107-37-9,MFCD00000486
Catalog No.:AA003NNV

107-37-9 | ALLYLTRICHLOROSILANE

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Purity
Availability
Price(USD)
Quantity
  
5g
95%
1 week  
$231.00   $162.00
- +
25g
95%
1 week  
$360.00   $252.00
- +
  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
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Technical Information
Catalog Number:
AA003NNV
Chemical Name:
ALLYLTRICHLOROSILANE
CAS Number:
107-37-9
Molecular Formula:
C3H5Cl3Si
Molecular Weight:
175.5163
MDL Number:
MFCD00000486
SMILES:
C=CC[Si](Cl)(Cl)Cl
NSC Number:
20940
UN Number:
1724
Properties
Properties
 
BP:
117.5°C  

Computed Properties
 
Complexity:
65.1  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0  
Defined Bond Stereocenter Count:
0  
Formal Charge:
0  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
0  
Hydrogen Bond Donor Count:
0  
Isotope Atom Count:
0  
Rotatable Bond Count:
1  
Undefined Atom Stereocenter Count:
0  
Undefined Bond Stereocenter Count:
0  

Literature

Title: Enantioselective allylation of α,β-unsaturated aldehydes with allyltrichlorosilane catalyzed by METHOX.

Journal: The Journal of organic chemistry 20110603

Title: A multiwell platform for studying stiffness-dependent cell biology.

Journal: PloS one 20110101

Title: Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes.

Journal: Organic & biomolecular chemistry 20090921

Title: Vibrational spectra of metals treated with allyltrimethoxysilane sol-gel and self-assembled monolayer of allytrichlorosilane.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20070701

Title: C2-symmetric bissulfoxides as organocatalysts in the allylation of benzoyl hydrazones: spacer and concentration effects.

Journal: Organic letters 20070524

Title: First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane.

Journal: Chemical communications (Cambridge, England) 20061207

Title: Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis.

Journal: Physical chemistry chemical physics : PCCP 20060521

Title: Structurally simple pyridine N-oxides as efficient organocatalysts for the enantioselective allylation of aromatic aldehydes.

Journal: The Journal of organic chemistry 20060217

Title: Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides.

Journal: The Journal of organic chemistry 20060217

Title: Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides.

Journal: The Journal of organic chemistry 20060217

Title: Readily available pyridine- and quinoline-N-oxides as new organocatalysts for the enantioselective allylation of aromatic aldehydes with allyl(trichloro)silane.

Journal: Chirality 20050801

Title: Proline-based N-oxides as readily available and modular chiral catalysts. Enantioselective reactions of allyltrichlorosilane with aldehydes.

Journal: Organic letters 20050721

Title: METHOX: a new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes.

Journal: Organic letters 20050721

Title: Polystyrenes with chiral phosphoramide substituents as Lewis base catalysts for asymmetric addition of allyltrichlorosilane: enhancement of catalytic performance by polymer effect.

Journal: Chemical communications (Cambridge, England) 20050414

Title: The first series of chiral 2,2':6',2''-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes.

Journal: Organic & biomolecular chemistry 20040721

Title: The first catalytic asymmetric allylation of imines with the tetraallylsilane-TBAF-MeOH system, using the chiral bis-pi-allylpalladium complex.

Journal: The Journal of organic chemistry 20040206

Title: New Lewis-basic N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes.

Journal: The Journal of organic chemistry 20031212

Title: Chiral sulfoxides in the enantioselective allylation of aldehydes with allyltrichlorosilane.

Journal: Chemical communications (Cambridge, England) 20031107

Title: A new synthetic route to enantiomerically pure axially chiral 2,2'-bipyridine N,N'-dioxides. Highly efficient catalysts for asymmetric allylation of aldehydes with allyl(trichloro)silanes.

Journal: The Journal of organic chemistry 20030808

Title: Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane.

Journal: Chemical communications (Cambridge, England) 20030121

Title: A novel axially chiral 2,2'-bipyridine N,N'-dioxide. Its preparation and use for asymmetric allylation of aldehydes with allyl(trichloro)silane as a highly efficient catalyst.

Journal: Organic letters 20020808

Title: Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane.

Journal: Organic letters 20020321

Title: Highly stereoselective synthesis of homoallylic amines based on addition of allyltrichlorosilanes to benzoylhydrazones.

Journal: Journal of the American Chemical Society 20011003

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Tags:107-37-9 Molecular Formula|107-37-9 MDL|107-37-9 SMILES|107-37-9 ALLYLTRICHLOROSILANE
Catalog No.: AA003NNV
107-37-9,MFCD00000486
107-37-9 | ALLYLTRICHLOROSILANE
Pack Size: 5g
Purity: 95%
1 week
$231.00 $162.00
Pack Size: 25g
Purity: 95%
1 week
$360.00 $252.00
Quantity
- +
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Technical Information
Catalog Number: AA003NNV
Chemical Name: ALLYLTRICHLOROSILANE
CAS Number: 107-37-9
Molecular Formula: C3H5Cl3Si
Molecular Weight: 175.5163
MDL Number: MFCD00000486
SMILES: C=CC[Si](Cl)(Cl)Cl
NSC Number: 20940
UN Number: 1724
Properties
BP: 117.5°C  
Complexity: 65.1  
Covalently-Bonded Unit Count: 1  
Defined Atom Stereocenter Count: 0  
Defined Bond Stereocenter Count: 0  
Formal Charge: 0  
Heavy Atom Count: 7  
Hydrogen Bond Acceptor Count: 0  
Hydrogen Bond Donor Count: 0  
Isotope Atom Count: 0  
Rotatable Bond Count: 1  
Undefined Atom Stereocenter Count: 0  
Undefined Bond Stereocenter Count: 0  
Literature fold

Title: Enantioselective allylation of α,β-unsaturated aldehydes with allyltrichlorosilane catalyzed by METHOX.

Journal: The Journal of organic chemistry20110603

Title: A multiwell platform for studying stiffness-dependent cell biology.

Journal: PloS one20110101

Title: Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes.

Journal: Organic & biomolecular chemistry20090921

Title: Vibrational spectra of metals treated with allyltrimethoxysilane sol-gel and self-assembled monolayer of allytrichlorosilane.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy20070701

Title: C2-symmetric bissulfoxides as organocatalysts in the allylation of benzoyl hydrazones: spacer and concentration effects.

Journal: Organic letters20070524

Title: First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane.

Journal: Chemical communications (Cambridge, England)20061207

Title: Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis.

Journal: Physical chemistry chemical physics : PCCP20060521

Title: Structurally simple pyridine N-oxides as efficient organocatalysts for the enantioselective allylation of aromatic aldehydes.

Journal: The Journal of organic chemistry20060217

Title: Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides.

Journal: The Journal of organic chemistry20060217

Title: Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides.

Journal: The Journal of organic chemistry20060217

Title: Readily available pyridine- and quinoline-N-oxides as new organocatalysts for the enantioselective allylation of aromatic aldehydes with allyl(trichloro)silane.

Journal: Chirality20050801

Title: Proline-based N-oxides as readily available and modular chiral catalysts. Enantioselective reactions of allyltrichlorosilane with aldehydes.

Journal: Organic letters20050721

Title: METHOX: a new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes.

Journal: Organic letters20050721

Title: Polystyrenes with chiral phosphoramide substituents as Lewis base catalysts for asymmetric addition of allyltrichlorosilane: enhancement of catalytic performance by polymer effect.

Journal: Chemical communications (Cambridge, England)20050414

Title: The first series of chiral 2,2':6',2''-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes.

Journal: Organic & biomolecular chemistry20040721

Title: The first catalytic asymmetric allylation of imines with the tetraallylsilane-TBAF-MeOH system, using the chiral bis-pi-allylpalladium complex.

Journal: The Journal of organic chemistry20040206

Title: New Lewis-basic N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes.

Journal: The Journal of organic chemistry20031212

Title: Chiral sulfoxides in the enantioselective allylation of aldehydes with allyltrichlorosilane.

Journal: Chemical communications (Cambridge, England)20031107

Title: A new synthetic route to enantiomerically pure axially chiral 2,2'-bipyridine N,N'-dioxides. Highly efficient catalysts for asymmetric allylation of aldehydes with allyl(trichloro)silanes.

Journal: The Journal of organic chemistry20030808

Title: Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane.

Journal: Chemical communications (Cambridge, England)20030121

Title: A novel axially chiral 2,2'-bipyridine N,N'-dioxide. Its preparation and use for asymmetric allylation of aldehydes with allyl(trichloro)silane as a highly efficient catalyst.

Journal: Organic letters20020808

Title: Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane.

Journal: Organic letters20020321

Title: Highly stereoselective synthesis of homoallylic amines based on addition of allyltrichlorosilanes to benzoylhydrazones.

Journal: Journal of the American Chemical Society20011003

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