680-31-9,MFCD00008303
Catalog No.:AA0034X4

680-31-9 | Hexamethylphosphoramide

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Purity
Availability
Price(USD)
Quantity
  
5g
98%
in stock  
$18.00   $13.00
- +
25g
98%
in stock  
$26.00   $18.00
- +
100g
98%
in stock  
$42.00   $29.00
- +
500g
98%
in stock  
$145.00   $102.00
- +
  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
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Technical Information
Catalog Number:
AA0034X4
Chemical Name:
Hexamethylphosphoramide
CAS Number:
680-31-9
Molecular Formula:
C6H18N3OP
Molecular Weight:
179.2004
MDL Number:
MFCD00008303
SMILES:
CN(P(=O)(N(C)C)N(C)C)C
Properties
Properties
 
BP:
232.5°C  
Form:
Solid  
MP:
7 °C(lit.)  
Refractive Index:
n20/D 1.459(lit.)  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
139  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0  
Defined Bond Stereocenter Count:
0  
Formal Charge:
0  
Heavy Atom Count:
11  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
0  
Isotope Atom Count:
0  
Rotatable Bond Count:
3  
Undefined Atom Stereocenter Count:
0  
Undefined Bond Stereocenter Count:
0  
XLogP3:
0.3  

Literature

Title: Synergism and inhibition in the combination of visible light and HMPA in SmI2 reductions.

Journal: The Journal of organic chemistry 20121019

Title: Chromosome aberration frequency in rat peripheral lymphocytes increases with repeated dosing with hexamethylphosphoramide or cyclophosphamide.

Journal: Mutagenesis 20120901

Title: 1-Methyl-1,3-diazinan-2-one.

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: [Simultaneous determination of phosphorous by-products and inorganic anions in glyphosate mother liquor by ion chromatography with suppressed-conductivity detection].

Journal: Se pu = Chinese journal of chromatography 20120401

Title: Synthetic strategies to terpene quinones/hydroquinones.

Journal: Marine drugs 20120201

Title: Scalable enantioselective total synthesis of taxanes.

Journal: Nature chemistry 20120101

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20111201

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20111001

Title: 1-Methyl-3,3-bis-[(4-methyl-phen-yl)sulfan-yl]piperidin-2-one.

Journal: Acta crystallographica. Section E, Structure reports online 20111001

Title: Determination of hexamethylphosphoramide and other highly polar phosphoramides in water samples using reversed-phase liquid chromatography/electrospray ionization time-of-flight mass spectrometry.

Journal: Journal of chromatography. A 20110916

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')yttrium(III)] [silver(I)-di-μ-sulfido-molybdenum(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20110901

Title: (1,2-Dicarba-closo-dodeca-boran-yl)trimethyl-methanaminium iodide.

Journal: Acta crystallographica. Section E, Structure reports online 20110801

Title: Influence of substrate dideuteration on the reaction of the bifunctional heme enzyme psi factor producing oxygenase A (PpoA).

Journal: Chembiochem : a European journal of chemical biology 20110321

Title: Phosphate additives determination in meat products by 31-phosphorus nuclear magnetic resonance using new internal reference standard: hexamethylphosphoroamide.

Journal: Talanta 20110315

Title: Prediction of contaminant persistence in aqueous phase: a quantum chemical approach.

Journal: Environmental science & technology 20110315

Title: α- and β-poly(vinylidene fluoride) evoke different cellular behaviours.

Journal: Journal of biomaterials science. Polymer edition 20110101

Title: Conformationally constrained histidines in the design of peptidomimetics: strategies for the χ-space control.

Journal: International journal of molecular sciences 20110101

Title: Hexamethylphosphoramide.

Journal: Report on carcinogens : carcinogen profiles 20110101

Title: Pretreatment of microcrystalline cellulose in organic electrolyte solutions for enzymatic hydrolysis.

Journal: Biotechnology for biofuels 20110101

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')cerium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20101201

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20101101

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20101001

Title: Structure and dynamics of α-aryl amide and ketone enolates: THF, PMDTA, TMTAN, HMPA, and crypt-solvated lithium enolates, and comparison with phosphazenium analogues.

Journal: The Journal of organic chemistry 20100917

Title: Quantum chemical prediction of redox reactivity and degradation pathways for aqueous phase contaminants: an example with HMPA.

Journal: Environmental science & technology 20100801

Title: 3,3-Bis[(4-chloro-phen-yl)sulfan-yl]-1-methyl-piperidin-2-one.

Journal: Acta crystallographica. Section E, Structure reports online 20100701

Title: Reduction of an hexamethylphosphoramide degradation product: a diazabutadiene.

Journal: Organic letters 20091015

Title: On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR.

Journal: Journal of the American Chemical Society 20090826

Title: Noninvasive monitoring of HPMA copolymer-RGDfK conjugates by magnetic resonance imaging.

Journal: Pharmaceutical research 20090501

Title: A simple synthesis of nitriles from aldoximes.

Journal: The Journal of organic chemistry 20090417

Title: Tricyclic pyrone compounds prevent aggregation and reverse cellular phenotypes caused by expression of mutant huntingtin protein in striatal neurons.

Journal: BMC neuroscience 20090101

Title: Characterization of CYP2A13*2, a variant cytochrome P450 allele previously found to be associated with decreased incidences of lung adenocarcinoma in smokers.

Journal: Drug metabolism and disposition: the biological fate of chemicals 20081101

Title: Anionic Snieckus-Fries rearrangement: solvent effects and role of mixed aggregates.

Journal: Journal of the American Chemical Society 20081015

Title: Lewis base-catalyzed conjugate reduction and reductive aldol reaction of alpha,beta-unsaturated ketones using trichlorosilane.

Journal: Chemical communications (Cambridge, England) 20080928

Title: Searching for voids in liquids with optical Kerr effect spectroscopy.

Journal: The journal of physical chemistry. B 20080724

Title: (1R,4'S)-4-(tert-Butyl-dimethyl-silan-oxy)-1-[2,2-dimethyl-3-(p-tolyl-sulfon-yl)-1,3-oxazolidin-4-yl]but-2-yn-1-ol.

Journal: Acta crystallographica. Section E, Structure reports online 20080601

Title: Reactivity of the triple ion and separated ion pair of tris(trimethylsilyl)methyllithium with aldehydes: a RINMR study.

Journal: Journal of the American Chemical Society 20080514

Title: catena-Poly[[tetra-kis(hexa-methyl-phos-pho-ramide-κO)bis-(nitrato-κO,O')neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20080301

Title: Temperature and length scale dependence of tetraalkylammonium ion-amide interaction.

Journal: The journal of physical chemistry. B 20080221

Title: catena-Poly[[tetra-kis(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: 5,5'-Bis[(trimethyl-silyl)meth-yl]-2,2'-bipyridine.

Journal: Acta crystallographica. Section E, Structure reports online 20080201

Title: Neutral and cationic phosphoramide adducts of silicon tetrachloride: synthesis and characterization of their solution and solid-state structures.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: Diverse reactions of 1,4-dilithio-1,3-dienes with nitriles: facile access to tricyclic Delta1-bipyrrolines, multiply substituted pyridines, siloles, and (Z,Z)-dienylsilanes by tuning of substituents on the butadienyl skeleton.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: Lithium diisopropylamide-mediated reactions of imines, unsaturated esters, epoxides, and aryl carbamates: influence of hexamethylphosphoramide and ethereal cosolvents on reaction mechanisms.

Journal: Journal of the American Chemical Society 20071128

Title: Solvent dynamical control of ultrafast ground state electron transfer: implications for Class II-III mixed valency.

Journal: Journal of the American Chemical Society 20071024

Title: Simultaneous quantification of cyclophosphamide and its active metabolite 4-hydroxycyclophosphamide in human plasma by high-performance liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC-MS/MS).

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20070701

Title: Lithium diisopropylamide solvated by hexamethylphosphoramide: substrate-dependent mechanisms for dehydrobrominations.

Journal: Journal of the American Chemical Society 20061206

Title: Synthesis, characterization, and structural determination of polynuclear lithium aggregates and factors affecting their aggregation.

Journal: Inorganic chemistry 20060904

Title: Monitoring of the insecticide trichlorfon by phosphorus-31 nuclear magnetic resonance (31P NMR) spectroscopy.

Journal: Analytica chimica acta 20060825

Title: Hydrogen-bond effects on the electronic absorption spectrum and evaluation of nonlinear optical properties of an aminobenzodifuranone derivative that exhibits the largest positive solvatochromism.

Journal: Journal of molecular modeling 20050901

Title: [Synthesis of substituted 3H-indole quaternary ammonium salt and study on its interaction with bovine serum albumin by fluorescence].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20050601

Title: Exploring SmBr2-, SmI2-, and YbI2-mediated reactions assisted by microwave irradiation.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050520

Title: Mechanism of anionic dearomatizing reactions of diphenylphosphinamide derivatives: a theoretical and experimental study.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050506

Title: Probing surface basicity of solid acids with an aminobenzodifurandione dye as the solvatochromic probe.

Journal: The journal of physical chemistry. B 20050421

Title: Intramolecular C-H/C-D exchange in cofacially stacked polyfluorenes via electron-induced bond activation.

Journal: Journal of the American Chemical Society 20050420

Title: The second cyclopropannulene: cycloprop-[8]annulene.

Journal: Journal of the American Chemical Society 20050202

Title: Polycyclooctatetraeneoxy alkane polyanionic polyradicals.

Journal: Journal of the American Chemical Society 20050112

Title: Detection of calf muscle alterations in patients with chronic heart failure by P magnetic resonance spectroscopy: Impaired adaptation to continuous exercise.

Journal: Experimental and clinical cardiology 20050101

Title: A first oxalamidino complex of samarium via reduction-coupling of carbodiimine: synthesis and molecular structure of [eta4-C2(NR)4][(MeC5H4)2Sm(HMPA)]2.2THF (R = Pr i, Cy).

Journal: Chemical communications (Cambridge, England) 20041207

Title: A spectroscopic study on defluorination of poly(tetrafluoroethylene) by alkyllithium/electron-donating solvents.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20041101

Title: Deuterium-labeling and NMR study of the dearomatization of N-alkyl-N-benzyldiphenylphosphinamides through anionic cyclization: ortho and benzylic lithiation directed by complex-induced proximity effects.

Journal: Journal of the American Chemical Society 20041006

Title: Vicinal stereocontrol during nucleophilic addition to arene chromium tricarbonyl complexes: formal synthesis of (+/-)-erythro Juvabione.

Journal: Organic letters 20040624

Title: Novel lanthanide(II) complexes supported by carbon-bridged biphenolate ligands: synthesis, structure and catalytic activity.

Journal: Dalton transactions (Cambridge, England : 2003) 20040321

Title: Simultaneous quantification of cyclophosphamide, 4-hydroxycyclophosphamide, N,N',N'-triethylenethiophosphoramide (thiotepa) and N,N',N'-triethylenephosphoramide (tepa) in human plasma by high-performance liquid chromatography coupled with electrospray ionization tandem mass spectrometry.

Journal: Journal of mass spectrometry : JMS 20040301

Title: Syntheses and solid-state and solution structures of [Ba[(C5Me5)2Ti2F7]2(hmpa)] and [Ba8Ti6F30I2(C5Me5)6(hmpa)6][I3]2.

Journal: Inorganic chemistry 20040223

Title: Female germ cell mutagenicity of model chemicals in Drosophila melanogaster: mechanistic information and analysis of repair systems.

Journal: Mutation research 20040112

Title: A reverse genetic screen in Drosophila using a deletion-inducing mutagen.

Journal: Genome biology 20040101

Title: Hexamethylphosphoramide.

Journal: Report on carcinogens : carcinogen profiles 20040101

Title: Rotaxane-stabilized thiophosphonium salt from disulfide and phosphine.

Journal: Organic letters 20031225

Title: Spin densities in dialkoxy-[16]annulene anion radicals: dimerization of alkoxy-[8]annulenes.

Journal: The Journal of organic chemistry 20030221

Title: Phosphoramidites are efficient, green organocatalysts for the Michael reaction. Mechanistic insights into the phosphorus-catalyzed Michael reaction of alkynones and implications for asymmetric catalysis.

Journal: The Journal of organic chemistry 20030207

Title: Drug-HPMA-HuIg conjugates effective against human solid cancer.

Journal: Advances in experimental medicine and biology 20030101

Title: A synthesis of the phenolic lipid, 3-[(Z)-pentadec-8-enyl] catechol, (15:1)-urushiol.

Journal: Chemistry and physics of lipids 20021201

Title: Mass spectral evidence of alkali metal insertion into C60-cyclooctatetraene complexes: M+@C60-C8H 8 *3-.

Journal: The Journal of organic chemistry 20021129

Title: Synthesis of open-framework zinc phosphates from organophosphorus amides.

Journal: Chemical communications (Cambridge, England) 20020821

Title: Samarium diiodide-induced reductive cross-coupling of nitrones with aldehydes and ketones.

Journal: Angewandte Chemie (International ed. in English) 20020517

Title: Hexamethylphosphoramide.

Journal: Report on carcinogens : carcinogen profiles 20020101

Title: Zwitterion radicals and anion radicals from electron transfer and solvent condensation with the fingerprint developing agent ninhydrin.

Journal: The Journal of organic chemistry 20011116

Title: Water soluble polymers in tumor targeted delivery.

Journal: Journal of controlled release : official journal of the Controlled Release Society 20010706

Title: Complex of cobalt(II) bromide with hexamethylphosphoric triamide.

Journal: Acta crystallographica. Section C, Crystal structure communications 20010601

Title: A novel type of nucleophilic substitution reactions on nonactivated aromatic compounds and benzene itself with trimethylsiliconide anions.

Journal: Organic letters 20010419

Title: Studies on the synthesis of 1,2-cis pentofuranosides from S-glycofuranosyl dithiocarbamates, dithiocarbonates and phosphorodithioates.

Journal: Carbohydrate research 20010115

Title: Nasal cytochrome P450 2A: identification, regional localization, and metabolic activity toward hexamethylphosphoramide, a known nasal carcinogen.

Journal: Toxicology and applied pharmacology 19970101

Title: The w/w+ SMART is a useful tool for the evaluation of pesticides.

Journal: Mutagenesis 19940701

Title: Sensory irritation potential of selected nasal tumorigens in the rat.

Journal: Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association 19850101

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Tags:680-31-9 Molecular Formula|680-31-9 MDL|680-31-9 SMILES|680-31-9 Hexamethylphosphoramide
Catalog No.: AA0034X4
680-31-9,MFCD00008303
680-31-9 | Hexamethylphosphoramide
Pack Size: 5g
Purity: 98%
in stock
$18.00 $13.00
Pack Size: 25g
Purity: 98%
in stock
$26.00 $18.00
Pack Size: 100g
Purity: 98%
in stock
$42.00 $29.00
Pack Size: 500g
Purity: 98%
in stock
$145.00 $102.00
Quantity
- +
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Technical Information
Catalog Number: AA0034X4
Chemical Name: Hexamethylphosphoramide
CAS Number: 680-31-9
Molecular Formula: C6H18N3OP
Molecular Weight: 179.2004
MDL Number: MFCD00008303
SMILES: CN(P(=O)(N(C)C)N(C)C)C
Properties
BP: 232.5°C  
Form: Solid  
MP: 7 °C(lit.)  
Refractive Index: n20/D 1.459(lit.)  
Storage: Inert atmosphere;Room Temperature;  
Complexity: 139  
Covalently-Bonded Unit Count: 1  
Defined Atom Stereocenter Count: 0  
Defined Bond Stereocenter Count: 0  
Formal Charge: 0  
Heavy Atom Count: 11  
Hydrogen Bond Acceptor Count: 4  
Hydrogen Bond Donor Count: 0  
Isotope Atom Count: 0  
Rotatable Bond Count: 3  
Undefined Atom Stereocenter Count: 0  
Undefined Bond Stereocenter Count: 0  
XLogP3: 0.3  
Literature fold

Title: Synergism and inhibition in the combination of visible light and HMPA in SmI2 reductions.

Journal: The Journal of organic chemistry20121019

Title: Chromosome aberration frequency in rat peripheral lymphocytes increases with repeated dosing with hexamethylphosphoramide or cyclophosphamide.

Journal: Mutagenesis20120901

Title: 1-Methyl-1,3-diazinan-2-one.

Journal: Acta crystallographica. Section E, Structure reports online20120501

Title: [Simultaneous determination of phosphorous by-products and inorganic anions in glyphosate mother liquor by ion chromatography with suppressed-conductivity detection].

Journal: Se pu = Chinese journal of chromatography20120401

Title: Synthetic strategies to terpene quinones/hydroquinones.

Journal: Marine drugs20120201

Title: Scalable enantioselective total synthesis of taxanes.

Journal: Nature chemistry20120101

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20111201

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20111001

Title: 1-Methyl-3,3-bis-[(4-methyl-phen-yl)sulfan-yl]piperidin-2-one.

Journal: Acta crystallographica. Section E, Structure reports online20111001

Title: Determination of hexamethylphosphoramide and other highly polar phosphoramides in water samples using reversed-phase liquid chromatography/electrospray ionization time-of-flight mass spectrometry.

Journal: Journal of chromatography. A20110916

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')yttrium(III)] [silver(I)-di-μ-sulfido-molybdenum(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20110901

Title: (1,2-Dicarba-closo-dodeca-boran-yl)trimethyl-methanaminium iodide.

Journal: Acta crystallographica. Section E, Structure reports online20110801

Title: Influence of substrate dideuteration on the reaction of the bifunctional heme enzyme psi factor producing oxygenase A (PpoA).

Journal: Chembiochem : a European journal of chemical biology20110321

Title: Phosphate additives determination in meat products by 31-phosphorus nuclear magnetic resonance using new internal reference standard: hexamethylphosphoroamide.

Journal: Talanta20110315

Title: Prediction of contaminant persistence in aqueous phase: a quantum chemical approach.

Journal: Environmental science & technology20110315

Title: α- and β-poly(vinylidene fluoride) evoke different cellular behaviours.

Journal: Journal of biomaterials science. Polymer edition20110101

Title: Conformationally constrained histidines in the design of peptidomimetics: strategies for the χ-space control.

Journal: International journal of molecular sciences20110101

Title: Hexamethylphosphoramide.

Journal: Report on carcinogens : carcinogen profiles20110101

Title: Pretreatment of microcrystalline cellulose in organic electrolyte solutions for enzymatic hydrolysis.

Journal: Biotechnology for biofuels20110101

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')cerium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20101201

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20101101

Title: catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20101001

Title: Structure and dynamics of α-aryl amide and ketone enolates: THF, PMDTA, TMTAN, HMPA, and crypt-solvated lithium enolates, and comparison with phosphazenium analogues.

Journal: The Journal of organic chemistry20100917

Title: Quantum chemical prediction of redox reactivity and degradation pathways for aqueous phase contaminants: an example with HMPA.

Journal: Environmental science & technology20100801

Title: 3,3-Bis[(4-chloro-phen-yl)sulfan-yl]-1-methyl-piperidin-2-one.

Journal: Acta crystallographica. Section E, Structure reports online20100701

Title: Reduction of an hexamethylphosphoramide degradation product: a diazabutadiene.

Journal: Organic letters20091015

Title: On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR.

Journal: Journal of the American Chemical Society20090826

Title: Noninvasive monitoring of HPMA copolymer-RGDfK conjugates by magnetic resonance imaging.

Journal: Pharmaceutical research20090501

Title: A simple synthesis of nitriles from aldoximes.

Journal: The Journal of organic chemistry20090417

Title: Tricyclic pyrone compounds prevent aggregation and reverse cellular phenotypes caused by expression of mutant huntingtin protein in striatal neurons.

Journal: BMC neuroscience20090101

Title: Characterization of CYP2A13*2, a variant cytochrome P450 allele previously found to be associated with decreased incidences of lung adenocarcinoma in smokers.

Journal: Drug metabolism and disposition: the biological fate of chemicals20081101

Title: Anionic Snieckus-Fries rearrangement: solvent effects and role of mixed aggregates.

Journal: Journal of the American Chemical Society20081015

Title: Lewis base-catalyzed conjugate reduction and reductive aldol reaction of alpha,beta-unsaturated ketones using trichlorosilane.

Journal: Chemical communications (Cambridge, England)20080928

Title: Searching for voids in liquids with optical Kerr effect spectroscopy.

Journal: The journal of physical chemistry. B20080724

Title: (1R,4'S)-4-(tert-Butyl-dimethyl-silan-oxy)-1-[2,2-dimethyl-3-(p-tolyl-sulfon-yl)-1,3-oxazolidin-4-yl]but-2-yn-1-ol.

Journal: Acta crystallographica. Section E, Structure reports online20080601

Title: Reactivity of the triple ion and separated ion pair of tris(trimethylsilyl)methyllithium with aldehydes: a RINMR study.

Journal: Journal of the American Chemical Society20080514

Title: catena-Poly[[tetra-kis(hexa-methyl-phos-pho-ramide-κO)bis-(nitrato-κO,O')neodymium(III)] [silver(I)-di-μ(2)-sulfido-tungsten(VI)-di-μ(2)-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20080301

Title: Temperature and length scale dependence of tetraalkylammonium ion-amide interaction.

Journal: The journal of physical chemistry. B20080221

Title: catena-Poly[[tetra-kis(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')lanthanum(III)] [silver(I)-di-μ(2)-sulfido-tungstate(VI)-di-μ(2)-sulfido]].

Journal: Acta crystallographica. Section E, Structure reports online20080201

Title: 5,5'-Bis[(trimethyl-silyl)meth-yl]-2,2'-bipyridine.

Journal: Acta crystallographica. Section E, Structure reports online20080201

Title: Neutral and cationic phosphoramide adducts of silicon tetrachloride: synthesis and characterization of their solution and solid-state structures.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20080101

Title: Diverse reactions of 1,4-dilithio-1,3-dienes with nitriles: facile access to tricyclic Delta1-bipyrrolines, multiply substituted pyridines, siloles, and (Z,Z)-dienylsilanes by tuning of substituents on the butadienyl skeleton.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20080101

Title: Lithium diisopropylamide-mediated reactions of imines, unsaturated esters, epoxides, and aryl carbamates: influence of hexamethylphosphoramide and ethereal cosolvents on reaction mechanisms.

Journal: Journal of the American Chemical Society20071128

Title: Solvent dynamical control of ultrafast ground state electron transfer: implications for Class II-III mixed valency.

Journal: Journal of the American Chemical Society20071024

Title: Simultaneous quantification of cyclophosphamide and its active metabolite 4-hydroxycyclophosphamide in human plasma by high-performance liquid chromatography coupled with electrospray ionization tandem mass spectrometry (LC-MS/MS).

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences20070701

Title: Lithium diisopropylamide solvated by hexamethylphosphoramide: substrate-dependent mechanisms for dehydrobrominations.

Journal: Journal of the American Chemical Society20061206

Title: Synthesis, characterization, and structural determination of polynuclear lithium aggregates and factors affecting their aggregation.

Journal: Inorganic chemistry20060904

Title: Monitoring of the insecticide trichlorfon by phosphorus-31 nuclear magnetic resonance (31P NMR) spectroscopy.

Journal: Analytica chimica acta20060825

Title: Hydrogen-bond effects on the electronic absorption spectrum and evaluation of nonlinear optical properties of an aminobenzodifuranone derivative that exhibits the largest positive solvatochromism.

Journal: Journal of molecular modeling20050901

Title: [Synthesis of substituted 3H-indole quaternary ammonium salt and study on its interaction with bovine serum albumin by fluorescence].

Journal: Guang pu xue yu guang pu fen xi = Guang pu20050601

Title: Exploring SmBr2-, SmI2-, and YbI2-mediated reactions assisted by microwave irradiation.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20050520

Title: Mechanism of anionic dearomatizing reactions of diphenylphosphinamide derivatives: a theoretical and experimental study.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20050506

Title: Probing surface basicity of solid acids with an aminobenzodifurandione dye as the solvatochromic probe.

Journal: The journal of physical chemistry. B20050421

Title: Intramolecular C-H/C-D exchange in cofacially stacked polyfluorenes via electron-induced bond activation.

Journal: Journal of the American Chemical Society20050420

Title: The second cyclopropannulene: cycloprop-[8]annulene.

Journal: Journal of the American Chemical Society20050202

Title: Polycyclooctatetraeneoxy alkane polyanionic polyradicals.

Journal: Journal of the American Chemical Society20050112

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