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84783-64-2,MFCD03094574
Catalog No.:AA003F77

84783-64-2 | 2,2'-Bis(diphenylphosphino)-1,1'-biphenyl

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100mg
>98.0%(GC)
in stock  
$34.00   $24.00
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250mg
98%
in stock  
$57.00   $40.00
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1g
98%
in stock  
$143.00   $100.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003F77
Chemical Name:
2,2'-Bis(diphenylphosphino)-1,1'-biphenyl
CAS Number:
84783-64-2
Molecular Formula:
C36H28P2
Molecular Weight:
522.5550
MDL Number:
MFCD03094574
SMILES:
c1ccc(cc1)P(c1ccccc1c1ccccc1P(c1ccccc1)c1ccccc1)c1ccccc1
Properties
Properties
 
Form:
Solid  
MP:
210-214 °C  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
573  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
38  
Rotatable Bond Count:
7  
XLogP3:
8.9  

Downstream Synthesis Route

[1]Uehara,Akira;Bailar,JohnC.[JournalofOrganometallicChemistry,1982,vol.239,#1,p.1-10]

[1]Bennett,MartinA.;Bhargava,SureshK.;Griffiths,DavidK.;Robertson,GlenB.[AngewandteChemie,1987,vol.99,#3,p.262-264]

[1]Mikami,Koichi;Aikawa,Kohsuke;Korenaga,Toshinobu[OrganicLetters,2001,vol.3,#2,p.243-245]

[2]Desponds,Olivier;Schlosser,Manfred[JournalofOrganometallicChemistry,1996,vol.507,#1-2,p.257-261]

[1]Mikami,Koichi;Aikawa,Kohsuke;Korenaga,Toshinobu[OrganicLetters,2001,vol.3,#2,p.243-245]

[1]Mikami,Koichi;Aikawa,Kohsuke;Korenaga,Toshinobu[OrganicLetters,2001,vol.3,#2,p.243-245]

Literature

Title: Chiral 1,1'-binaphthyl-2,2'-dithiol-stabilized gold clusters: size separation and optical activity in the UV-vis.

Journal: Chirality 20080301

Title: An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides.

Journal: Organic letters 20020516

Title: Asymmetric catalysis with the normally unresolvable, conformationally dynamic 2,2'-bis(diphenylphosphino)-1,1'-biphenyl (biphep).

Journal: Journal of the American Chemical Society 20010926

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