Home Pyridines 2456-81-7
2456-81-7,MFCD00006415
Catalog No.:AA002OH2

2456-81-7 | 4-Pyrrolidinopyridine

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5g
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$11.00   $8.00
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10g
98%
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$16.00   $11.00
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25g
98%
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$26.00   $18.00
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100g
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$62.00   $43.00
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500g
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA002OH2
Chemical Name:
4-Pyrrolidinopyridine
CAS Number:
2456-81-7
Molecular Formula:
C9H12N2
Molecular Weight:
148.2050
MDL Number:
MFCD00006415
SMILES:
C1CCN(C1)c1ccncc1
Properties
Properties
 
BP:
263.1°C at 760 mmHg  
Form:
Solid  
MP:
57-58 °C  
Refractive Index:
1.5378 (estimate)  
Solubility:
methanol: 0.1 g/mL, clear  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
113  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
11  
Hydrogen Bond Acceptor Count:
2  
Rotatable Bond Count:
1  
XLogP3:
1.5  

Upstream Synthesis Route

[1]Synlett,2000,#1,p.116-118

[2]TetrahedronLetters,2001,vol.42,#33,p.5689-5692

[3]BioorganicandMedicinalChemistryLetters,2009,vol.19,#21,p.6122-6126

[4]TetrahedronLetters,2004,vol.45,#4,p.757-759

[1]ChemSusChem,2015,vol.8,#6,p.1083-1087

[2]TetrahedronLetters,2004,vol.45,#4,p.757-759

[1]Patent:US4513141,1985,A,

[2]Patent:EP126950,1991,B1,

[1]Synthesis,1988,#12,p.985-988

[1]TetrahedronLetters,2004,vol.45,#12,p.2667-2669

Downstream Synthesis Route

[1]TetrahedronLetters,1990,vol.31,p.7599-7602

[1]ChemischeBerichte,1984,vol.117,p.1523-1541

[1]ChemischeBerichte,1984,vol.117,p.1523-1541

2402-79-1    2456-81-7   
1,1'-bis4-pyrrolidino-(3,5-dichloro-pyridine-2,6-diyl)pyridiniumdichloride 

[1]Tetrahedron,2006,vol.62,p.1667-1674

19050-46-5    2456-81-7   
1,1'-bis4-pyrrolidino-(3,5-dichloro-4-(2-propylsulfanyl)-pyridine-2,6-diyl)pyridiniumdichloride 

[1]Tetrahedron,2006,vol.62,p.1667-1674

Literature

Title: Theoretical prediction of selectivity in kinetic resolution of secondary alcohols catalyzed by chiral DMAP derivatives.

Journal: Journal of the American Chemical Society 20120606

Title: 1H and 13C NMR spectral assignments of pyridinium salts linked to a N-9 or N-3 adenine moiety.

Journal: Magnetic resonance in chemistry : MRC 20120601

Title: Room-temperature dissociation of 1,2-dibromodisilenes to bromosilylenes.

Journal: Journal of the American Chemical Society 20111214

Title: Enantioselective acylation of silyl ketene acetals through fluoride anion-binding catalysis.

Journal: Journal of the American Chemical Society 20110907

Title: A dual-catalysis/anion-binding approach to the kinetic resolution of allylic amines.

Journal: Organic letters 20110506

Title: Tetra-μ-benzoato-bis-{[4-(pyrrolidin-1-yl)pyridine]zinc(II)}.

Journal: Acta crystallographica. Section E, Structure reports online 20100101

Title: A rapid and sensitive method for the simultaneous analysis of aliphatic and polar molecules containing free carboxyl groups in plant extracts by LC-MS/MS.

Journal: Plant methods 20090101

Title: Zwitterionic salts as mild organocatalysts for transesterification.

Journal: Organic letters 20080605

Title: Iron complexes of dendrimer-appended carboxylates for activating dioxygen and oxidizing hydrocarbons.

Journal: Journal of the American Chemical Society 20080402

Title: A catalytic one-step process for the chemo- and regioselective acylation of monosaccharides.

Journal: Journal of the American Chemical Society 20071024

Title: Enhancement of ninhydrin- or DFO-treated latent fingerprints on thermal paper.

Journal: Journal of forensic sciences 20070501

Title: Facile syntheses of acyl dihydroxyacetone phosphates and lysophosphatidic acids having different acyl groups.

Journal: Journal of lipid research 20060801

Title: From uncharged to decacationic molecules: syntheses and spectroscopic properties of heteroarenium-substituted pyridines.

Journal: Organic & biomolecular chemistry 20051021

Title: Alpha- and beta- aspartyl peptide ester formation via aspartimide ring opening.

Journal: Journal of peptide science : an official publication of the European Peptide Society 20051001

Title: Kinetic resolution of sec-alcohols using a new class of readily assembled (S)-proline-derived 4-(pyrrolidino)-pyridine analogues.

Journal: Organic & biomolecular chemistry 20050321

Title: L-Phe end-capped poly(L-lactide) as macroinitiator for the synthesis of poly(L-lactide)-B-poly(L-lysine) block copolymer.

Journal: Biomacromolecules 20050101

Title: A facile preparation of 1-(6-hydroxyindol-1-yl)-2,2-dimethylpropan-1-one.

Journal: Chemical & pharmaceutical bulletin 20030101

Title: Enantioselective addition of amines to ketenes catalyzed by a planar-chiral derivative of PPY: possible intervention of chiral Brønsted-acid catalysis.

Journal: Journal of the American Chemical Society 20020828

Title: Enantioselective Staudinger synthesis of beta-lactams catalyzed by a planar-chiral nucleophile.

Journal: Journal of the American Chemical Society 20020227

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Tags:2456-81-7 Molecular Formula|2456-81-7 MDL|2456-81-7 SMILES|2456-81-7 4-Pyrrolidinopyridine |Organic_Building_Blocks