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123237-62-7,MFCD01862148
Catalog No.:AA000K4C

123237-62-7 | (S)-Glycidoxy-t-butyldimethylsilane

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
95%
in stock  
$14.00   $10.00
- +
5g
97%
in stock  
$54.00   $38.00
- +
25g
97%
in stock  
$128.00   $90.00
- +
100g
97%
in stock  
$411.00   $288.00
- +
500g
97%
in stock  
$1,607.00   $1,125.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA000K4C
Chemical Name:
(S)-Glycidoxy-t-butyldimethylsilane
CAS Number:
123237-62-7
Molecular Formula:
C9H20O2Si
Molecular Weight:
188.3394
MDL Number:
MFCD01862148
SMILES:
CC([Si](OC[C@H]1OC1)(C)C)(C)C
Properties
Properties
 
BP:
209.088°C at 760 mmHg  
Form:
Liquid  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
160  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
1  
Heavy Atom Count:
12  
Hydrogen Bond Acceptor Count:
2  
Rotatable Bond Count:
4  

Downstream Synthesis Route

[1]Locationinpatent:schemeortablePospisil,Jiri;Mueller,Christoph;Fuerstner,Alois[Chemistry-AEuropeanJournal,2009,vol.15,#24,p.5956-5968]

[2]Locationinpatent:experimentalpartZaed,AhmedM.;Sutherland,Andrew[OrganicandBiomolecularChemistry,2011,vol.9,#23,p.8030-8037]

[3]Winkler,JeremyW.;Uddin,Jasim;Serhan,CharlesN.;Petasis,NicosA.[OrganicLetters,2013,vol.15,#7,p.1424-1427]

[4]CurrentPatentAssignee:UNIVERSITYOFSOUTHERNCALIFORNIA-WO2014/130894,2014,A1Locationinpatent:Page/Pagecolumn41

[5]Lai,Ming-tain;Oh,Eugene;Shih,Younan;Liu,Hung-wen[JournalofOrganicChemistry,1992,vol.57,#8,p.2471-2476]

[6]Zaed,AhmedM.;Sutherland,Andrew[OrganicandBiomolecularChemistry,2010,vol.8,#19,p.4394-4399]

[7]Withall,DavidM.;Haynes,StuartW.;Challis,GregoryL.[JournaloftheAmericanChemicalSociety,2015,vol.137,#24,p.7889-7897]

[8]Bold,ChristianP.;Klaus,Cindy;Pfeiffer,Bernhard;Schurmann,Jasmine;Lombardi,Rafael;Lucena-Agell,Daniel;Diaz,J.Fernando;Altmann,Karl-Heinz[OrganicLetters,2021,vol.23,#6,p.2238-2242]

[9]Wang,Jian-Chao;Just,George[JournalofOrganicChemistry,1999,vol.64,#22,p.8090-8097]

[10]Gamble,MarkP.;Studley,JohnR.;Wills,Martin[TetrahedronAsymmetry,1996,vol.7,#11,p.3071-3074]

[11]CurrentPatentAssignee:BETTAPHARMACEUTICALSCOLTD-WO2022/52886,2022,A1Locationinpatent:Page/Pagecolumn18

[12]Sato,Manabu;Azuma,Hiroki;Daigaku,Akihiro;Sato,Sota;Takasu,Kiyosei;Okano,Kentaro;Tokuyama,Hidetoshi[AngewandteChemie-InternationalEdition,2017,vol.56,#4,p.1087-1091][Angew.Chem.,2017,vol.56,p.1107-1111]

[13]Fujiwara,Kenshu;Amano,Seiji;Oka,Takahiro;Murai,Akio[ChemistryLetters,1994,#11,p.2147-2150]

[14]Manabe,Shino[ChemicalCommunications,1997,#8,p.737-738]

[15]Hubbs,JedL.;Heathcock,ClaytonH.[JournaloftheAmericanChemicalSociety,2003,vol.125,#42,p.12836-12843]

[16]Wang,Liang;Menche,Dirk[AngewandteChemie-InternationalEdition,2012,vol.51,#37,p.9425-9427]

[17]Morita,Masao;Ohmori,Ken;Suzuki,Keisuke[OrganicLetters,2015,vol.17,#22,p.5634-5637]

[18]CurrentPatentAssignee:MERCK&COINC-WO2009/140163,2009,A1Locationinpatent:Page/Pagecolumn56-57

[1]Locationinpatent:experimentalpartZaed,AhmedM.;Sutherland,Andrew[OrganicandBiomolecularChemistry,2011,vol.9,#23,p.8030-8037]

[2]Manabe,Shino[ChemicalCommunications,1997,#8,p.737-738]

[1]Wang,Jian-Chao;Just,George[JournalofOrganicChemistry,1999,vol.64,#22,p.8090-8097]

7051-16-3   
tert-butyldimethylsilyl(S)-glycidylether 
  257299-90-4 

[1]AngewandteChemie-InternationalEdition,1999,vol.38,p.3530-3533

CASUnavailable 
  123237-62-7    259856-84-3 

[1]Haddad,Mansour;Larcheveque,Marc[TetrahedronAsymmetry,1999,vol.10,#21,p.4231-4237]

Literature
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Tags:123237-62-7 Molecular Formula|123237-62-7 MDL|123237-62-7 SMILES|123237-62-7 (S)-Glycidoxy-t-butyldimethylsilane