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259-79-0,MFCD00001110
Catalog No.:AA00BF7X

259-79-0 | Biphenylene

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100mg
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$67.00   $47.00
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250mg
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1g
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$288.00   $202.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA00BF7X
Chemical Name:
Biphenylene
CAS Number:
259-79-0
Molecular Formula:
C12H8
Molecular Weight:
152.1919
MDL Number:
MFCD00001110
SMILES:
c1ccc2c(c1)c1c2cccc1
NSC Number:
101862
Properties
Computed Properties
 
Complexity:
339  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
12  
XLogP3:
2.3  

Downstream Synthesis Route

[1]Molecules,2003,vol.8,p.593-598

[2]JournaloftheChemicalSociety,1958,p.2658,2662

[3]JournaloftheChemicalSocietyC:Organic,1968,p.1663-1667

[1]Organometallics,2019,vol.38,p.2818-2823

[2]JournaloftheChemicalSociety.PerkintransactionsI,1985,p.115-120

[3]BulletinoftheChemicalSocietyofJapan,1984,vol.57,p.1914-1919

[4]JournalofOrganicChemistry,2020,vol.85,p.5158-5172

[5]JournalofOrganicChemistry,1992,vol.57,p.2740-2741

[6]Chemistry-AEuropeanJournal,2017,vol.23,p.13684-13695

[7]JournaloftheChemicalSociety,1958,p.2658,2662

[8]JournalofPhysicalOrganicChemistry,2004,vol.17,p.798-806

[1]JournalofOrganicChemistry,1990,vol.55,p.929-935

[1]JournalofOrganicChemistry,1990,vol.55,p.929-935

[1]CanadianJournalofChemistry,1990,vol.68,p.1950-1960

[2]CanadianJournalofChemistry,1990,vol.68,p.1950-1960

Literature

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Journal: Journal of the American Chemical Society 20121017

Title: The 'Texas-sized' molecular box: a versatile building block for the construction of anion-directed mechanically interlocked structures.

Journal: Accounts of chemical research 20120821

Title: Photoinduced electron transfer in Os(terpyridine)-biphenylene-(bi)pyridinium assemblies.

Journal: Inorganic chemistry 20120507

Title: Synthesis of aromatic compounds by catalytic C-C bond activation of biphenylene or angular [3]phenylene.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120402

Title: Applying the conjugated circuits method to Clar structures of [n]phenylenes for determining resonance energies.

Journal: Physical chemistry chemical physics : PCCP 20111214

Title: Nickel(II) and iron(II) triple helicates assembled from expanded quaterpyridines incorporating flexible linkages.

Journal: Dalton transactions (Cambridge, England : 2003) 20111207

Title: Creation of coating surfaces possessing superhydrophobic and superoleophobic characteristics with fluoroalkyl end-capped vinyltrimethoxysilane oligomeric nanocomposites having biphenylene segments.

Journal: Journal of colloid and interface science 20111015

Title: Mechanistic implications of an asymmetric intermediate in catalytic C-C coupling by a dinuclear nickel complex.

Journal: Chemical communications (Cambridge, England) 20110828

Title: Unimolecular dissociation of anthracene and acridine cations: the importance of isomerization barriers for the C2H2 loss and HCN loss channels.

Journal: The Journal of chemical physics 20110828

Title: Novel products from C6H5 + C6H6/C6H5 reactions.

Journal: The journal of physical chemistry. A 20110602

Title: Handedness inversion in preparing chiral 4, 4(')-biphenylene-silica nanostructures.

Journal: Nanotechnology 20110401

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Journal: The Journal of chemical physics 20110128

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Journal: Organic letters 20100917

Title: Electronic properties of the biphenylene sheet and its one-dimensional derivatives.

Journal: ACS nano 20100824

Title: Variable products in dielectric-barrier discharge assisted benzene oxidation.

Journal: Journal of hazardous materials 20100615

Title: Correlations between local aromaticity indices of bipartite conjugated hydrocarbons.

Journal: The journal of physical chemistry. A 20100513

Title: Scope and limitations of accurate structure determination of solutes dissolved in liquid crystals.

Journal: The journal of physical chemistry. A 20100513

Title: Solid-state molecular rotors with perdeuterated stators: mechanistic insights from biphenylene rotational dynamics in ordered and disordered crystal forms.

Journal: The Journal of organic chemistry 20100416

Title: Structure and stereodynamics of aryldiimino derivatives.

Journal: The Journal of organic chemistry 20100416

Title: An overview of recent development in composite catalysts from porous materials for various reactions and processes.

Journal: International journal of molecular sciences 20100101

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Journal: PloS one 20100101

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Journal: The journal of physical chemistry. B 20091231

Title: A reliable quantum-chemical protocol for the characterization of organic mixed-valence compounds.

Journal: Journal of the American Chemical Society 20091111

Title: Synthesis and properties of oligophenylene-layered polymers.

Journal: Macromolecular rapid communications 20090701

Title: Flash-vacuum-pyrolytic reorganization of angular [4]phenylene.

Journal: Chemical communications (Cambridge, England) 20090421

Title: Mechanisms of product formation from the pyrolytic thermal degradation of catechol.

Journal: Chemosphere 20080901

Title: On the destabilization (strain) energy of biphenylene.

Journal: The journal of physical chemistry. A 20080821

Title: 4'-Hydroxy-biphenyl-4-carboxylic acid.

Journal: Acta crystallographica. Section E, Structure reports online 20080601

Title: Geometric and chelation influences on the electronic structure and optical properties of tetra(carboxylic acid)phenyleneethynylene dyes.

Journal: The journal of physical chemistry. A 20080508

Title: Strain in biphenylene and some of its derivatives.

Journal: The journal of physical chemistry. A 20080320

Title: Mechanisms of molecular product and persistent radical formation from the pyrolysis of hydroquinone.

Journal: Chemosphere 20080301

Title: Electronic spectroscopy of biphenylene inside helium nanodroplets.

Journal: The journal of physical chemistry. A 20070809

Title: Ligand-field dependence of the excited state dynamics of Hangman bisporphyrin dyad complexes.

Journal: The journal of physical chemistry. B 20070719

Title: Self-assembly and host-guest chemistry of a 3.5-nm coordination nanotube.

Journal: Chemistry, an Asian journal 20070402

Title: Fast, through-bond mediated energy transfer from Ir(III) to Ru(II) in di- and tetranuclear heterometallic assemblies: elucidation of a two-step Ir --> Ir --> Ru energy transfer process.

Journal: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20070401

Title: Regioselective [5,5]-sigmatropic rearrangement reactions of aryl hydrazides.

Journal: Organic letters 20060511

Title: Cobalt(IV) corroles as catalysts for the electroreduction of O2: reactions of heterobimetallic dyads containing a face-to-face linked Fe(III) or Mn(III) porphyrin.

Journal: Journal of inorganic biochemistry 20060401

Title: Intercepting palladacycles derived by C-H insertion. A mechanism-driven entry to heterocyclic tetraphenylenes.

Journal: Journal of the American Chemical Society 20060125

Title: Electrochemistry and spectroelectrochemistry of heterobimetallic porphyrin-corrole dyads. Influence of the spacer, metal ion, and oxidation state on the pyridine binding ability.

Journal: Inorganic chemistry 20051128

Title: Iron-dependent lysosomal destabilization initiates silica-induced apoptosis in murine macrophages.

Journal: Toxicology letters 20051115

Title: Electrochemistry, spectroelectrochemistry, chloride binding, and O2 catalytic reactions of free-base porphyrin-cobalt corrole dyads.

Journal: Inorganic chemistry 20050919

Title: Efficient C-F and C-C activation by a novel N-heterocyclic carbene-nickel(0) complex.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050819

Title: PECT model analysis and predictions of experimental collisional energy transfer probabilities P(E',E) and moments <DeltaE> for azulene and biphenylene.

Journal: The journal of physical chemistry. B 20050505

Title: The phane properties of anti-[2.2](1,4)biphenylenophane.

Journal: The Journal of organic chemistry 20050429

Title: Cobalt(III) corroles as electrocatalysts for the reduction of dioxygen: reactivity of a monocorrole, biscorroles, and porphyrin-corrole dyads.

Journal: Journal of the American Chemical Society 20050420

Title: Dynamic evolution of Kohn-Sham electron density in the real-time domain with finite basis expansion.

Journal: Chemphyschem : a European journal of chemical physics and physical chemistry 20050401

Title: Alkyl- and aryl-substituted corroles. 5. Synthesis, physicochemical properties, and X-ray structural characterization of copper biscorroles and porphyrin-corrole dyads.

Journal: Inorganic chemistry 20041115

Title: Orientational control of electronic coupling in mixed-valence, binuclear ruthenium(II)-bis(2,2':6',2' '-terpyridine) complexes.

Journal: Journal of the American Chemical Society 20041027

Title: Tris(benzocyclobutadieno)triphenylene and its lower biphenylene homologues by palladium-catalyzed cyclizations of 2,3-didehydrobiphenylene.

Journal: Organic letters 20040930

Title: Electrophilic aromatic substitution by the fluorofullerene C60F18.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20040920

Title: Highly efficient recognition of native TpT by artificial ditopic hydrogen-bonding receptors possessing a conformationally well-defined linkage.

Journal: The Journal of organic chemistry 20030207

Title: Alkyl and aryl substituted corroles. 3. Reactions of cofacial cobalt biscorroles and porphyrin-corroles with pyridine and carbon monoxide.

Journal: Inorganic chemistry 20020729

Title: Electron-capture detector and multiple negative ions of aromatic hydrocarbons.

Journal: Journal of chromatography. A 20020405

Title: A hot molecule as an intermediate in multiphoton reactions: first photoinduced reactions of biphenylene.

Journal: Journal of the American Chemical Society 20011017

Title: Alkyl and aryl substituted corroles. 2. Synthesis and characterization of linked 'face-to-face' biscorroles. X-ray structure of (BCA)Co(2)(py)(3), where BCA represents a biscorrole with an anthracenyl bridge.

Journal: Inorganic chemistry 20010910

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