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142-45-0,MFCD00004362
Catalog No.:AA003NL3

142-45-0 | But-2-ynedioic acid

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  • Technical Information
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Technical Information
Catalog Number:
AA003NL3
Chemical Name:
But-2-ynedioic acid
CAS Number:
142-45-0
Molecular Formula:
C4H2O4
Molecular Weight:
114.0563
MDL Number:
MFCD00004362
SMILES:
OC(=O)C#CC(=O)O
Properties
Properties
 
BP:
362.4°C at 760 mmHg  
Form:
Solid  
MP:
180-187 °C (dec.)(lit.)  
Refractive Index:
1.5260 (estimate)  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
161  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
8  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
2  
XLogP3:
0.1  

Literature

Title: Facile synthesis of dispirooxindole-fused heterocycles via domino 1,4-dipolar addition and Diels-Alder reaction of in situ generated Huisgen 1,4-dipoles.

Journal: Organic letters 20121019

Title: Chiral cyclopalladated complex promoted asymmetric synthesis of diester-substituted P,N-ligands via stepwise hydrophosphination and hydroamination reactions.

Journal: Dalton transactions (Cambridge, England : 2003) 20120507

Title: Dimethyl 2-[23-oxo-22,24-diphenyl-8,11,14-trioxa-25-aza-tetra-cyclo-[19.3.1.0(2,7).0(15,20)]penta-cosa-2,4,6,15(20),16,18-hexaen-25-yl]but-2-enedioate.

Journal: Acta crystallographica. Section E, Structure reports online 20120501

Title: Three-component reactions of isocyanides, dialkyl acetylenedicarboxylates, and trans-cinnamoyl chlorides for the synthesis of highly functionalized 2-vinyl furans.

Journal: Molecular diversity 20120201

Title: Diversity oriented syntheses of conventional heterocycles by smart multi component reactions (MCRs) of the last decade.

Journal: Molecules (Basel, Switzerland) 20120120

Title: Efficient synthesis and in vitro antitubercular activity of 1,2,3-triazoles as inhibitors of Mycobacterium tuberculosis.

Journal: Bioorganic & medicinal chemistry letters 20111215

Title: Synthesis of 3,4-dihydropyridin-2(1H)-ones and 3,4-dihydro-2H-pyrans via Four-component reactions of aromatic aldehydes, cyclic 1,3-carbonyls, arylamines, and dimethyl acetylenedicarboxylate.

Journal: ACS combinatorial science 20110711

Title: Trimethyl-3-meth-oxy-4-oxo-5-triphenyl-phospho-ranyl-idene-cyclo-pent-1-ene-1,2,3-tricarboxyl-ate.

Journal: Acta crystallographica. Section E, Structure reports online 20101101

Title: Optimized synthesis of tetrafluoroterephthalic acid: a versatile linking ligand for the construction of new coordination polymers and metal-organic frameworks.

Journal: Inorganic chemistry 20101018

Title: Synthesis of symmetrical and unsymmetrical diarylalkynes from propiolic acid using palladium-catalyzed decarboxylative coupling.

Journal: The Journal of organic chemistry 20100917

Title: Synthesis of polysubstituted dihydropyridines by four-component reactions of aromatic aldehydes, malononitrile, arylamines, and acetylenedicarboxylate.

Journal: Organic letters 20100820

Title: Protruding interfacial OH groups and 'on-water' heterogeneous catalysis.

Journal: Journal of physics. Condensed matter : an Institute of Physics journal 20100721

Title: Thieno[2,3-d]pyrimidines in the synthesis of antitumor and antioxidant agents.

Journal: Archiv der Pharmazie 20100501

Title: Structures of strontium diformate and strontium fumarate. A synchrotron powder diffraction study.

Journal: Acta crystallographica. Section B, Structural science 20090801

Title: Silver nanoparticles and graphitic carbon through thermal decomposition of a silver/acetylenedicarboxylic salt.

Journal: Nanoscale research letters 20090101

Title: Three-component synthesis of dialkyl 2-(alkylimino-methylene)3- (2,2,5-trimethyl-4,6-dioxo-1,3-dioxan-5-yl)-succinates.

Journal: Molecular diversity 20060501

Title: Three-component synthesis of functionalized 5-oxo-4,5-dihydroindeno[1,2-b]pyrans.

Journal: Molecular diversity 20060501

Title: Unsymmetrical photodimerization of a 9-aminomethylanthracene in the crystalline salt.

Journal: The Journal of organic chemistry 20060428

Title: Interaction of aryloxychlorocarbenes with acetylenedicarboxylate: novel formation of polyfunctional butadienes and 8-oxatricyclo[3.2.1.0(2.4)]oct-6-enes.

Journal: The Journal of organic chemistry 20050610

Title: An open-framework rare-earth acetylenedicarboxylate: MIL-95, Eu(III)2(H2O)2(CO3)2.{O2C-C2-CO2}.{H2O}x.

Journal: Inorganic chemistry 20050207

Title: Polyunsaturated dicarboxylate tethers connecting dimolybdenum redox and chromophoric centers: absorption spectra and electronic structures.

Journal: Journal of the American Chemical Society 20030507

Title: In situ proton NMR analysis of alpha-alkynoate biotransformations. From 'invisible' substrates to detectable metabolites.

Journal: European journal of biochemistry 20030401

Title: [Cu[C2(COO)2](H2O)3].H2O, the first copper complex of acetylenedicarboxylic acid.

Journal: Acta crystallographica. Section C, Crystal structure communications 20030401

Title: Sr[C2(COO)2]: the first anhydrous salt of acetylenedicarboxylic acid.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20021004

Title: [Cd[C2(COO)2](H2O)3].H2O, the first cadmium salt of acetylenedicarboxylic acid.

Journal: Acta crystallographica. Section C, Crystal structure communications 20020901

Title: A new synthesis of oxadiazole, thiazolidinone, N-phthalimidoamino carbonyl and arylidene derivatives with potential antimicrobial activity.

Journal: Archiv der Pharmazie 20020601

Title: The simplest supramolecular complexes containing pairs of Mo(2)(formamidinate)(3) units linked with various dicarboxylates: preparative methods, structures, and electrochemistry.

Journal: Inorganic chemistry 20010312

Title: Supramolecular squares with Mo2(4+) corners.

Journal: Inorganic chemistry 20010129

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