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87-88-7,MFCD00001596
Catalog No.:AA003OP9

87-88-7 | Chloranilic acid

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5g
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25g
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100g
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003OP9
Chemical Name:
Chloranilic acid
CAS Number:
87-88-7
Molecular Formula:
C6H2Cl2O4
Molecular Weight:
208.9837
MDL Number:
MFCD00001596
SMILES:
C1(=C(C(=O)C(=C(C1=O)Cl)O)Cl)O
NSC Number:
6108
Properties
Properties
 
BP:
300.3°C at 760 mmHg  
Form:
Solid  
MP:
≥300 °C(lit.)  
Refractive Index:
1.4570 (estimate)  
Storage:
Room Temperature;Keep in dry area;  

Computed Properties
 
Complexity:
306  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
12  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
2  
XLogP3:
1.4  

Downstream Synthesis Route
87-88-7    564480-29-1   
C6H2Cl2O4*C9H6N2S4 

[1]Murata,Tsuyoshi;Morita,Yasushi;Yakiyama,Yumi;Fukui,Kozo;Yamochi,Hideki;Saito,Gunzi;Nakasuji,Kazuhiro[JournaloftheAmericanChemicalSociety,2007,vol.129,#35,p.10837-10846]

[1]InorganicaChimicaActa,2001,vol.318,p.127-134

Iron(III)nitratenonahydrate 
  12126-50-0    87-88-7    493029-44-0 

[1]JournaloftheAmericanChemicalSociety,2003,vol.125,p.221-232

hexaaquairon(III)perchlorate 
  4199-89-7    87-88-7   
Fe2(C6Cl2O4)(ClC12H7N2)4(4+)*4ClO4(1-)=Fe2(C6Cl2O4)(ClC12H7N2)4(ClO4)4 

[1]Polyhedron,1998,vol.17,p.1423-1427

87-88-7    123-03-5   
bis(hexadecylpyridinium)bis(3,6-dichloro-4,5-dihydroxy-3,5-cyclohexadiene-1,2-dionato-κ(2)O(4),O(5))beryllium 

[1]ActaCrystallographica,SectionC:CrystalStructureCommunications,1995,vol.51,p.190-193

Literature

Title: Spectrophotometric, FTIR and theoretical studies of the charge-transfer complexes between isoniazid (pyridine-4-carboxylic acid hydrazide) and the acceptors (p-chloranil, chloranilic acid and tetracyanoethylene) in acetonitrile, their association constants, thermodynamic properties and other related properties.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120901

Title: Spectrophotometric, Fourier transform infrared spectroscopic and theoretical studies of the charge-transfer complexes between methyldopa [(S)-2 amino-3-(3,4-dihydroxyphenyl)-2-methyl propanoic acid] and the acceptors (chloranilic acid, o-chloranil and dichlorodicyanobenzoquinone) in acetonitrile and their thermodynamic properties.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120615

Title: Molecular characterization of chloranilic acid degradation in Pseudomonas putida TQ07.

Journal: Journal of microbiology (Seoul, Korea) 20111201

Title: Intermolecular hydrogen bond complexes by in situ charge transfer complexation of o-tolidine with picric and chloranilic acids.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20110801

Title: A partial proton transfer in hydrogen bond O-H···O in crystals of anhydrous potassium and rubidium complex chloranilates.

Journal: The journal of physical chemistry. A 20110414

Title: Spectroscopic characterization of charge-transfer complexes of morpholine with chloranilic and picric acids in organic media: crystal structure of bis(morpholinium 2,4,6-trinitrocyclohexanolate).

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20100201

Title: [Spectrophotometric and HPLC evaluation of ceftazidime stability].

Journal: Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi 20100101

Title: Utility of certain sigma- and pi-acceptors for the spectrophotometric determination of ganciclovir in pharmaceutical formulations.

Journal: Talanta 20091115

Title: Exploiting pi-acceptors for the determination of thyroid hormones (T3 and T4) using a single interface flow system.

Journal: Talanta 20090915

Title: Vanadium-induced nucleophilic IPSO substitutions in a coordinated tetrachlorosemiquinone ring: formation of the chloranilate anion as a bridging ligand.

Journal: Inorganic chemistry 20090202

Title: Spectroscopic and structural characterization of the charge-transfer interaction of N,N'-bis-alkyl derivatives of 1,4,6,8-naphthalenediimide with chloranilic and picric acids.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20080901

Title: Spectrophotometric determination of terfenadine in pharmaceutical preparations by charge-transfer reactions.

Journal: Talanta 20080615

Title: Oxidative double dehalogenation of tetrachlorocatechol by a bio-inspired CuII complex: formation of chloranilic acid.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: Spin exchange effects on the physicochemical properties of tetraoxolene-bridged bimetallic complexes.

Journal: Inorganic chemistry 20070416

Title: Synthesis, structure, and magnetic properties of valence ambiguous dinuclear antiferromagnetically coupled cobalt and ferromagnetically coupled iron complexes containing the chloranilate(2-) and the significantly stronger coupling chloranilate(*3-) radical trianion.

Journal: Journal of the American Chemical Society 20070227

Title: Hydrogen bonding in two solid phases of phenazine-chloranilic acid (1/1) determined at 170 and 93 K.

Journal: Acta crystallographica. Section C, Crystal structure communications 20070101

Title: Indirect flow-injection spectrophotometric determination of meloxicam, tenoxicam and piroxicam in pharmaceutical formulations.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20061201

Title: [Spectrophotometric determination of azithromycin by charge transfer reaction].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20060501

Title: Spectrophotometric analysis of selective serotonin reuptake inhibitors based on formation of charge-transfer complexes with tetracyanoquinodimethane and chloranilic acid.

Journal: Journal of AOAC International 20060101

Title: Preparation and spectroscopic studies on charge-transfer complexes of 2,2'-bipyridine with picric and chloranilic acids.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20051101

Title: Reductions by aquatitanium(II).

Journal: Dalton transactions (Cambridge, England : 2003) 20050521

Title: Application of pi-acceptors to the spectrophotometric determination of lisinopril in commercial dosage forms.

Journal: Farmaco (Societa chimica italiana : 1989) 20050101

Title: [Fluorescence spectroscopy determination of lomefloxacin by charge transfer complex formation with chloranilic acid].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20041201

Title: Validated spectrophotometric methods for the determination of amiodarone hydrochloride in commercial dosage forms using p-chloranilic acid and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20040801

Title: Spectrophotometric determination of nizatidine and ranitidine through charge transfer complex formation.

Journal: Archives of pharmacal research 20040701

Title: Determination of some psychotropic phenothiazine drugs by charge-transfer complexation reaction with chloranilic acid.

Journal: Farmaco (Societa chimica italiana : 1989) 20040401

Title: Thermodynamic consideration of the charge transfer interaction of the donor: acceptor type between chloranilic acid and haloperidol.

Journal: Chemical & pharmaceutical bulletin 20040301

Title: Spectroscopic analytical study for the charge-transfer complexation of certain cephalosporins with chloranilic acid.

Journal: Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 20030201

Title: Use of pi-acceptors for spectrophotometric determination of dicyclomine hydrochloride.

Journal: Journal of AOAC International 20030101

Title: Cloning and characterization of a FAD-monooxygenase gene ( cadA) involved in degradation of chloranilic acid (2,5-dichloro-3,6-dihydroxybenzo-1,4-quinone) in Pseudomonas putida TQ07.

Journal: Applied microbiology and biotechnology 20020801

Title: Physico-chemical studies on the charge-transfer complex formed between sulfadoxine and pyrimethamine with chloranilic acid.

Journal: Journal of pharmaceutical and biomedical analysis 20020720

Title: Spectrophotometric determination of ciprofloxacin, enrofloxacin and pefloxacin through charge transfer complex formation.

Journal: Journal of pharmaceutical and biomedical analysis 20020101

Title: Spectrophotometric determination of nikethamide by charge--transfer complexation with chloranilic acid.

Journal: Bollettino chimico farmaceutico 20020101

Title: Detection of alpha-methyldopa on thin-layer plates using pi-acceptors in 1,4-dioxane.

Journal: Bollettino chimico farmaceutico 20020101

Title: Studies of the complexation of chloranilic acid with proguanil.

Journal: Bollettino chimico farmaceutico 20010101

Title: Quantitative determination of famotidine through charge-transfer complexation with chloranilic acid.

Journal: Bollettino chimico farmaceutico 20010101

Title: Spectrophotometric and some thermodynamic parameters of the charge transfer complexation between chloranilic acid and chlorpheniramine.

Journal: Bollettino chimico farmaceutico 20010101

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