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18968-05-3,MFCD00012354
Catalog No.:AA002DT5

18968-05-3 | 1,3,4,6-Tetra-o-acetyl-beta-d-mannopyranose

Pack Size
Purity
Availability
Price(USD)
Quantity
  
250mg
97%
in stock  
$16.00   $11.00
- +
1g
97%
in stock  
$50.00   $35.00
- +
5g
97%
in stock  
$218.00   $153.00
- +
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA002DT5
Chemical Name:
1,3,4,6-Tetra-o-acetyl-beta-d-mannopyranose
CAS Number:
18968-05-3
Molecular Formula:
C14H20O10
Molecular Weight:
348.3026
MDL Number:
MFCD00012354
SMILES:
CC(=O)OC[C@H]1O[C@@H](OC(=O)C)[C@H]([C@H]([C@@H]1OC(=O)C)OC(=O)C)O
Properties
Properties
 
BP:
425.537°C at 760 mmHg  
Form:
Solid  
MP:
160-161 °C(lit.)  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
502  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
5  
Heavy Atom Count:
24  
Hydrogen Bond Acceptor Count:
10  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
9  
XLogP3:
0.1  

Upstream Synthesis Route

[1]BioorganicandMedicinalChemistry,2018,vol.26,#8,p.1848-1858

[2]Tetrahedron,1992,vol.48,#47,p.10249-10264

[3]TetrahedronLetters,2013,vol.54,#17,p.2190-2193

[1]Patent:CN103739635,2016,B,.Locationinpatent:Paragraph0029

[1]Patent:US2006/67888,2006,A1,.Locationinpatent:Page/Pagecolumn11;sheet7

[1]ChemischeBerichte,1930,vol.63,p.386,390

[2]JournaloftheAmericanChemicalSociety,1958,vol.80,p.3372,3378

[3]JournaloftheAmericanChemicalSociety,1959,vol.81,p.5171,5172,5176

[4]TetrahedronLetters,2013,vol.54,#17,p.2190-2193

[5]BioorganicandMedicinalChemistry,2018,vol.26,#8,p.1848-1858

[1]ChemischeBerichte,1980,vol.113,#2,p.489-510

Downstream Synthesis Route

[1]Tetrahedron,1992,vol.48,p.10249-10264

[2]JournaloftheAmericanChemicalSociety,2010,vol.132,p.7405-7417

[3]CarbohydrateResearch,1991,vol.210,p.333-337

[4]OrganicandBiomolecularChemistry,2009,vol.7,p.564-575

[5]CarbohydrateResearch,1984,vol.128,p.291-296

[6]BioorganicandMedicinalChemistry,2018,vol.26,p.1848-1858

[7]CarbohydrateResearch,1993,vol.245,p.219-231

[8]TetrahedronAsymmetry,2005,vol.16,p.321-335

[9]ActaCrystallographica,SectionC:CrystalStructureCommunications,2012,vol.68,p.o338-o340

36913-91-4    18968-05-3   
1,3,4,6-tetra-O-acetyl-2-(1,1,2,2,3,3,4,4,4-nonafluoro-butane-sulfonate)-β-D-mannopyranoside 

[1]AngewandteChemie-InternationalEdition,2007,vol.46,p.941-944

2991-84-6    18968-05-3   
1,3,4,6-tetra-O-acetyl-2-(perfluorobutanoate)-β-D-mannopyranoside 

[1]AngewandteChemie-InternationalEdition,2007,vol.46,p.941-944

[2]OrganicandBiomolecularChemistry,2009,vol.7,p.564-575

18968-05-3   
2-deoxy-2-fluoro-D-glucopyranose1-phosphate 

[1]Journaloflabelledcompoundsandradiopharmaceuticals,2007,vol.50,p.55-63

18968-05-3   
Cyclopropanecarboxylicacid(2S,3R,4R,5S,6R)-4,5-dihydroxy-6-hydroxymethyl-2-((1R,2R,3R,5S)-2,3,5-trihydroxy-5-hydroxymethyl-cyclohexyloxy)-tetrahydro-pyran-3-yl-amide 

[1]BioorganicandMedicinalChemistryLetters,2007,vol.17,p.444-447

Literature

Title: Practical and reliable synthesis of 1,3,4,6-tetra-O-acetyl-2-O-trifluoromethanesulfonyl-beta-D-mannopyranose, a precursor of 2-deoxy-2-[18F]fluoro-D-glucose (FDG).

Journal: Molecular imaging and biology : MIB : the official publication of the Academy of Molecular Imaging 20040101

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