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77-48-5,MFCD00003189
Catalog No.:AA003DGB

77-48-5 | 1,3-Dibromo-5,5-dimethylimidazolidine-2,4-dione

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  • Technical Information
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  • Technical Information
  • Properties
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Technical Information
Catalog Number:
AA003DGB
Chemical Name:
1,3-Dibromo-5,5-dimethylimidazolidine-2,4-dione
CAS Number:
77-48-5
Molecular Formula:
C5H6Br2N2O2
Molecular Weight:
285.9213
MDL Number:
MFCD00003189
SMILES:
BrN1C(=O)N(C(C1=O)(C)C)Br
NSC Number:
33305
Properties
Properties
 
BP:
250.2 °C at 760 mmHg  
Form:
Solid  
MP:
197-199 °C (dec.)(lit.)  
Refractive Index:
1.6220 (estimate)  
Solubility:
1g/l  
Stability:
Moisture Sensitive  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
229  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
11  
Hydrogen Bond Acceptor Count:
2  
XLogP3:
1.5  

Literature

Title: Intramolecular alkene electrophilic bromination initiated ipso-bromocyclization for the synthesis of functionalized azaspirocyclohexadienones.

Journal: Organic letters 20120706

Title: C3-symmetric trisimidazoline-catalyzed enantioselective bromolactonization of internal alkenoic acids.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120702

Title: Organocatalysis as a safe practical method for the stereospecific dibromination of unsaturated compounds.

Journal: Organic letters 20120406

Title: Synthesis of geminal difluorides by oxidative desulfurization-difluorination of alkyl aryl thioethers with halonium electrophiles in the presence of fluorinating reagents and its application for 18F-radiolabeling.

Journal: The Journal of organic chemistry 20100917

Title: Effectiveness of 1,3-dibromo-5,5 dimethylhydantoin on reduction of Escherichia coli O157:H7- and Salmonella-inoculated fresh meat.

Journal: Journal of food protection 20090101

Title: Lewis acid catalyzed benzylic bromination.

Journal: Chemistry, an Asian journal 20080901

Title: Short intermolecular N-Br...O=C contacts in 1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione.

Journal: Acta crystallographica. Section C, Crystal structure communications 20070701

Title: Quantification of dibromodimethylhydantoin disinfectants in water by chemiluminescent method.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20070301

Title: An efficient, stereoselective synthesis of the hydroxyethylene dipeptide isostere core for the HIV protease inhibitor A-792611.

Journal: The Journal of organic chemistry 20060707

Title: An efficient chemoenzymatic approach to (S)-gamma-fluoroleucine ethyl ester.

Journal: The Journal of organic chemistry 20050318

Title: Facile exchange of glycosyl S,S-acetals to their O,O-acetals and preparation of glycofuranosides from acyclic glycosyl S,S-acetals under metal-free reaction conditions in the presence of 1,3-dibromo-5,5-dimethylhydantoin.

Journal: Carbohydrate research 20050227

Title: Highly efficient catalytic aerobic oxidations of benzylic alcohols in water.

Journal: The Journal of organic chemistry 20050121

Title: Determination of iodine values using 1,3-dibromo-5,5-dimethylhydantoin (DBH) and ethyl acetate as solvent. Analytical methods with DBH in respect to environmental and economical concern, part 18.

Journal: Die Pharmazie 20040801

Title: Cetylpyridinium tetrachlorozincate as standard for tenside titration. Analytical methods with 1,3-dibromo-5,5-dimethylhydantoin (DBH) in respect to environmental and economical concern, part 19.

Journal: Die Pharmazie 20040801

Title: Hypohalites and related oxidants as chemiluminescence reagents: a review.

Journal: Luminescence : the journal of biological and chemical luminescence 20040101

Title: Synthesis of fluorinated analogs of myristic acid as potential inhibitors of Egyptian armyworm (Spodoptera littoralis) delta11 desaturase.

Journal: Lipids 20030801

Title: Determination of iodine values using 1,3-dibromo-5,5-dimethylhydantoin (DBH) without the employment of chlorinated hydrocarbons. Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern. Part 17.

Journal: Die Pharmazie 20020801

Title: Determination of organically bound iodine by reductive mineralization with aluminium powder. Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern. Part 16.

Journal: Die Pharmazie 20020701

Title: 1,3-Dibromo-5,5-dimethylhydantoin (DBH) as oxidant and precipitant for drug identification according to PH. EUR Analytical methods of pharmacopoeias with DBH in respect of environmental and economical concern, Part 15(1).

Journal: Die Pharmazie 20020601

Title: Application of 1,3-dibromo-5,5-dimethylhydantoin (DBH) instead of bromine gas or bromine water decolorization for drug identification according to PH. EUR. Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern, Part 14.

Journal: Die Pharmazie 20020501

Title: Determination of propylthiouracil using 1,3-dibromo-5,5-dimethylhydantoin (DBH): analytical methods of pharmacopeias with DBH in respect to environmental and economical concern: part 9.

Journal: Journal of pharmaceutical and biomedical analysis 20020415

Title: Determination of selenium sulfide using 1,3-dibromo-5,5-dimethylhydantoin (DBH). Analytical methods of pharmacopeias with DBH in respect to environmental and economical concern Part 11.

Journal: Journal of pharmaceutical and biomedical analysis 20020415

Title: Determination of iodine values according to Hanus using 1,3-dibromo-5,5-dimethylhydantoin (DBH): analytical methods of pharmacopeias with DBH: part 7.

Journal: Journal of pharmaceutical and biomedical analysis 20020401

Title: Replacement of cyanogen bromide solution PH. EUR. with 1,3-dibromo-5,5-dimethylhydantoin (DBH). Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern, Part 13.

Journal: Die Pharmazie 20020401

Title: Colour reactions of PH. EUR. for identification of drugs using 1,3-dibromo-5,5-dimethylhydantoin (DBH) instead of elemental bromine. Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern, Part 10.

Journal: Die Pharmazie 20020301

Title: Determination of iron limiting values according to PH. EUR. using 1,3-dibromo-5,5-dimethylhydantoin (DBH) instead of elemental bromine. Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern. Part 8.

Journal: Die Pharmazie 20020101

Title: Determination of phenol and resorcinol using 1,3-dibromo-5,5-dimethylhydantoin (DBH) analogous to the Koppeschaar reaction. Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern, Part 6.

Journal: Die Pharmazie 20011001

Title: Identification of lactate. Analytical methods of pharmacopoeias with DBH in respect to environmental and economical concern, Part 4.

Journal: Die Pharmazie 20010701

Title: Determination of iodide with 1,3-dibromo-5,5-dimethylhydantoin (DBH) in comparison with the ICl-method. Analytical methods of pharmacopeias with DBH in respect to environmental and economical concern. Part 3.

Journal: Journal of pharmaceutical and biomedical analysis 20010601

Title: An S, et al. Small-molecule PROTACs: An emerging and promising approach for the development of targeted therapy drugs. EBioMedicine. 2018 Oct;36:553-562

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Tags:77-48-5 Molecular Formula|77-48-5 MDL|77-48-5 SMILES|77-48-5 1,3-Dibromo-5,5-dimethylimidazolidine-2,4-dione