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2683-82-1,MFCD00009627
Catalog No.:AA003FD4

2683-82-1 | 2,3,7,8,12,13,17,18-Octaethyl-21h,23h-porphine

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100mg
>95.0%(N)
in stock  
$96.00   $68.00
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250mg
≥ 99% (HPLC)
in stock  
$186.00   $130.00
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1g
97%
in stock  
$321.00   $225.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003FD4
Chemical Name:
2,3,7,8,12,13,17,18-Octaethyl-21h,23h-porphine
CAS Number:
2683-82-1
Molecular Formula:
C36H46N4
Molecular Weight:
534.7772
MDL Number:
MFCD00009627
SMILES:
CCC1=C(CC)C2=Cc3[nH]c(c(c3CC)CC)C=C3N=C(C=c4[nH]c(=CC1=N2)c(CC)c4CC)C(=C3CC)CC
Properties
Properties
 
Form:
Solid  
MP:
322℃  
Storage:
Room Temperature;  

Computed Properties
 
Complexity:
725  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
40  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
8  
XLogP3:
8.5  

Downstream Synthesis Route

[1]Fischer;Baeumler[JustusLiebigsAnnalenderChemie,1929,vol.468,p.61,74]

[2]Tang;Verkade[JournalofOrganicChemistry,1994,vol.59,#25,p.7793-7802]

[3]Milgram,BenjaminC.;Eskildsen,Katrine;Richter,StevenM.;Scheidt,W.Robert;Scheidt,KarlA.[JournalofOrganicChemistry,2007,vol.72,#10,p.3941-3944]

109-99-9    2683-82-1   
C36H44N4(2-)*4C4H8O*2Li(1+) 

[1]Arnold,John[JournaloftheChemicalSociety.Chemicalcommunications,1990,#14,p.976-978]

[1]Sessler,JonathanL.;Mozaffari,Azadeh;Johnson,MartinR.[OrganicSyntheses,1992,vol.70,p.68-68]

[2]Rohrer;Ocampo;Callot[Synthesis,1994,#9,p.923-925]

[3]Tang;Verkade[JournalofOrganicChemistry,1994,vol.59,#25,p.7793-7802]

[4]Alexy,EricJ.;Hintz,CarlW.;Hughes,HubertM.;Taniguchi,Masahiko;Lindsey,JonathanS.[OrganicandBiomolecularChemistry,2015,vol.13,#39,p.10025-10031]

(2,3,7,8,12,13,17,18-octaethylporphyrinato)nickel(II) 
  2683-82-1 

[1]Battersby,AlanR.;Jones,Keith;Snow,RogerJ.[AngewandteChemie,1983,vol.95,#9,p.742-743]

[1]Andrews,LauraE.;Bonnett,Raymond;Ridge,RichardJ.;Appelman,EvanH.[JournaloftheChemicalSociety.PerkintransactionsI,1983,#1,p.103-107]

Literature

Title: Complexes of Ir(III)-octaethylporphyrin with peptides as probes for sensing cellular O2.

Journal: Chembiochem : a European journal of chemical biology 20120529

Title: Spectroscopic and theoretical insights on fullerene-octaethylporphyrin self assembled non-covalent conjugates studied in solution.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120501

Title: Lifetime-based photoacoustic oxygen sensing in vivo.

Journal: Journal of biomedical optics 20120501

Title: Optical acetylcholine sensor based on free base porphyrin as a chromoionophore.

Journal: The Analyst 20110921

Title: Electron induced dissociation (EID) tandem mass spectrometry of octaethylporphyrin and its iron(III) complex.

Journal: Chemical communications (Cambridge, England) 20110107

Title: Oxygen sensitive microwells.

Journal: Lab on a chip 20101207

Title: Polythiophene-fullerene based photodetectors: tuning of spectral response and application in photoluminescence based (bio)chemical sensors.

Journal: Advanced materials (Deerfield Beach, Fla.) 20101001

Title: Environment-responsive upconversion based on dendrimer-supported efficient triplet-triplet annihilation in aqueous media.

Journal: Chemical communications (Cambridge, England) 20100628

Title: Phosphorescent sensing of carbon dioxide based on secondary inner-filter quenching.

Journal: Analytica chimica acta 20091123

Title: Direct evidence for mode-specific vibrational energy relaxation from quantum time-dependent perturbation theory. III. The nu(4) and nu(7) modes of nonplanar nickel porphyrin models.

Journal: The Journal of chemical physics 20090607

Title: Stepwise conversion of two pyrrole moieties of octaethylporphyrin to pyridin-3-ones: synthesis, mass spectral, and photophysical properties of mono and bis(oxypyri)porphyrins.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20090602

Title: Highly reactive porphyrin-iron-oxo derivatives produced by photolyses of metastable porphyrin-iron(IV) diperchlorates.

Journal: Journal of the American Chemical Society 20090225

Title: Controlled self-assembly of functional metal octaethylporphyrin 1 D nanowires by solution-phase precipitative method.

Journal: Chemistry, an Asian journal 20081113

Title: Intermolecular dynamics in crystalline iron octaethylporphyrin (FeOEP).

Journal: The journal of physical chemistry. B 20081009

Title: Modulation of metal displacements in a saddle distorted macrocycle: synthesis, structure, and properties of high-spin Fe(III) porphyrins and implications for the hemoproteins.

Journal: Inorganic chemistry 20080915

Title: Regioselective transformation of octaethylporphyrin into a phytoporphyrin analogue.

Journal: The Journal of organic chemistry 20070914

Title: Optical fluoride sensor based on monomer-dimer equilibrium of scandium(III)-octaethylporphyrin in a plasticized polymeric film.

Journal: Analytica chimica acta 20070829

Title: Density functional theory studies on the electronic and vibrational spectra of octaethylporphyrin diacid.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20070801

Title: Preparation and characterization of polymeric micelles for solubilization of poorly soluble anticancer drugs.

Journal: European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V 20061101

Title: State preparation and excited electronic and vibrational behavior in hemes.

Journal: The journal of physical chemistry. B 20061012

Title: Single site electronic spectroscopy of free base octaethylporphyrin, octaethychlorin and their diacids in n-octane at 298K and 7K.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20060601

Title: Observation of a photoexcited state of a paramagnetic transition metal complex by time-resolved electron paramagnetic resonance spectroscopy.

Journal: Physical chemistry chemical physics : PCCP 20060514

Title: Quenching platinum octaethylporphine phosphorescence in solution by poly(ferrocenylsilane).

Journal: Photochemistry and photobiology 20060101

Title: Nonplanar heme deformations and excited state displacements in nickel porphyrins detected by Raman spectroscopy at soret excitation.

Journal: The journal of physical chemistry. A 20051124

Title: Fluoride-selective optical sensor based on aluminum(III)-octaethylporphyrin in thin polymeric film: further characterization and practical application.

Journal: Analytical chemistry 20051015

Title: Efficient electrochemical conversion of carbon monoxide by rhodium octaethylporphyrin adsorbed on carbon black.

Journal: Inorganic chemistry 20050919

Title: Study and application of a controlled-potential electrochemistry-electrospray emitter for electrospray mass spectrometry.

Journal: Analytical chemistry 20050715

Title: Highly selective optical fluoride ion sensor with submicromolar detection limit based on aluminum(III) octaethylporphyrin in thin polymeric film.

Journal: Journal of the American Chemical Society 20050420

Title: Electrochemical redox control of ferrocene using a supramolecular assembly of ferrocene-linked C(60) derivative and metallooctaethylporphyrin array on a Au(111) electrode.

Journal: Langmuir : the ACS journal of surfaces and colloids 20041207

Title: Inner-sphere electron-transfer reorganization energies of zinc porphyrins.

Journal: Journal of the American Chemical Society 20041201

Title: Octaethylporphyrin and expanded porphyrin complexes containing coordinated BF2 groups.

Journal: Chemical communications (Cambridge, England) 20040507

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Tags:2683-82-1 Molecular Formula|2683-82-1 MDL|2683-82-1 SMILES|2683-82-1 2,3,7,8,12,13,17,18-Octaethyl-21h,23h-porphine