7703-74-4 | 2,6-Bis(bromomethyl)pyridine

Title: Synthesis and fluorescence emission of neutral and anionic di- and tetra-carboranyl compounds.

Journal: Dalton transactions (Cambridge, England : 2003) 20110807

Title: 5,8-Dibromo-2,11-dithia-[3,3](2,6)pyridino-paracyclo-phane.

Journal: Acta crystallographica. Section E, Structure reports online 20100801

Title: Selenoether macrocyclic chemistry-syntheses and ligand properties of new small-ring Se(3)- and Se(2)N-donor macrocycles.

Journal: Dalton transactions (Cambridge, England : 2003) 20090621

Title: Enantioselective recognitions of chiral molecular tweezers containing imidazoliums for amino acids.

Journal: Chirality 20090501

Title: Hydrogen and copper ion-induced molecular reorganizations in scorpionand-like ligands. A potentiometric, mechanistic, and solid-state study.

Journal: Inorganic chemistry 20070709

Title: Oxo- and imidovanadium complexes incorporating methylene- and dimethyleneoxa-bridged calix[3]- and -[4]arenes: synthesis, structures and ethylene polymerisation catalysis.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20070101

Title: Secondary interactions in the isomorphous compounds 2,6-bis(chloromethyl)pyridinium chloride and 2,6-bis(bromomethyl)pyridinium bromide.

Journal: Acta crystallographica. Section C, Crystal structure communications 20040901

Title: The synthesis of carboacycles derived from B,B'-bis(aryl) derivatives of icosahedral ortho-carborane.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20030616

Title: Alkylation reactions of [WS(4)](2)(-) and [(eta(5)-C(5)Me(5))WS(3)](-) with 2,6-bis(bromomethyl)pyridine: the first isolation of bisalkylated tetrathiometalate WS(2)[2,6-(SCH(2))(2)(C(5)H(3)N)].

Journal: Inorganic chemistry 20020812

2,6-Bis(bromomethyl)pyridine is a versatile compound widely used in organic synthesis for the preparation of various functional derivatives and complex molecules. It serves as a key building block in the synthesis of several important compounds, including:

1. **New Pyridine-Pyrazole Derivatives:** 2,6-Bis(bromomethyl)pyridine is employed in the synthesis of novel pyridine-pyrazole derivatives, such as 2,6-bis(3,5-diphenylpyrazol-1-ylmethyl)pyridine. These derivatives may exhibit unique chemical and biological properties with potential applications in medicinal chemistry and materials science.

2. **Large Macrocyclic Ligands:** It is utilized in the preparation of large macrocyclic ligands, exemplified by N(1),N(7)-pyridine-2,6-dimethyl-N(2),N(6)-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamido)pyridin-2-yl)pyridine-2,6-dicarboxamide dibromide. These ligands often possess complex structures and can exhibit diverse coordination properties, making them valuable in coordination chemistry and catalysis.

3. **Small-Ring Tridentate Ligands:** 2,6-Bis(bromomethyl)pyridine participates in the synthesis of small-ring, potentially tridentate Se(2)N(pyridyl)-donor macrocycles. These macrocycles feature a unique molecular architecture with the potential to coordinate metal ions, making them useful in the design of novel metal-organic frameworks and coordination polymers.

Overall, 2,6-Bis(bromomethyl)pyridine serves as a versatile and valuable intermediate in organic synthesis, enabling the construction of complex molecules with diverse structures and functionalities. Its reactivity and ability to undergo selective chemical transformations make it a valuable tool for the preparation of advanced organic compounds in various fields of chemistry.