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1833-51-8,MFCD00040858
Catalog No.:AA0027ES

1833-51-8 | Chloromethyldimethylphenylsilane

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Purity
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250mg
97%
in stock  
$6.00   $4.00
- +
5g
97%
in stock  
$21.00   $15.00
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25g
97%
in stock  
$96.00   $68.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA0027ES
Chemical Name:
Chloromethyldimethylphenylsilane
CAS Number:
1833-51-8
Molecular Formula:
C9H13ClSi
Molecular Weight:
184.7380
MDL Number:
MFCD00040858
SMILES:
ClC[Si](c1ccccc1)(C)C
NSC Number:
155366
Properties
Properties
 
BP:
223.8°C at 760 mmHg  
Form:
Liquid  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
117  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
11  
Rotatable Bond Count:
2  

Downstream Synthesis Route
1719-57-9   
phenylmagnesiumbromide 
  1833-51-8 

[1]Carleer,Robert;Anteunis,MarcJ.O.[OrganicMagneticResonance,1980,vol.13,#4,p.253-258]

[2]Sommeretal.[JournaloftheAmericanChemicalSociety,1949,vol.71,p.1509]

[3]Pola,J.etal.[CollectionofCzechoslovakChemicalCommunications,1973,vol.38,p.1522-1527]

[4]Bourne,A.J.;Jarvie,A.W.P.[JournalofOrganometallicChemistry,1970,vol.24,p.335-340]

[1]Organ,MichaelG.;Mallik,Debasis[CanadianJournalofChemistry,2006,vol.84,#10,p.1259-1262]

[2]CurrentPatentAssignee:AUXENIONGMBH-WO2018/154118,2018,A2Locationinpatent:Page/Pagecolumn108

[3]Dunn,Jonathan;Dobbs,AdrianP.[Tetrahedron,2015,vol.71,#39,p.7386-7414]

[4]Yarosh;Zhilitskaya;Shagun;Dorofeev;Larina[RussianJournalofOrganicChemistry,2017,vol.53,#3,p.413-417][Zh.Org.Khim.,2017,vol.53,#3,p.413-417,5]

[5]Huang;Wang[HuaxueXuebao/ActaChimicaSinica,1959,vol.25,p.330,331-340][Chem.Abstr.,1960,#16375]

[6]Nakashima,Tohru;Fujiyama,Ryoji;Fujio,Mizue;Tsuno,Yuho[BulletinoftheChemicalSocietyofJapan,1999,vol.72,#4,p.741-750]

[7]Mercadante,MichaelA.;Kelly,ChristopherB.;Hamlin,TrevorA.;DelleChiaie,KaylaR.;Drago,MichaelD.;Duffy,KatherineK.;Dumas,MeganT.;Fager,DianaC.;Glod,BryannaL.C.;Hansen,KatherineE.;Hill,CameronR.;Leising,RebeccaM.;Lynes,CatherineL.;Macinnis,AllysonE.;McGohey,MadelineR.;Murray,StephanieA.;Piquette,MarcC.;Roy,ShainaL.;Smith,RyanM.;Sullivan,KatherineR.;Truong,BaoH.;Vailonis,KristinaM.;Gorbatyuk,Vitaliy;Leadbeater,NicholasE.;Tilley,LeonJ.[ChemicalScience,2014,vol.5,#10,p.3983-3994]

[1]Wilt,J.W.etal.[JournaloftheAmericanChemicalSociety,1969,vol.91,p.2624-2631]

[1]Pola,J.etal.[CollectionofCzechoslovakChemicalCommunications,1973,vol.38,p.1522-1527]

[2]Simov,BiljanaPeric;Wuggenig,Frank;Mereiter,Kurt;Andres,Hendrik;France,Julien;Schnelli,Peter;Hammerschmidt,Friedrich[JournaloftheAmericanChemicalSociety,2005,vol.127,#40,p.13934-13940]

[3]Kabachnik,M.I.;Zakharov,L.S.;Molchanova,G.N.;Drozdova,T.D.;Petrovskii,P.V.[BulletinoftheAcademyofSciencesoftheUSSRDivisionofChemicalScience,1989,vol.38,#7.2,p.1527-1532][IzvestiyaAkademiiNaukSSSR,SeriyaKhimicheskaya,1989,vol.38,#7,p.1664-1670]

[4]Boons;Elie;VanderMarel;VanBoom[TetrahedronLetters,1990,vol.31,#15,p.2197-2200]

[5]Buisson,David-Alexandre;Crassous,Jeanne;Feuillastre,Sophie;Lesot,Philippe;Naret,Timothee;Pieters,Gregory;Polavarapu,PrasadL.;Puente,AndrewR.[OrganicLetters,2020,vol.22,#22,p.8846-8849]

[1]Noll,J.E.;Speier,J.E.;Daubert,B.F.[JournaloftheAmericanChemicalSociety,1951,vol.73,p.3867-3871]

[2][GmelinHandbuchderAnorganischenChemie,GmelinHandbook:Si:MVol.C,22,page68-71]

[3]Andrianov,K.A.etal.[JournalofgeneralchemistryoftheUSSR,1975,vol.45,p.340-345][ZhurnalObshcheiKhimii,1975,vol.45,p.351-357]

Literature

Title: Direct chemical synthesis of chiral methanol of 98% ee and its conversion to [(2)H1,(3)H]methyl tosylate and [(2)H1,(3)H-methyl]methionine.

Journal: Journal of the American Chemical Society 20051012

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Tags:1833-51-8 Molecular Formula|1833-51-8 MDL|1833-51-8 SMILES|1833-51-8 Chloromethyldimethylphenylsilane