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65355-14-8,MFCD02093485
Catalog No.:AA003C7P

65355-14-8 | (R)-5,5',6,6',7,7',8,8'-Octahydro[1,1'-binaphthalene]-2,2'-diol

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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003C7P
Chemical Name:
(R)-5,5',6,6',7,7',8,8'-Octahydro[1,1'-binaphthalene]-2,2'-diol
CAS Number:
65355-14-8
Molecular Formula:
C20H22O2
Molecular Weight:
294.3875
MDL Number:
MFCD02093485
SMILES:
Oc1ccc2c(c1c1c(O)ccc3c1CCCC3)CCCC2
Properties
Properties
 
BP:
516.7°C at 760 mmHg  
Form:
Solid  
MP:
165-169 °C(lit.)  
Refractive Index:
50 ° (C=1, CHCl3)  
Stability:
Hygroscopic  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
346  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
22  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
1  
XLogP3:
5.6  

Downstream Synthesis Route

[1]Duursma,Ate;Boiteau,Jean-Guy;Lefort,Laurent;Boogers,JeroenA.F.;DeVries,AndreH.M.;DeVries,JohannesG.;Minnaard,AdriaanJ.;Feringa,BenL.[JournalofOrganicChemistry,2004,vol.69,#23,p.8045-8052]

[2]Gao,Guorui;Du,Shaozhi;Yang,Yang;Lei,Xue;Huang,Haizhou;Chang,Mingxin[Molecules,2018,vol.23,#9]

[1]Duursma,Ate;Boiteau,Jean-Guy;Lefort,Laurent;Boogers,JeroenA.F.;DeVries,AndreH.M.;DeVries,JohannesG.;Minnaard,AdriaanJ.;Feringa,BenL.[JournalofOrganicChemistry,2004,vol.69,#23,p.8045-8052]

[1]Harada,Hitoshi;Thalji,ReemaK.;Bergman,RobertG.;Ellman,JonathanA.[JournalofOrganicChemistry,2008,vol.73,#17,p.6772-6779]

[1]Hrdina,Radim;Guenee,Laure;Moraleda,Delphine;Lacour,Jeroime[Organometallics,2013,vol.32,#2,p.473-479]

[1]Lee,Pin-Sheng;Yoshikai,Naohiko[OrganicLetters,2015,vol.17,#1,p.22-25]

[2]Zhu,Deng;Yu,Lu;Luo,Hui-Yun;Xue,Xiao-Song;Chen,Zhi-Min[AngewandteChemie-InternationalEdition,2022,vol.61,#42][Angew.Chem.,2022,vol.134,#42]

Literature

Title: (R)-2'-Benz-yloxy-5,5',6,6',7,7',8,8'-octa-hydro-1,1'-binaphthyl-2-ol.

Journal: Acta crystallographica. Section E, Structure reports online 20100201

Title: Highly efficient synthesis of optically pure 5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol and -naphthylamine derivatives by partial hydrogenation of 1,1'-binaphthyls with carbon nanofiber supported ruthenium nanoparticles.

Journal: The Journal of organic chemistry 20071221

Title: Chiral separation of 1,1'-bi-2-naphthol and its analogue on molecular imprinting monolithic columns by HPLC.

Journal: Journal of separation science 20051101

Title: A highly enantioselective hetero-Diels-Alder reaction of aldehydes with Danishefsky's diene catalyzed by chiral titanium(IV) 5,5',6,6',7,7',8,8'-octahydro-1,1'-bi-2-naphthol complexes.

Journal: The Journal of organic chemistry 20020405

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SDS
Tags:65355-14-8 Molecular Formula|65355-14-8 MDL|65355-14-8 SMILES|65355-14-8 (R)-5,5',6,6',7,7',8,8'-Octahydro[1,1'-binaphthalene]-2,2'-diol