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67-51-6,MFCD00005243
Catalog No.:AA0033GV

67-51-6 | 3,5-Dimethylpyrazole

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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0033GV
Chemical Name:
3,5-Dimethylpyrazole
CAS Number:
67-51-6
Molecular Formula:
C5H8N2
Molecular Weight:
96.1304
MDL Number:
MFCD00005243
SMILES:
Cc1[nH]nc(c1)C
NSC Number:
8729
Properties
Properties
 
BP:
218°C at 760 mmHg  
Form:
Solid  
MP:
105-108 °C(lit.)  
Refractive Index:
1.4739 (estimate)  
Solubility:
methanol: 0.1 g/mL, clear  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
63.1  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
1  
XLogP3:
1  

Literature

Title: Reactivity of rhodium(I) complexes bearing nitrogen-containing ligands toward CH3I: synthesis and full characterization of neutral cis-[RhX(CO)2(L)] and acetyl [RhI(μ-I)(COMe)(CO)(L)]2 complexes.

Journal: Inorganic chemistry 20120820

Title: Highly efficient redox isomerisation of allylic alcohols catalysed by pyrazole-based ruthenium(IV) complexes in water: mechanisms of bifunctional catalysis in water.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120618

Title: Bis(4,4''-difluoro-1,1':3',1''-terphenyl-2'-carboxyl-ato-κO)bis-(3,5-dimethyl-1H-pyrazole-κN(2))manganese(II).

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: Bis(3,5-dimethyl-1H-pyrazole-κN(2))bis-(3,3'',5,5''-tetra-methyl-[1,1':3',1''-terphen-yl]-2'-carboxyl-ato-κO)iron(II) dichloro-methane monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: Distorted cubic tetranuclear vanadium(IV) phosphonate cages: double-four-ring (D4R) containing transition metal ion phosphonate cages.

Journal: Dalton transactions (Cambridge, England : 2003) 20120121

Title: Synthesis of ruthenium(II) complexes of tetradentate bis(N-pyridylimidazolylidenyl)methane and their reactivities towards N- donors.

Journal: Dalton transactions (Cambridge, England : 2003) 20120114

Title: Synthesis of new bitopic tetra(pyrazolyl)-ligands with neopentane and O-xylene backbones.

Journal: TheScientificWorldJournal 20120101

Title: Metal Ion Chelates as Surrogates of Nucleobases for the Recognition of Nucleic Acid Sequences: The Pd(2+) Complex of 2,6-Bis(3,5-dimethylpyrazol-1-yl)purine Riboside.

Journal: Journal of nucleic acids 20120101

Title: cis-Bis(2,2'-bipyridine-κN,N')bis-(dimethyl sulfoxide-κO)zinc bis-(tetra-phenyl-borate) dimethyl sulfoxide monosolvate.

Journal: Acta crystallographica. Section E, Structure reports online 20111201

Title: Novel C-H···C contacts involving 3,5-dimethylpyrazole ligands in a tetracoordinate Co(II) complex.

Journal: Dalton transactions (Cambridge, England : 2003) 20111121

Title: Dibromidobis(3,5-dimethyl-1H-pyrazole-κN)cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20111101

Title: The co-ordination chemistry of tris(3,5-dimethylpyrazolyl)methane manganese carbonyl complexes: synthetic, electrochemical and DFT studies.

Journal: Dalton transactions (Cambridge, England : 2003) 20110928

Title: Two different hydrogen bond donor ligands together: a selectivity improvement in organometallic {Re(CO)3} anion hosts.

Journal: Inorganic chemistry 20110905

Title: Molecular structure, vibrational spectral studies of pyrazole and 3,5-dimethyl pyrazole based on density functional calculations.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20110901

Title: New azole antifungal agents with novel modes of action: synthesis and biological studies of new tridentate ligands based on pyrazole and triazole.

Journal: European journal of medicinal chemistry 20110901

Title: 3,5-Dimethyl-1H-pyrazole-2-hy-droxy-5-(phenyl-diazen-yl)benzoic acid (1/1).

Journal: Acta crystallographica. Section E, Structure reports online 20110901

Title: Synthesis and structure of ruthenium(IV) complexes featuring N-heterocyclic ligands with an N-H group as the hydrogen-bond donor: hydrogen interactions in solution and in the solid state.

Journal: Inorganic chemistry 20110606

Title: Aqua-bis-(3,5-dimethyl-1H-pyrazole-κN)(oxydiacetato-κO,O',O'')copper(II) dihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20110601

Title: Chloridotris(3,5-dimethyl-1H-pyrazole-κN)(formato-κO)copper(II)-dichlorido-bis(3,5-dimethyl-1H-pyrazole-κN)copper(II) (2/1).

Journal: Acta crystallographica. Section E, Structure reports online 20110601

Title: Influence of N-donor bases and the solvent in oxodiperoxomolybdenum catalysed olefin epoxidation with hydrogen peroxide in ionic liquids.

Journal: Dalton transactions (Cambridge, England : 2003) 20110521

Title: Bis(3,5-dimethyl-1H-pyrazole-κN)silver(I) hexa-fluorido-anti-monate.

Journal: Acta crystallographica. Section E, Structure reports online 20110401

Title: Experimental charge density distribution of non-coordinating sp3 carbanions in [Mg{(pz*)3C}2].

Journal: Chemical communications (Cambridge, England) 20110314

Title: Dichlorido(3,5-dimethyl-1H-pyrazole-κN)[hydro-tris-(3,5-dimethyl-1H-pyrazol-1-yl-κN)borato]chromium(III) tetra-hydro-furan mono-solvate.

Journal: Acta crystallographica. Section E, Structure reports online 20110301

Title: catena-Poly[[[(3,5-dimethyl-1H-pyrazole)-copper(II)]-μ-{N-[1-(2-oxidophen-yl)ethyl-idene]-l-valinato}] methanol monosolvate].

Journal: Acta crystallographica. Section E, Structure reports online 20110201

Title: Electronic configuration of five-coordinate high-spin pyrazole-ligated iron(II) porphyrinates.

Journal: Inorganic chemistry 20101206

Title: 3-Chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine.

Journal: Acta crystallographica. Section E, Structure reports online 20101001

Title: Computational study on the reactivity of tetrazines toward organometallic reagents.

Journal: The Journal of organic chemistry 20100917

Title: Cracking the framework of bulk CuCN with flexible bipyrazolyl-based ligands to assemble [CuCN]n-based coordination polymers.

Journal: Dalton transactions (Cambridge, England : 2003) 20100907

Title: Breaking the cycle: impact of sterically-tailored tetra(pyrazolyl)lutidines on the self-assembly of silver(I) complexes.

Journal: Inorganic chemistry 20100906

Title: Diethyl 2-[(3,5-dimethyl-1H-pyrazol-1-yl)(4-meth-oxy-phen-yl)meth-yl]propane-dioate.

Journal: Acta crystallographica. Section E, Structure reports online 20100801

Title: Structural requirements of strigolactones for hyphal branching in AM fungi.

Journal: Plant & cell physiology 20100701

Title: Mono- versus dinuclear Pt(II) 6-(5-trifluoromethyl-pyrazol-3-yl)-2,2'-bipyridine complexes: synthesis, characterization, and remarkable difference in luminescent properties.

Journal: Inorganic chemistry 20100215

Title: [Diphenyldi(pyrazol-1-yl)methane]-dinitratocobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20100201

Title: Ligand effect on ethylene trimerisation with [NNN]-heteroscorpionate pyrazolyl Cr(III) catalysts.

Journal: Dalton transactions (Cambridge, England : 2003) 20091114

Title: Experimental FTIR, FT-IR (gas phase), FT-Raman and NMR spectra, hyperpolarizability studies and DFT calculations of 3,5-dimethylpyrazole.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20091015

Title: Synthesis and characterization of Sn(II), Pb(II) and Yb(II) complexes supported by [C(Ph(2)P=NSiMe3){6-(2-RC5H3N)}]2- or [CH(Ph2P=NSiMe3){6-(2-RC5H3N)}]- (R = 3,5-dimethyl-1-pyrazolyl or iminophosphoranyl) ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20091014

Title: 3-(3,5-Dimethyl-1H-pyrazol-1-yl)propanamide.

Journal: Acta crystallographica. Section E, Structure reports online 20091001

Title: Solvent induced reactivity of 3,5-dimethylpyrazole towards zinc (II) carboxylates.

Journal: Dalton transactions (Cambridge, England : 2003) 20090928

Title: Manipulating self-assembly in silver(I) complexes of 1,3-di-N-pyrazolylorganyls.

Journal: Inorganic chemistry 20090907

Title: Nuclearity control in molecular iron phosphates through choice of iron precursors and ancillary ligands.

Journal: Chemistry, an Asian journal 20090602

Title: Bis(acetato-κO,O')bis-(3,5-dimethyl-1H-pyrazole-κN)copper(II).

Journal: Acta crystallographica. Section E, Structure reports online 20090601

Title: Novel dinuclear dimethylamido-3,5-dimethylpyrazolato and tetranuclear dimethylamido-3,5-dimethylpyrazolato-polyoxo zirconium(IV) complexes. Synthesis and structural characterisation.

Journal: Dalton transactions (Cambridge, England : 2003) 20090414

Title: Stimulation of autophagy by antilipolytic drugs may rescue rodents from age-associated hypercholesterolemia.

Journal: Rejuvenation research 20090401

Title: Tris(3,5-dimethyl-1H-pyrazole-κN)(pyridine-2,6-dicarboxyl-ato-κO,N,O)cobalt(II) monohydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20090401

Title: Synthesis of mixed Cp/Tp(Me2) lanthanide complexes from lanthanocene precursors and their structures and reactivities.

Journal: Inorganic chemistry 20090216

Title: Controlling the structure of manganese(II) phosphates by the choice and ratio of organophosphate and auxiliary ligands.

Journal: Chemistry, an Asian journal 20090105

Title: Di-, tri-, tetra-, and hexanuclear copper(II) mono-organophosphates: structure and nuclearity dependence on the choice of phosphorus substituents and auxiliary N-donor ligands.

Journal: Inorganic chemistry 20090105

Title: In vitro evaluation of dichloro-bis(pyrazole)palladium(II) and dichloro-bis(pyrazole)platinum(II) complexes as anticancer agents.

Journal: Cancer chemotherapy and pharmacology 20081201

Title: μ-2,2,4,4,6,6-Hexakis(3,5-dimethyl-pyrazol-1-yl)-2λ,4λ,6λ-1,3,5,2,4,6-triaza-triphosphinine]bis-[bis-(nitrato- κO,O')cadmium(II).

Journal: Acta crystallographica. Section E, Structure reports online 20081201

Title: Tetra-kis(3,5-dimethyl-1H-pyrazole-κN)(nitrato-κO,O')cadmium(II) nitrate.

Journal: Acta crystallographica. Section E, Structure reports online 20081201

Title: Assembly of tetra, di and mononuclear molecular cadmium phosphonates using 2,4,6-triisopropylphenylphosponic acid and ancillary ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20081014

Title: Ni(II) complexes featuring non-metallated pincer-type ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20080921

Title: N-[(3,5-Dimethyl-pyrazol-1-yl)meth-yl]phthalimide.

Journal: Acta crystallographica. Section E, Structure reports online 20080901

Title: Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN)cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080801

Title: μ(3)-2,2,4,4,6,6-Hexakis(3,5-dimethyl-pyrazol-1-yl)-2λ,4λ,6λ-1,3,5,2,4,6-triaza-triphosphinine]tris-[cis-dichloridopalladium(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080801

Title: Nitric oxide binding and photodelivery based on ruthenium(II) complexes of 4-arylazo-3,5-dimethylpyrazole.

Journal: Dalton transactions (Cambridge, England : 2003) 20080721

Title: Chemical composition and inhibitory parameters of essential oil and extracts of Nandina domestica Thunb. to control food-borne pathogenic and spoilage bacteria.

Journal: International journal of food microbiology 20080715

Title: Barrel- and crown-shaped dodecanuclear copper(II) cages built from phosphonate, pyrazole, and hydroxide ligands.

Journal: Inorganic chemistry 20080616

Title: Synthesis, in vitro and in vivo characterization of (64)Cu(I) complexes derived from hydrophilic tris(hydroxymethyl)phosphane and 1,3,5-triaza-7-phosphaadamantane ligands.

Journal: Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20080201

Title: Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol-yl)methanone]palladium(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: Bis(3,5-dimethyl-pyrazole)[N-salicyl-idene-β-alaninato(2-)]copper(II) dihydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: Aqua-bis(3,5-dimethyl-1H-pyrazole-κN)(oxalato-κO,O')copper(II).

Journal: Acta crystallographica. Section E, Structure reports online 20080101

Title: Blue-emitting platinum(II) complexes bearing both pyridylpyrazolate chelate and bridging pyrazolate ligands: synthesis, structures, and photophysical properties.

Journal: Inorganic chemistry 20071224

Title: A planar carboxylate-rich tetraironII complex and its conversion to linear triironII and paddlewheel diironII complexes.

Journal: Inorganic chemistry 20071210

Title: Rational design of minimal artificial Diels-Alderases based on the copper(II) cation-aromatic pi attractive interaction.

Journal: Accounts of chemical research 20071001

Title: Pyrazole complexes as anion receptors: effects of changing the metal, the pyrazole substitution pattern, and the number of pyrazole ligands.

Journal: Inorganic chemistry 20070416

Title: Evidence for selective mitochondrial autophagy and failure in aging.

Journal: Autophagy 20070101

Title: Electronic structure of four-coordinate C3v nickel(II) scorpionate complexes: investigation by high-frequency and -field electron paramagnetic resonance and electronic absorption spectroscopies.

Journal: Inorganic chemistry 20061030

Title: Synthesis, solid-state NMR, and X-ray powder diffraction characterization of group 12 coordination polymers, including the first example of a C-mercuriated pyrazole.

Journal: Inorganic chemistry 20061030

Title: Rhenium-mediated coupling of acetonitrile and pyrazoles. New molecular clefts for anion binding.

Journal: Inorganic chemistry 20060821

Title: Design and solvothermal synthesis of luminescent copper(I)-pyrazolate coordination oligomer and polymer frameworks.

Journal: Chemical communications (Cambridge, England) 20060721

Title: Double lawton SN2'addition to epoxyvinyl sulfones: selective construction of the stereotetrads of aplyronine A.

Journal: Organic letters 20060706

Title: Pyrazole complexes as anion receptors.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060301

Title: Stimulation of macroautophagy can rescue older cells from 8-OHdG mtDNA accumulation: a safe and easy way to meet goals in the SENS agenda.

Journal: Rejuvenation research 20060101

Title: Uranium(III)/(IV) nitrile adducts including UI4(N[triple bond]CPh)4, a synthetically useful uranium(IV) complex.

Journal: Inorganic chemistry 20051017

Title: One-dimensional and two-dimensional coordination polymers from self-assembling of trinuclear triangular Cu(II) secondary building units.

Journal: Inorganic chemistry 20050905

Title: New [Mo(eta3-allyl)(CO)2L3]+ complexes with monodentate or tridentate nitrogen-donor ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20050307

Title: Cationic fac-tris(pyrazole) complexes as anion receptors.

Journal: Chemical communications (Cambridge, England) 20050128

Title: Catena-poly[[bis(1H-benzotriazole-kappaN3)cobalt(II)]-di-mu-tricyanomethanido-kappa2N:N'] and catena-poly[[bis(3,5-dimethyl-1H-pyrazole-kappaN2)manganese(II)]-di-mu-tricyanomethanido-kappa2N:N'].

Journal: Acta crystallographica. Section C, Crystal structure communications 20040601

Title: Fourier transform infrared studies on deblocking and crosslinking mechanisms of some fluorine containing monocomponent polyurethanes.

Journal: Applied spectroscopy 20040501

Title: Ageing-related changes in the in vivo function of rat liver macroautophagy and proteolysis.

Journal: Experimental gerontology 20030501

Title: Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons.

Journal: Journal of the American Chemical Society 20020904

Title: Spectroscopic study on charge transfer molecular complexes of pyrazole derivatives with some pi-electron acceptors.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20020701

Title: Chemistry of stable iminopropadienones, RN=C=C=C=O.

Journal: The Journal of organic chemistry 20020419

Title: Bis(3,5-dimethylpyrazole-kappaN2)silver(I) nitrate.

Journal: Acta crystallographica. Section C, Crystal structure communications 20020401

Title: New structural forms in molecular metal phosphonates: novel tri- and hexanuclear zinc(II) cages containing phosphonate and pyrazole ligands.

Journal: Inorganic chemistry 20020311

Title: The antilipolytic agent 3,5-dimethylpyrazole inhibits insulin release in response to both nutrient secretagogues and cyclic adenosine monophosphate agonists in isolated rat islets.

Journal: Metabolism: clinical and experimental 20020101

Title: Aquabis(3,5-dimethyl-1H-pyrazole-kappaN2)(malonato-kappa2O,O')copper(II) dihydrate.

Journal: Acta crystallographica. Section C, Crystal structure communications 20011201

Title: Synthesis, structure, and electronic properties of monomeric and dimeric trispyrazolylborate platinum(II) hydride complexes.

Journal: Inorganic chemistry 20010827

Title: Flash vacuum pyrolysis over solid catalysts. 1. Pyrazoles over zeolites.

Journal: The Journal of organic chemistry 20010504

Title: Di-tert-butyl phosphate complexes of cobalt(II) and zinc(II) as precursors for ceramic M(PO3)2 and M2P2O7 materials: synthesis, spectral characterization, structural studies, and role of auxiliary ligands.

Journal: Inorganic chemistry 20010129

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Tags:67-51-6 Molecular Formula|67-51-6 MDL|67-51-6 SMILES|67-51-6 3,5-Dimethylpyrazole |Organic_Building_Blocks