-temperature ionic liquid including an oxygen atom in side chain/lithium salt binary electrolytes: ionic conductivity and 1H, 7Li, and 19F NMR studies on diffusion coefficients and local motions.

Journal: The journal of physical chemistry. B 20080131

Title: Electrodeposition of Al in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ionic liquids: in situ STM and EQCM studies.

Journal: The journal of physical chemistry. B 20070510

Title: Temperature-dependent electronic and vibrational structure of the 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide room-temperature ionic liquid surface: a study with XPS, UPS, MIES, and HREELS.

Journal: The journal of physical chemistry. B 20070510

Title: Using XPS to determine solute solubility in room temperature ionic liquids.

Journal: The Analyst 20070301

Title: An unusual stereoselectivity in the anomeric substitution with carbamates promoted by HNTf2.

Journal: Organic & biomolecular chemistry 20070207

Title: Stepwise acid-promoted double-Michael process: an alternative to Diels-Alder cycloadditions for hindered silyloxydiene-dienophile pairs.

Journal: Organic letters 20070118

Title: Unexpected reduction pathway of a Co(2+) salt to [HCo(CO)(4)] via [Co(2)(CO)(8)] in an ionic liquid.

Journal: Dalton transactions (Cambridge, England : 2003) 20070114

Title: Liquid structure of the ionic liquid 1,3-dimethylimidazolium bis[(trifluoromethyl)sulfonyl]amide.

Journal: The journal of physical chemistry. B 20060622

Title: Pyrazolyl-functionalized 2-methylimidazolium-based ionic liquids and their palladium(II) complexes as recyclable catalysts.

Journal: Organic & biomolecular chemistry 20060521

Title: Chemical capacitance of nanoporous-nanocrystalline TiO2 in a room temperature ionic liquid.

Journal: Physical chemistry chemical physics : PCCP 20060421

Title: Nanostructural organization in ionic liquids.

Journal: The journal of physical chemistry. B 20060223

Title: Chiral ionic liquid that functions as both solvent and chiral selector for the determination of enantiomeric compositions of pharmaceutical products.

Journal: Analytical chemistry 20060215

Title: Triflimide (HNTf2)-catalyzed aldehyde cross-aldol reaction using 'super silyl' enol ethers.

Journal: Nature protocols 20060101

Title: Volatile solvent-free solid-state polymer-sensitized TiO2 solar cells with poly(3,4-ethylenedioxythiophene) as a hole-transporting medium.

Journal: Chemical communications (Cambridge, England) 20050507

Title: Fluorescence and CD spectroscopic analysis of the alpha-chymotrypsin stabilization by the ionic liquid, 1-ethyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]amide.

Journal: Biotechnology and bioengineering 20041230

Title: Metal bis[trifluoromethyl)sulfonyl]amide complexes: highly efficient Friedel-Crafts acylation catalysts.

Journal: Chemical communications (Cambridge, England) 20040621

Title: The first (ferrocenylmethyl)imidazolium and (ferrocenylmethyl)triazolium room temperature ionic liquids.

Journal: Inorganic chemistry 20040531

Title: Solvent extraction of sr2+ and cs+ based on room-temperature ionic liquids containing monoaza-substituted crown ethers.

Journal: Analytical chemistry 20040515

Title: Low melting inorganic salts of alkyl-, fluoroalkyl-, alkyl ether-, and fluoroalkyl ether-substituted oxazolidine and morpholine.

Journal: Inorganic chemistry 20040503

Title: Kinetic resolution of rac-2-pentanol catalyzed by Candida antarctica lipase B in the ionic liquid, 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]amide.

Journal: Biotechnology letters 20040201

Title: Triflimide activation of a chiral oxazaborolidine leads to a more general catalytic system for enantioselective Diels-Alder addition.

Journal: Journal of the American Chemical Society 20030528

Title: Brønsted acid-base ionic liquids and their use as new materials for anhydrous proton conductors.

Journal: Chemical communications (Cambridge, England) 20030421

Title: EXAFS investigations of the mechanism of facilitated ion transfer into a room-temperature ionic liquid.

Journal: Journal of the American Chemical Society 20020911

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Tags:82113-65-3 Molecular Formula|82113-65-3 MDL|82113-65-3 SMILES|82113-65-3 Trifluoromethanesulfonimide