Home Boronic Acids 871125-68-7
871125-68-7,MFCD07784374
Catalog No.:AA003USU

871125-68-7 | Trans-2-(3-methoxyphenyl)vinylboronic acid pinacol ester

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250mg
95%
in stock  
$55.00   $39.00
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1g
95%
in stock  
$149.00   $104.00
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5g
95%
in stock  
$600.00   $420.00
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  • Technical Information
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  • Downstream Synthesis Route
  • Literature
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
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Technical Information
Catalog Number:
AA003USU
Chemical Name:
Trans-2-(3-methoxyphenyl)vinylboronic acid pinacol ester
CAS Number:
871125-68-7
Molecular Formula:
C15H21BO3
Molecular Weight:
260.1364
MDL Number:
MFCD07784374
SMILES:
COc1cccc(c1)/C=C/B1OC(C(O1)(C)C)(C)C
Properties
Properties
 
BP:
313.5°C at 760 mmHg  
Form:
Solid  
MP:
36-42°C(lit.);  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
322  
Covalently-Bonded Unit Count:
1  
Defined Bond Stereocenter Count:
1  
Heavy Atom Count:
19  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
3  

Downstream Synthesis Route

[1]Kumar,GobbillaSai;Moorthy,Shruti;Karmakar,Himadri;Singh,SaurabhKumar;Panda,TarunK.[EuropeanJournalofInorganicChemistry,2022,vol.2022,#2]

[2]Liu,Jichao;Wu,Caiyan;Hu,Tinghui;Yang,Wei;Xie,Yaoyao;Shi,Yinyin;Liu,Qianrui;Shao,Yinlin;Zhang,Fangjun[JournalofOrganicChemistry,2022,vol.87,#5,p.3442-3452]

[3]Magre,Marc;Maity,Bholanath;Falconnet,Alban;Cavallo,Luigi;Rueping,Magnus[AngewandteChemie-InternationalEdition,2019,vol.58,#21,p.7025-7029][Angew.Chem.,2019,vol.131,#21,p.7099-7103,5]

[4]Wang,YanongD.;Kimball,Gregory;Prashad,AmarS.;Wang,Yan[TetrahedronLetters,2005,vol.46,#50,p.8777-8780]

[5]Arnaud,Alexandre;Doléans-Jordheim,Anne;Gioia,Bruna;Radix,Sylvie;Rocheblave,Luc;Walchshofer,Nadia[TetrahedronLetters,2020]

[1]CurrentPatentAssignee:Novartis(w/oSandoz);NOVARTISAG-WO2008/25512,2008,A1Locationinpatent:Page/Pagecolumn39-40

[1]Locationinpatent:schemeortableNiu,Chuansheng;Boschelli,DianeH.;Tumey,L.Nathan;Bhagirath,Niala;Subrath,Joan;Shim,Jaechul;Wang,Yan;Wu,Biqi;Eid,Clark;Lee,Julie;Yang,Xiaoke;Brennan,Agnes;Chaudhary,Divya[BioorganicandMedicinalChemistryLetters,2009,vol.19,#20,p.5829-5832]

768-70-7    73183-34-3    871125-68-7   
2-(1-(3-methoxyphenyl)vinyl)-4,4,5,5-tetramethyl-1,3-dioxa-2-borolane 

[1]Jang,Hwanjong;Zhugralin,AdilR.;Lee,Yunmi;Hoveyda,AmirH.[JournaloftheAmericanChemicalSociety,2011,vol.133,#20,p.7859-7871]

[2]Zhang,Pinglu;MeijideSuárez,Jorge;Driant,Thomas;Derat,Etienne;Zhang,Yongmin;Ménand,Mickaël;Roland,Sylvain;Sollogoub,Matthieu[AngewandteChemie-InternationalEdition,2017,vol.56,#36,p.10821-10825][Angew.Chem.,2017,vol.129,#36,p.10961-10965]

Literature
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