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Home Other Building Blocks 137915-37-8
137915-37-8,MFCD00799597
Catalog No.:AA003N8W

137915-37-8 | 6-O-(Triisopropylsilyl)-d-glucal

Pack Size
Purity
Availability
Price(USD)
Quantity
  
25mg
>95.0%(GC)
2 weeks  
$227.00   $159.00
- +
100mg
>95.0%(GC)
2 weeks  
$567.00   $397.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003N8W
Chemical Name:
6-O-(Triisopropylsilyl)-d-glucal
CAS Number:
137915-37-8
Molecular Formula:
C15H30O4Si
Molecular Weight:
302.4818
MDL Number:
MFCD00799597
SMILES:
CC([Si](C(C)C)(C(C)C)OC[C@H]1OC=C[C@H]([C@@H]1O)O)C
Properties
Properties
 
BP:
361.9°C at 760 mmHg  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
306  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
3  
Heavy Atom Count:
20  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
6  

Downstream Synthesis Route

[1]Grinstaff,MarkW.;Haque,Farihah;Lu,Wei;Varghese,Maria[Biomacromolecules,2022]

[2]Lellouche;Koeller[JournalofOrganicChemistry,2001,vol.66,#3,p.693-696]

[3]Balmond,EdwardI.;Benito-Alifonso,David;Coe,DianeM.;Alder,RogerW.;McGarrigle,EoghanM.;Galan,M.Carmen[AngewandteChemie-InternationalEdition,2014,vol.53,#31,p.8190-8194][Angew.Chem.,2014,vol.126,#31,p.8329-8333,5]

[4]CurrentPatentAssignee:GUIZHOUMEDICALUNIVERSITY;OCEANUNIVERSITYOFCHINA-CN106146475,2016,ALocationinpatent:Paragraph0752

[5]CurrentPatentAssignee:OCEANUNIVERSITYOFCHINA;GUIZHOUMEDICALUNIVERSITY-CN106083830,2016,ALocationinpatent:Paragraph0754;0755

[6]Schell,Peter;Orgueira,HernanA.;Roehrig,Susanne;Seeberger,PeterH.[TetrahedronLetters,2001,vol.42,#23,p.3811-3814]

[7]Mikula,Hannes;Matscheko,Dominik;Schwarz,Markus;Hametner,Christian;Fröhlich,Johannes[CarbohydrateResearch,2013,vol.370,p.19-23]

[8]Balijepalli,AnantS.;Sabatelle,RobertC.;Chen,Mingfu;Suki,Bela;Grinstaff,MarkW.[AngewandteChemie-InternationalEdition,2020,vol.59,#2,p.704-710][Angew.Chem.,2020,vol.132,#2,p.714-720,7]

Literature
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SDS
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Tags:137915-37-8 Molecular Formula|137915-37-8 MDL|137915-37-8 SMILES|137915-37-8 6-O-(Triisopropylsilyl)-d-glucal