563-79-1,MFCD00008897
Catalog No.:AA0035LQ

563-79-1 | Tetramethylethylene

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Purity
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25g
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$185.00   $129.00
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100g
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$483.00   $338.00
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  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
  • Download SDS
Technical Information
Catalog Number:
AA0035LQ
Chemical Name:
Tetramethylethylene
CAS Number:
563-79-1
Molecular Formula:
C6H12
Molecular Weight:
84.1595
MDL Number:
MFCD00008897
SMILES:
CC(=C(C)C)C
NSC Number:
73907
UN Number:
1993
Properties
Properties
 
BP:
73.3°C  
Form:
Liquid  
MP:
-75℃  
Storage:
2-8℃;  

Computed Properties
 
Complexity:
50.1  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0  
Defined Bond Stereocenter Count:
0  
Formal Charge:
0  
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
0  
Hydrogen Bond Donor Count:
0  
Isotope Atom Count:
0  
Rotatable Bond Count:
0  
Undefined Atom Stereocenter Count:
0  
Undefined Bond Stereocenter Count:
0  
XLogP3:
2.9  

Literature

Title: Voltammetric determination of Os(VI)-modified oligosaccharides at nanomolar level.

Journal: Bioelectrochemistry (Amsterdam, Netherlands) 20121201

Title: Surface chemistry of isopropoxy tetramethyl dioxaborolane on Cu(111).

Journal: Langmuir : the ACS journal of surfaces and colloids 20120417

Title: Evolution of structure and reactivity in a series of iconic carbenes.

Journal: The Journal of organic chemistry 20120120

Title: Scalable enantioselective total synthesis of taxanes.

Journal: Nature chemistry 20120101

Title: Ultrafast non-adiabatic dynamics of methyl substituted ethylenes: the π3s Rydberg state.

Journal: The Journal of chemical physics 20111028

Title: A study of the alkene-ozone reactions, 2,3-dimethyl 2-butene + O3 and 2-methyl propene + O3, with photoelectron spectroscopy: measurement of product branching ratios and atmospheric implications.

Journal: Physical chemistry chemical physics : PCCP 20111021

Title: Development of miracle medicines from sialic acids.

Journal: Proceedings of the Japan Academy. Series B, Physical and biological sciences 20110610

Title: Understanding the electronic reorganization along the nonpolar [3 + 2] cycloaddition reactions of carbonyl ylides.

Journal: The Journal of organic chemistry 20110121

Title: 2,3-Dimethyl-2-butene (TME) ozonolysis: pressure dependence of stabilized Criegee intermediates and evidence of stabilized vinyl hydroperoxides.

Journal: The journal of physical chemistry. A 20110120

Title: Investigation of the thermal and photochemical reactions of ozone with 2,3-dimethyl-2-butene.

Journal: The journal of physical chemistry. A 20101209

Title: Activation of molecular oxygen by a dioxygenase pathway by a ruthenium bis-bipyridine compound with a proximal selenium site.

Journal: Journal of the American Chemical Society 20100120

Title: Solvation of dichlorocarbene: complexation with aryl ethers.

Journal: The journal of physical chemistry. A 20100114

Title: Selective and unexpected transformations of 2-methylpropane to 2,3-dimethylbutane and 2-methylpropene to 2,3-dimethylbutene catalyzed by an alumina-supported tungsten hydride.

Journal: Chemical communications (Cambridge, England) 20090514

Title: Acetone reactions over the surfaces of polycrystalline UO2: a kinetic and spectroscopic study.

Journal: Langmuir : the ACS journal of surfaces and colloids 20090421

Title: Multidimensional exploration of valley-ridge inflection points on potential-energy surfaces.

Journal: Journal of the American Chemical Society 20090225

Title: Photoarylation/alkylation of bromonaphthols.

Journal: The Journal of organic chemistry 20090206

Title: The kinetics of tetramethylethene ozonolysis: decomposition of the primary ozonide and subsequent product formation in the condensed phase.

Journal: The journal of physical chemistry. A 20081225

Title: Theoretical prediction of a perepoxide intermediate for the reaction of singlet oxygen with trans-cyclooctene contrasts with the two-step no-intermediate ene reaction for acyclic alkenes.

Journal: The Journal of organic chemistry 20081107

Title: Di-μ(3)-oxido-di-μ(2)-oxido-tetra-oxido-bis-(1,1,2,2-tetra-methyl-ethylenedicyclo-penta-dien-yl)-dimolyb-denum(IV)-dimolybdenum(VI) hexa-hydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20081101

Title: Activation parameters for additions of ambiphilic methoxychlorocarbene to alkenes.

Journal: Organic letters 20080918

Title: Enthalpy versus entropy in chlorocarbene/alkene addition reactions.

Journal: Journal of the American Chemical Society 20080430

Title: Facile and selective aliphatic C-H bond activation at ambient temperatures initiated by Cp*W(NO)(CH2CMe3)(eta(3)-CH2CHCHMe).

Journal: Journal of the American Chemical Society 20080319

Title: A new solvent-dependent mechanism for a triazolinedione ene reaction.

Journal: The Journal of organic chemistry 20080201

Title: Analysis of triacetone triperoxide (TATP) and TATP synthetic intermediates by electrospray ionization mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20080101

Title: Atmospheric reaction of OH radicals with 1,3-butadiene and 4-hydroxy-2-butenal.

Journal: The journal of physical chemistry. A 20071206

Title: Tracking 'invisible' alkylchlorocarbenes by their sigma --> p absorptions: dynamics and solvent interactions.

Journal: Journal of the American Chemical Society 20070815

Title: Kinetics of the oxygenation of unsaturated organics with singlet oxygen generated from H2O2 by a heterogeneous molybdenum catalyst.

Journal: Journal of the American Chemical Society 20070530

Title: Controlled OH radical production via ozone-alkene reactions for use in aerosol aging studies.

Journal: Environmental science & technology 20070401

Title: CuCl-induced formation and migration of isoindazolyl carbenoids.

Journal: The Journal of organic chemistry 20070330

Title: Homogeneous decatungstate-catalyzed photooxygenation of tetrasubstituted alkenes: a deuterium kinetic isotope effect study.

Journal: The Journal of organic chemistry 20061110

Title: Reaction of thianthrene and phenoxathiin cation radicals with 2,3-dimethyl-2-butene. Chemical and electrochemical studies.

Journal: The Journal of organic chemistry 20060512

Title: Formation of phenol and carbonyls from the atmospheric reaction of OH radicals with benzene.

Journal: Physical chemistry chemical physics : PCCP 20060314

Title: Confined space-controlled olefin-oxygen charge transfer in zeolites.

Journal: The journal of physical chemistry. B 20060223

Title: Light-induced coumarin cyclopentannelation.

Journal: Organic letters 20051110

Title: Photochemical sources of organic acids. 1. Reaction of ozone with isoprene, propene, and 2-butenes under dry and humid conditions using SPME.

Journal: The journal of physical chemistry. A 20050623

Title: A practical, fast, and high-yielding aziridination procedure using simple Cu(II) complexes containing N-donor pyridine-based ligands.

Journal: The Journal of organic chemistry 20050610

Title: Photocatalytic oxygenation of anthracenes and olefins with dioxygen via selective radical coupling using 9-mesityl-10-methylacridinium ion as an effective electron-transfer photocatalyst.

Journal: Journal of the American Chemical Society 20041215

Title: Direct aziridination of alkenes by a cationic (salen)ruthenium(VI) nitrido complex.

Journal: Journal of the American Chemical Society 20041201

Title: Ozonolysis of tetramethylethylene: characterization of cyclic and open-chain oligoperoxidic products.

Journal: The Journal of organic chemistry 20041015

Title: Aryl cations from aromatic halides. Photogeneration and reactivity of 4-hydroxy(methoxy)phenyl cation.

Journal: The Journal of organic chemistry 20040514

Title: Evidence for specific solvation of two halocarbene amides.

Journal: Journal of the American Chemical Society 20040512

Title: Self-assembly of interlocked supramolecular dendrimers.

Journal: The Journal of organic chemistry 20040402

Title: Thermal activation of hydrocarbon C-H bonds initiated by a tungsten allyl complex.

Journal: Journal of the American Chemical Society 20031210

Title: Synthesis and photochemistry of isothiocoumarins fused to an additional pyranone or thiopyranone ring.

Journal: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20031101

Title: Polyoxometalate sensitization in mechanistic studies of photochemical reactions: the decatungstate anion as a reference sensitizer for photoinduced free radical oxygenations of organic compounds.

Journal: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20030301

Title: A new form of kinetic isotope effect. Dynamic effects on isotopic selectivity and regioselectivity.

Journal: Journal of the American Chemical Society 20030205

Title: Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism.

Journal: Journal of the American Chemical Society 20030205

Title: Planar transition structures in the epoxidation of alkenes. A DFT study on the reaction of peroxyformic acid with norbornene derivatives.

Journal: The Journal of organic chemistry 20021129

Title: Deciphering the mechanistic dichotomy in the cyclization of 1-(2-ethynylphenyl)-3,3-dialkyltriazenes: competition between pericyclic and pseudocoarctate pathways.

Journal: Journal of the American Chemical Society 20021113

Title: Theoretical investigation of electron transfer transition in tetracyanoethylene-contained organic complexes.

Journal: Journal of computational chemistry 20020715

Title: Completely spirocyclopropanated macrocyclic oligodiacetylenes and their permethylated analogues: preparation and properties.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20020715

Title: Photochemistry of cyclic vicinal tricarbonyl compounds. Laser flash photolysis study of the reaction of indane-1,2,3-trione and its 5-methoxy derivative with olefins.

Journal: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20020401

Title: Direct measurement of OH radicals from ozonolysis of selected alkenes: a EUPHORE simulation chamber study.

Journal: Environmental science & technology 20011201

Title: The reaction of permanganyl chloride with olefins: intermediates and mechanism as derived from matrix-isolation studies and density functional theory calculations.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20011105

Title: Photoinduced, ionic Meerwein arylation of olefins.

Journal: The Journal of organic chemistry 20010921

Title: Reactions of aliphatic ketones R2CO (R=Me, Et, iPr and tBu) with the MCI4/Li(Hg) system (M=U or Ti): mechanistic analogies between the McMurry, Wittig, and Clemmensen reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20010716

Title: Molecular addition compounds. 18. Borane adducts with hydroxydialkyl sulfide borates for hydroboration. New, essentially odorless, water-soluble sulfide borane acceptors for hydroboration.

Journal: The Journal of organic chemistry 20010713

Title: Carbomethoxychlorocarbene: spectroscopy, theory, chemistry and kinetics.

Journal: Journal of the American Chemical Society 20010627

Title: Chemistry of the diazeniumdiolates. 3. Photoreactivity.

Journal: Journal of the American Chemical Society 20010613

Title: Reductive activation of 1,1-dichloro-1-fluoroethane (HCFC-141b) by phenobarbital- and pyridine-induced rat liver microsomal cytochrome P450.

Journal: Xenobiotica; the fate of foreign compounds in biological systems 19960401

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Tags:563-79-1 Molecular Formula|563-79-1 MDL|563-79-1 SMILES|563-79-1 Tetramethylethylene
Catalog No.: AA0035LQ
563-79-1,MFCD00008897
563-79-1 | Tetramethylethylene
Pack Size: 25g
Purity:
in stock
$185.00 $129.00
Pack Size: 100g
Purity:
in stock
$483.00 $338.00
Quantity
- +
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Technical Information
Catalog Number: AA0035LQ
Chemical Name: Tetramethylethylene
CAS Number: 563-79-1
Molecular Formula: C6H12
Molecular Weight: 84.1595
MDL Number: MFCD00008897
SMILES: CC(=C(C)C)C
NSC Number: 73907
UN Number: 1993
Properties
BP: 73.3°C  
Form: Liquid  
MP: -75℃  
Storage: 2-8℃;  
Complexity: 50.1  
Covalently-Bonded Unit Count: 1  
Defined Atom Stereocenter Count: 0  
Defined Bond Stereocenter Count: 0  
Formal Charge: 0  
Heavy Atom Count: 6  
Hydrogen Bond Acceptor Count: 0  
Hydrogen Bond Donor Count: 0  
Isotope Atom Count: 0  
Rotatable Bond Count: 0  
Undefined Atom Stereocenter Count: 0  
Undefined Bond Stereocenter Count: 0  
XLogP3: 2.9  
Literature fold

Title: Voltammetric determination of Os(VI)-modified oligosaccharides at nanomolar level.

Journal: Bioelectrochemistry (Amsterdam, Netherlands)20121201

Title: Surface chemistry of isopropoxy tetramethyl dioxaborolane on Cu(111).

Journal: Langmuir : the ACS journal of surfaces and colloids20120417

Title: Evolution of structure and reactivity in a series of iconic carbenes.

Journal: The Journal of organic chemistry20120120

Title: Scalable enantioselective total synthesis of taxanes.

Journal: Nature chemistry20120101

Title: Ultrafast non-adiabatic dynamics of methyl substituted ethylenes: the π3s Rydberg state.

Journal: The Journal of chemical physics20111028

Title: A study of the alkene-ozone reactions, 2,3-dimethyl 2-butene + O3 and 2-methyl propene + O3, with photoelectron spectroscopy: measurement of product branching ratios and atmospheric implications.

Journal: Physical chemistry chemical physics : PCCP20111021

Title: Development of miracle medicines from sialic acids.

Journal: Proceedings of the Japan Academy. Series B, Physical and biological sciences20110610

Title: Understanding the electronic reorganization along the nonpolar [3 + 2] cycloaddition reactions of carbonyl ylides.

Journal: The Journal of organic chemistry20110121

Title: 2,3-Dimethyl-2-butene (TME) ozonolysis: pressure dependence of stabilized Criegee intermediates and evidence of stabilized vinyl hydroperoxides.

Journal: The journal of physical chemistry. A20110120

Title: Investigation of the thermal and photochemical reactions of ozone with 2,3-dimethyl-2-butene.

Journal: The journal of physical chemistry. A20101209

Title: Activation of molecular oxygen by a dioxygenase pathway by a ruthenium bis-bipyridine compound with a proximal selenium site.

Journal: Journal of the American Chemical Society20100120

Title: Solvation of dichlorocarbene: complexation with aryl ethers.

Journal: The journal of physical chemistry. A20100114

Title: Selective and unexpected transformations of 2-methylpropane to 2,3-dimethylbutane and 2-methylpropene to 2,3-dimethylbutene catalyzed by an alumina-supported tungsten hydride.

Journal: Chemical communications (Cambridge, England)20090514

Title: Acetone reactions over the surfaces of polycrystalline UO2: a kinetic and spectroscopic study.

Journal: Langmuir : the ACS journal of surfaces and colloids20090421

Title: Multidimensional exploration of valley-ridge inflection points on potential-energy surfaces.

Journal: Journal of the American Chemical Society20090225

Title: Photoarylation/alkylation of bromonaphthols.

Journal: The Journal of organic chemistry20090206

Title: The kinetics of tetramethylethene ozonolysis: decomposition of the primary ozonide and subsequent product formation in the condensed phase.

Journal: The journal of physical chemistry. A20081225

Title: Theoretical prediction of a perepoxide intermediate for the reaction of singlet oxygen with trans-cyclooctene contrasts with the two-step no-intermediate ene reaction for acyclic alkenes.

Journal: The Journal of organic chemistry20081107

Title: Di-μ(3)-oxido-di-μ(2)-oxido-tetra-oxido-bis-(1,1,2,2-tetra-methyl-ethylenedicyclo-penta-dien-yl)-dimolyb-denum(IV)-dimolybdenum(VI) hexa-hydrate.

Journal: Acta crystallographica. Section E, Structure reports online20081101

Title: Activation parameters for additions of ambiphilic methoxychlorocarbene to alkenes.

Journal: Organic letters20080918

Title: Enthalpy versus entropy in chlorocarbene/alkene addition reactions.

Journal: Journal of the American Chemical Society20080430

Title: Facile and selective aliphatic C-H bond activation at ambient temperatures initiated by Cp*W(NO)(CH2CMe3)(eta(3)-CH2CHCHMe).

Journal: Journal of the American Chemical Society20080319

Title: A new solvent-dependent mechanism for a triazolinedione ene reaction.

Journal: The Journal of organic chemistry20080201

Title: Analysis of triacetone triperoxide (TATP) and TATP synthetic intermediates by electrospray ionization mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM20080101

Title: Atmospheric reaction of OH radicals with 1,3-butadiene and 4-hydroxy-2-butenal.

Journal: The journal of physical chemistry. A20071206

Title: Tracking 'invisible' alkylchlorocarbenes by their sigma --> p absorptions: dynamics and solvent interactions.

Journal: Journal of the American Chemical Society20070815

Title: Kinetics of the oxygenation of unsaturated organics with singlet oxygen generated from H2O2 by a heterogeneous molybdenum catalyst.

Journal: Journal of the American Chemical Society20070530

Title: Controlled OH radical production via ozone-alkene reactions for use in aerosol aging studies.

Journal: Environmental science & technology20070401

Title: CuCl-induced formation and migration of isoindazolyl carbenoids.

Journal: The Journal of organic chemistry20070330

Title: Homogeneous decatungstate-catalyzed photooxygenation of tetrasubstituted alkenes: a deuterium kinetic isotope effect study.

Journal: The Journal of organic chemistry20061110

Title: Reaction of thianthrene and phenoxathiin cation radicals with 2,3-dimethyl-2-butene. Chemical and electrochemical studies.

Journal: The Journal of organic chemistry20060512

Title: Formation of phenol and carbonyls from the atmospheric reaction of OH radicals with benzene.

Journal: Physical chemistry chemical physics : PCCP20060314

Title: Confined space-controlled olefin-oxygen charge transfer in zeolites.

Journal: The journal of physical chemistry. B20060223

Title: Light-induced coumarin cyclopentannelation.

Journal: Organic letters20051110

Title: Photochemical sources of organic acids. 1. Reaction of ozone with isoprene, propene, and 2-butenes under dry and humid conditions using SPME.

Journal: The journal of physical chemistry. A20050623

Title: A practical, fast, and high-yielding aziridination procedure using simple Cu(II) complexes containing N-donor pyridine-based ligands.

Journal: The Journal of organic chemistry20050610

Title: Photocatalytic oxygenation of anthracenes and olefins with dioxygen via selective radical coupling using 9-mesityl-10-methylacridinium ion as an effective electron-transfer photocatalyst.

Journal: Journal of the American Chemical Society20041215

Title: Direct aziridination of alkenes by a cationic (salen)ruthenium(VI) nitrido complex.

Journal: Journal of the American Chemical Society20041201

Title: Ozonolysis of tetramethylethylene: characterization of cyclic and open-chain oligoperoxidic products.

Journal: The Journal of organic chemistry20041015

Title: Aryl cations from aromatic halides. Photogeneration and reactivity of 4-hydroxy(methoxy)phenyl cation.

Journal: The Journal of organic chemistry20040514

Title: Evidence for specific solvation of two halocarbene amides.

Journal: Journal of the American Chemical Society20040512

Title: Self-assembly of interlocked supramolecular dendrimers.

Journal: The Journal of organic chemistry20040402

Title: Thermal activation of hydrocarbon C-H bonds initiated by a tungsten allyl complex.

Journal: Journal of the American Chemical Society20031210

Title: Synthesis and photochemistry of isothiocoumarins fused to an additional pyranone or thiopyranone ring.

Journal: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology20031101

Title: Polyoxometalate sensitization in mechanistic studies of photochemical reactions: the decatungstate anion as a reference sensitizer for photoinduced free radical oxygenations of organic compounds.

Journal: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology20030301

Title: A new form of kinetic isotope effect. Dynamic effects on isotopic selectivity and regioselectivity.

Journal: Journal of the American Chemical Society20030205

Title: Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism.

Journal: Journal of the American Chemical Society20030205

Title: Planar transition structures in the epoxidation of alkenes. A DFT study on the reaction of peroxyformic acid with norbornene derivatives.

Journal: The Journal of organic chemistry20021129

Title: Deciphering the mechanistic dichotomy in the cyclization of 1-(2-ethynylphenyl)-3,3-dialkyltriazenes: competition between pericyclic and pseudocoarctate pathways.

Journal: Journal of the American Chemical Society20021113

Title: Theoretical investigation of electron transfer transition in tetracyanoethylene-contained organic complexes.

Journal: Journal of computational chemistry20020715

Title: Completely spirocyclopropanated macrocyclic oligodiacetylenes and their permethylated analogues: preparation and properties.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20020715

Title: Photochemistry of cyclic vicinal tricarbonyl compounds. Laser flash photolysis study of the reaction of indane-1,2,3-trione and its 5-methoxy derivative with olefins.

Journal: Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology20020401

Title: Direct measurement of OH radicals from ozonolysis of selected alkenes: a EUPHORE simulation chamber study.

Journal: Environmental science & technology20011201

Title: The reaction of permanganyl chloride with olefins: intermediates and mechanism as derived from matrix-isolation studies and density functional theory calculations.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20011105

Title: Photoinduced, ionic Meerwein arylation of olefins.

Journal: The Journal of organic chemistry20010921

Title: Reactions of aliphatic ketones R2CO (R=Me, Et, iPr and tBu) with the MCI4/Li(Hg) system (M=U or Ti): mechanistic analogies between the McMurry, Wittig, and Clemmensen reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20010716

Title: Molecular addition compounds. 18. Borane adducts with hydroxydialkyl sulfide borates for hydroboration. New, essentially odorless, water-soluble sulfide borane acceptors for hydroboration.

Journal: The Journal of organic chemistry20010713

Title: Carbomethoxychlorocarbene: spectroscopy, theory, chemistry and kinetics.

Journal: Journal of the American Chemical Society20010627

Title: Chemistry of the diazeniumdiolates. 3. Photoreactivity.

Journal: Journal of the American Chemical Society20010613

Title: Reductive activation of 1,1-dichloro-1-fluoroethane (HCFC-141b) by phenobarbital- and pyridine-induced rat liver microsomal cytochrome P450.

Journal: Xenobiotica; the fate of foreign compounds in biological systems19960401

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