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75-97-8,MFCD00008846
Catalog No.:AA0033EW

75-97-8 | Pinacolone

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25g
98%
in stock  
$147.00   $103.00
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100g
98%
in stock  
$297.00   $208.00
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500g
98%
in stock  
$934.00   $654.00
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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0033EW
Chemical Name:
Pinacolone
CAS Number:
75-97-8
Molecular Formula:
C6H12O
Molecular Weight:
100.1589
MDL Number:
MFCD00008846
SMILES:
CC(=O)C(C)(C)C
NSC Number:
935
Properties
Properties
 
BP:
106.1°C  
Form:
Liquid  
MP:
-52.5 °C  
Refractive Index:
n20/D 1.396(lit.)  
Solubility:
19g/l  
Storage:
Room Temperature;  

Computed Properties
 
Complexity:
76.7  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
1  
XLogP3:
1.2  

Literature

Title: The role of acid catalysis in the Baeyer-Villiger reaction. A theoretical study.

Journal: The Journal of organic chemistry 20120817

Title: Hg(OTf)2-catalyzed vinylogous semi-pinacol rearrangement leading to 1,4-dihydroquinolines.

Journal: Organic letters 20120302

Title: (E)-1-(1,3-Benzodioxol-5-yl)-4,4-di-methyl-pent-1-en-3-one.

Journal: Acta crystallographica. Section E, Structure reports online 20120301

Title: Ionic crystals [M3O(OOCC6H5)6(H2O)3]4[α-SiW12O40] (M = Cr, Fe) as heterogeneous catalysts for pinacol rearrangement.

Journal: Inorganic chemistry 20120116

Title: Synthesis, spectroscopic, and in vitro photosensitizing efficacy of ketobacteriochlorins derived from ring-B and ring-D reduced chlorins via pinacol-pinacolone rearrangement.

Journal: The Journal of organic chemistry 20111104

Title: Isolation and characterization of 4-tert-butylphenol-utilizing Sphingobium fuliginis strains from Phragmites australis rhizosphere sediment.

Journal: Applied and environmental microbiology 20101001

Title: Direct conversion of arylamines to pinacol boronates: a metal-free borylation process.

Journal: Angewandte Chemie (International ed. in English) 20100301

Title: Effect of guest-host hydrogen bonding on the structures and properties of clathrate hydrates.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100118

Title: Calyculins and related marine natural products as serine-threonine protein phosphatase PP1 and PP2A inhibitors and total syntheses of calyculin A, B, and C.

Journal: Marine drugs 20100101

Title: Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-pot.

Journal: Chemical communications (Cambridge, England) 20091107

Title: 1-(4-Chloro-phen-yl)-4,4-dimethyl-pent-1-en-3-one.

Journal: Acta crystallographica. Section E, Structure reports online 20090301

Title: The hydrogenation/transfer hydrogenation network in asymmetric reduction of ketones catalyzed by [RuCl2(binap)(pica)] complexes.

Journal: Chemistry, an Asian journal 20081006

Title: Radical nucleophilic substitution of 2-(4-halophenyl)-2-methyl-1-chloropropane with enolate ions of ketones.

Journal: The Journal of organic chemistry 20070413

Title: Coupling of enantioselective biooxidation of DL-1,2-propanediol and bioreduction of pinacolone via regeneration cycle of coenzyme.

Journal: Applied microbiology and biotechnology 20060801

Title: Coupling of an aldehyde or ketone to pyridine mediated by a tungsten imido complex.

Journal: Inorganic chemistry 20051212

Title: Synthesis of 2H-1,2-benzothiazine 1,1-dioxides via heteroannulation reactions of 2-iodobenzenesulfonamide with ketone enolates under S(RN)1 conditions.

Journal: The Journal of organic chemistry 20051111

Title: A RuH(2)(CO)(PPh(3))(3)-catalyzed regioselective arylation of aromatic ketones with arylboronates via carbon-hydrogen bond cleavage.

Journal: Journal of the American Chemical Society 20050427

Title: Designing the 'search pathway' in the development of a new class of highly efficient stereoselective hydrosilylation catalysts.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050422

Title: Enzymatic enantioselective transcyanation of silicon-containing aliphatic ketone with (S)-hydroxynitrile lyase from Manihot esculenta.

Journal: Applied microbiology and biotechnology 20041101

Title: Highly chemoselective oxidation of dithioester enethiolates to sulfenates: application to the synthesis of ketene dithioacetal s-oxides.

Journal: The Journal of organic chemistry 20041001

Title: Degradation of isooctane by Mycobacterium austroafricanum IFP 2173: growth and catabolic pathway.

Journal: Journal of applied microbiology 20040101

Title: Pinacol coupling reaction of beta-halo-alpha,beta-unsaturated aldehydes promoted by TiI4.

Journal: Organic letters 20021114

Title: Multiplicity control in the polygeminal diazeniumdiolation of active hydrogen bearing carbons: chemistry of a new type of trianionic molecular propeller.

Journal: Journal of the American Chemical Society 20011107

Title: Effect of meso-substituents on the osmium tetraoxide reaction and pinacol-pinacolone rearrangement of the corresponding vic-dihydroxyporphyrins.

Journal: The Journal of organic chemistry 20010601

Title: Palladium-catalyzed tandem reactions to form 1-vinyl-1h-isochromene derivatives.

Journal: The Journal of organic chemistry 20010518

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