Name: Name:6,6'-Dimethyl-2,2'-dipyridyl
Brand: AABLOCKS
SKU: AA0035ZZ
Rating: 90 (10 reviews)

Technical Information

Catalog Number: AA0035ZZ

Chemical Name: 6,6'-Dimethyl-2,2'-dipyridyl

CAS Number: 4411-80-7

Molecular Formula: C12H12N2

Molecular Weight: 184.2371

MDL Number: MFCD00059776

SMILES: Cc1cccc(n1)c1cccc(n1)C

NSC Number: 4705

Properties

BP: 278.6°C at 760 mmHg

Form: Solid

MP: 93-95 °C(lit.);

Storage: Keep in dry area;Room Temperature;

Complexity: 161

Covalently-Bonded Unit Count: 1

Defined Atom Stereocenter Count: 0

Defined Bond Stereocenter Count: 0

Formal Charge: 0

Heavy Atom Count: 14

Hydrogen Bond Acceptor Count: 2

Hydrogen Bond Donor Count: 0

Isotope Atom Count: 0

Rotatable Bond Count: 1

Undefined Atom Stereocenter Count: 0

Undefined Bond Stereocenter Count: 0

XLogP3: 2.3

83:

Literature fold

Title: Modulation in selectivity and allosteric properties of small-molecule ligands for CC-chemokine receptors.

Journal: Journal of medicinal chemistry20120927

Title: Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cadmium.

Journal: Acta crystallographica. Section E, Structure reports online20120901

Title: Definition of an intramolecular Eu-to-Eu energy transfer within a discrete [Eu2L] complex in solution.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20120625

Title: Pentacoordinate Ni(II) complexes: preparation, magnetic measurements, and ab initio calculations of the magnetic anisotropy terms.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20120326

Title: Anti-mycobacterial activities of some cationic and anionic calix[4]arene derivatives.

Journal: Bioorganic & medicinal chemistry20120315

Title: Diaqua-(5-carb-oxy-benzene-1,3-dicarboxyl-ato-κO,O)(6,6'-dimethyl-2,2'-bipyridine-κN,N')nickel(II) hepta-hydrate.

Journal: Acta crystallographica. Section E, Structure reports online20110901

Title: (6,6'-Dimethyl-2,2'-bipyridine-κN,N')diiodidomercury(II).

Journal: Acta crystallographica. Section E, Structure reports online20110301

Title: Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online20101001

Title: Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')cadmium(II).

Journal: Acta crystallographica. Section E, Structure reports online20100801

Title: (2,2'-Bipyridine-κN,N')dibromido(dimethyl sulfoxide-κO)zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online20100601

Title: Ferromagnetic coupling and magnetic anisotropy in oxalato-bridged trinuclear chromium(III)-cobalt(II) complexes with aromatic diimine ligands.

Journal: Dalton transactions (Cambridge, England : 2003)20100307

Title: Photochemical stereospecific hydrogenation of a Ru complex with an NAD(+)/NADH-type ligand.

Journal: Inorganic chemistry20091221

Title: Dibromido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online20091101

Title: Dibenzoato-κO;κO,O'-(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II)-benzoic acid (1/1).

Journal: Acta crystallographica. Section E, Structure reports online20091101

Title: (6,6'-Dimethyl-2,2'-bipyridine-κN,N')diiodidozinc(II).

Journal: Acta crystallographica. Section E, Structure reports online20091101

Title: Studies on bis(halogeno) dioxomolybdenum(VI)-bipyridine complexes: synthesis and catalytic activity.

Journal: Dalton transactions (Cambridge, England : 2003)20091028

Title: Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online20091001

Title: Structural characterization, solution studies, and DFT calculations on a series of binuclear gold(III) oxo complexes: relationships to biological properties.

Journal: Inorganic chemistry20080407

Title: Iron(II) complexes of sterically bulky alpha-ketocarboxylates. structural models for alpha-ketoacid-dependent nonheme iron halogenases.

Journal: Inorganic chemistry20080218

Title: Structural and solution chemistry, antiproliferative effects, and DNA and protein binding properties of a series of dinuclear gold(III) compounds with bipyridyl ligands.

Journal: Journal of medicinal chemistry20060907

Title: Ruthenium-cluster-mediated activation of all bonds of a methyl group of 6,6'-dimethyl-2,2'-bipyridine and 2,9-dimethyl-1,10-phenanthroline: transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenanthroline ligand.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20060201

Title: Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+ and five-coordinate [CuL2(solvent)]2+ complexes (L = 6,6'-dimethyl-2,2'-bipyridine or 2,9-dimethyl-1,10-phenanthroline): completely gated reduction reaction of [Cu(dmp)2]2+ in nitromethane.

Journal: Dalton transactions (Cambridge, England : 2003)20050321

Title: Structure-dependent photophysical properties of singlet and triplet metal-to-ligand charge transfer states in copper(I) bis(diimine) compounds.

Journal: Inorganic chemistry20031006

Title: Luminescent lanthanide complexes of a bis-bipyridine-phosphine-oxide ligand as tools for anion detection.

Journal: Journal of the American Chemical Society20020703

Application fold

6,6'-Dimethyl-2,2'-bipyridyl, also known as 6,6'-Dimethyl-2,2'-dipyridyl, is a compound utilized in organic synthesis for the preparation of novel oligobipyridine ligands. These ligands play essential roles in coordination chemistry, where they coordinate with metal ions to form stable complexes. The introduction of methyl groups at the 6th positions of both pyridine rings enhances the steric and electronic properties of the ligand, thereby influencing its coordination behavior and the properties of the resulting metal complexes. This compound's versatility makes it valuable for designing and synthesizing ligands tailored to specific applications in catalysis, materials science, and coordination chemistry.

4411-80-7 | 6,6'-Dimethyl-2,2'-dipyridyl