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99646-28-3,MFCD01311709
Catalog No.:AA00ILHP

99646-28-3 | Phosphine, (1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)-

Pack Size
Purity
Availability
Price(USD)
Quantity
  
250mg
98%
in stock  
$13.00   $9.00
- +
1g
98%
in stock  
$29.00   $21.00
- +
5g
98%
in stock  
$117.00   $82.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA00ILHP
Chemical Name:
Phosphine, (1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)-
CAS Number:
99646-28-3
Molecular Formula:
C48H40P2
Molecular Weight:
678.7787
MDL Number:
MFCD01311709
SMILES:
Cc1ccc(cc1)P(c1ccc2c(c1c1c(ccc3c1cccc3)P(c1ccc(cc1)C)c1ccc(cc1)C)cccc2)c1ccc(cc1)C
Properties
Computed Properties
 
Complexity:
897  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
50  
Rotatable Bond Count:
7  
XLogP3:
12.9  

Downstream Synthesis Route

[1]JournalofOrganicChemistry,1986,vol.51,p.629-635

[2]OrganicLetters,2004,vol.6,p.4675-4678

99646-28-3   
(R)-2'-(di-p-tolyl-phosphinothioyl)-1,1'binaphthalen-2-yl-di-p-tolyl-phosphane 
 
(R)-2,2'-bis-(di-p-tolyl-phosphinothioyl)-1,1'binaphthalenyl 

[1]TetrahedronAsymmetry,2003,vol.14,p.705-710

[1]AngewandteChemie-InternationalEdition,2004,vol.43,p.6491-6493

[1]JournalofOrganicChemistry,1986,vol.51,p.629-635

[1]JournalofOrganicChemistry,1986,vol.51,p.629-635

Literature

Title: Solution structures and behavior of trans-RuH(eta(1)-BH(4)) (binap)(1,2-diamine) complexes.

Journal: Magnetic resonance in chemistry : MRC 20060101

Title: Asymmetric hydrogenation of tert-alkyl ketones.

Journal: Journal of the American Chemical Society 20050615

Title: Mechanism of asymmetric hydrogenation of ketones catalyzed by BINAP/1,2-diamine-rutheniumII complexes.

Journal: Journal of the American Chemical Society 20031105

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SDS
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Tags:99646-28-3 Molecular Formula|99646-28-3 MDL|99646-28-3 SMILES|99646-28-3 Phosphine, (1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)-