Home Fluorides 88189-03-1
88189-03-1,MFCD08272314
Catalog No.:AA0034GL

88189-03-1 | Bismuth(iii) trifluoromethanesulfonate

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250mg
98%
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$8.00   $6.00
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1g
98%
in stock  
$11.00   $8.00
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5g
98%
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$13.00   $9.00
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10g
98%
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$19.00   $14.00
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25g
98%
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$24.00   $17.00
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100g
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$87.00   $61.00
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500g
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$428.00   $300.00
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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0034GL
Chemical Name:
Bismuth(iii) trifluoromethanesulfonate
CAS Number:
88189-03-1
Molecular Formula:
C3BiF9O9S3
Molecular Weight:
656.1877
MDL Number:
MFCD08272314
SMILES:
FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.[Bi+3]
Properties
Properties
 
Form:
Liquid  
MP:
300 °C  
Solubility:
Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.  
Stability:
Hygroscopic  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
145  
Covalently-Bonded Unit Count:
4  
Heavy Atom Count:
25  
Hydrogen Bond Acceptor Count:
18  

Literature

Title: Bi(OTf)3-, TfOH-, and TMSOTf-mediated, one-pot epoxide rearrangement, addition, and intramolecular silyl-modified Sakurai (ISMS) cascade toward dihydropyrans: comparison of catalysts and role of Bi(OTf)3.

Journal: The Journal of organic chemistry 20111118

Title: Bi(OTf)3-catalysed prenylation of electron-rich aryl ethers and phenols with isoprene: a direct route to prenylated derivatives.

Journal: Organic & biomolecular chemistry 20110721

Title: Biomimetic cationic polyannulation reaction catalyzed by Bi(OTf)3: cyclization of 1,6-dienes, 1,6,10-trienes, and aryl polyenes.

Journal: Organic letters 20110701

Title: Synthesis of chiral 1-substituted tetrahydroisoquinolines by the intramolecular 1,3-chirality transfer reaction catalyzed by Bi(OTf)3.

Journal: The Journal of organic chemistry 20110401

Title: Efficient conversion of triacylglycerols and fatty acids to biodiesel in a microwave reactor using metal triflate catalysts.

Journal: Organic & biomolecular chemistry 20101021

Title: Bismuth(III) triflate-catalyzed direct conversion of corticosteroids into highly functionalized 17-ketosteroids by cleavage of the C17-dihydroxyacetone side chain.

Journal: The Journal of organic chemistry 20091106

Title: Multicatalytic synthesis of complex tetrahydrofurans involving bismuth(III) triflate catalyzed intramolecular hydroalkoxylation of unactivated olefins.

Journal: Organic letters 20090319

Title: Bismuth triflate-catalyzed Wagner-Meerwein rearrangement in terpenes. Application to the synthesis of the 18alpha-oleanane core and A-neo-18alpha-oleanene compounds from lupanes.

Journal: Organic & biomolecular chemistry 20090207

Title: An efficient and mild bismuth triflate-catalysed three-component Mannich-type reaction.

Journal: Organic & biomolecular chemistry 20071007

Title: New entries to water-compatible Lewis acids.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060807

Title: Bismuth triflate-chiral bipyridine complexes as water-compatible chiral Lewis acids.

Journal: Organic letters 20051013

Title: Bismuth compounds in organic synthesis. A one-pot synthesis of homoallyl ethers and homoallyl acetates from aldehydes catalyzed by bismuth triflate.

Journal: The Journal of organic chemistry 20050318

Title: Glycosylation of sialyl acetates with a novel catalyst combination: bismuth triflate and BF3.OEt2 system.

Journal: Bioorganic & medicinal chemistry 20030717

Title: Highly powerful and practical acylation of alcohols with acid anhydride catalyzed by Bi(OTf)(3).

Journal: The Journal of organic chemistry 20011228

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Tags:88189-03-1 Molecular Formula|88189-03-1 MDL|88189-03-1 SMILES|88189-03-1 Bismuth(iii) trifluoromethanesulfonate