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78-85-3,MFCD00006974
Catalog No.:AA00351Z

78-85-3 | Methacrolein (stabilized with HQ)

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1g
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$29.00   $20.00
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5g
95%
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$45.00   $32.00
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25g
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$95.00   $67.00
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100g
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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA00351Z
Chemical Name:
Methacrolein (stabilized with HQ)
CAS Number:
78-85-3
Molecular Formula:
C4H6O
Molecular Weight:
70.0898
MDL Number:
MFCD00006974
SMILES:
CC(=C)C=O
NSC Number:
8260
UN Number:
2396
Properties
Properties
 
BP:
68.4°C  
Form:
Liquid  
MP:
-81 °C  
Refractive Index:
n20/D 1.416(lit.)  
Stability:
Light Sensitive  
Storage:
2-8℃;  

Computed Properties
 
Complexity:
54.7  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
5  
Hydrogen Bond Acceptor Count:
1  
Rotatable Bond Count:
1  
XLogP3:
0.7  

Literature

Title: Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects.

Journal: Organic letters 20121019

Title: Scanning tunneling microscopy study of nano-structured polyatom-substituted H4PW11M1O40 Keggin and H7P2W17M1O62 (M = Nb, Ta) Wells-Dawson heteropolyacid catalysts.

Journal: Journal of nanoscience and nanotechnology 20120701

Title: Atmospheric fate of methacrolein. 1. Peroxy radical isomerization following addition of OH and O2.

Journal: The journal of physical chemistry. A 20120621

Title: Atmospheric fate of methacrolein. 2. Formation of lactone and implications for organic aerosol production.

Journal: The journal of physical chemistry. A 20120621

Title: Branching ratios for the reaction of selected carbonyl-containing peroxy radicals with hydroperoxy radicals.

Journal: The journal of physical chemistry. A 20120621

Title: Reaction of methacrolein with the hydroxyl radical in air: incorporation of secondary O2 addition into the MACR + OH master equation.

Journal: The journal of physical chemistry. A 20120607

Title: Measurements of secondary organic aerosol formed from OH-initiated photo-oxidation of isoprene using online photoionization aerosol mass spectrometry.

Journal: Environmental science & technology 20120403

Title: The overall reaction process of ozone with methacrolein and isoprene in the condensed phase.

Journal: The journal of physical chemistry. A 20120223

Title: Mukaiyama-Michael reactions with acrolein and methacrolein: a catalytic enantioselective synthesis of the C17-C28 fragment of pectenotoxins.

Journal: Organic letters 20120217

Title: Acute airway irritation of methyl formate in mice.

Journal: Archives of toxicology 20120201

Title: Fermentative production of isobutene.

Journal: Applied microbiology and biotechnology 20120201

Title: A biomimetic polyketide-inspired approach to small-molecule ligand discovery.

Journal: Nature chemistry 20120201

Title: Direct detection of isoprene photooxidation products by using synchrotron radiation photoionization mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20120130

Title: Uptake of methacrolein into aqueous solutions of sulfuric acid and hydrogen peroxide.

Journal: The journal of physical chemistry. A 20120112

Title: Analysis of volatile organic compounds released from human lung cancer cells and from the urine of tumor-bearing mice.

Journal: Cancer cell international 20120101

Title: Oxygen radical-mediated oxidation reactions of an alanine peptide motif - density functional theory and transition state theory study.

Journal: Chemistry Central journal 20120101

Title: Nanostructured H(3+x)PW(12-x)NbxO40 (x = 0-3) Keggin heteropolyacid catalysts.

Journal: Journal of nanoscience and nanotechnology 20110901

Title: Denuder sampling techniques for the determination of gas-phase carbonyl compounds: a comparison and characterisation of in situ and ex situ derivatisation methods.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20110515

Title: Radical dependence of the yields of methacrolein and methyl vinyl ketone from the OH-initiated oxidation of isoprene under NO(x)-free conditions.

Journal: Environmental science & technology 20110201

Title: Detection of plant volatiles after leaf wounding and darkening by proton transfer reaction 'time-of-flight' mass spectrometry (PTR-TOF).

Journal: PloS one 20110101

Title: Quantitative determination of biogenic volatile organic compounds in the atmosphere using proton-transfer reaction linear ion trap mass spectrometry.

Journal: Analytical chemistry 20101001

Title: Uptake of methacrolein and methyl vinyl ketone by tree saplings and implications for forest atmosphere.

Journal: Environmental science & technology 20100915

Title: Quantum chemical study of the acrolein (CH2CHCHO) + OH + O2 reactions.

Journal: The journal of physical chemistry. A 20100819

Title: Kinetics and mechanism of the reaction of methacrolein with chlorine atoms in 1-950 Torr of N2 or N2/O2 diluent at 297 K.

Journal: The journal of physical chemistry. A 20100701

Title: N-Methacryloyl-4-(piperidin-1-yl)-1,8-naphthalimide.

Journal: Acta crystallographica. Section E, Structure reports online 20100601

Title: Aluminium complexes derived from tridentate thioetherbis(phenolate) ligands and their activity in Diels-Alder catalysis.

Journal: Dalton transactions (Cambridge, England : 2003) 20100514

Title: Heterogeneous reactions of methacrolein and methyl vinyl ketone on α-Al2O3 particles.

Journal: Environmental science & technology 20100315

Title: Narghile (water pipe) smoking among university students in Jordan: prevalence, pattern and beliefs.

Journal: Harm reduction journal 20100101

Title: Sub-chronic lung inflammation after airway exposures to Bacillus thuringiensis biopesticides in mice.

Journal: BMC microbiology 20100101

Title: Enantioselective synthesis of allylic alcohols via an oxazaborolidinium ion catalyzed Diels-Alder/Retro-Diels-Alder sequence.

Journal: Organic letters 20091119

Title: Quantum chemistry and TST study of the mechanisms and branching ratios for the reactions of OH with unsaturated aldehydes.

Journal: Physical chemistry chemical physics : PCCP 20090921

Title: Identification of degraded products of aldicarb due to the catalytic behavior of titanium dioxide/polyacrylonitrile nanofiber.

Journal: Journal of chromatography. A 20090904

Title: DFT study of the molecular mechanism of Lewis acid induced [4 + 3] cycloadditions of 2-alkylacroleins with cyclopentadiene.

Journal: The Journal of organic chemistry 20090821

Title: Hookah (Shisha, Narghile) Smoking and Environmental Tobacco Smoke (ETS). A critical review of the relevant literature and the public health consequences.

Journal: International journal of environmental research and public health 20090201

Title: Computational evaluation of enantioselective Diels-Alder reactions mediated by Corey's cationic oxazaborolidine catalysts.

Journal: The Journal of organic chemistry 20090116

Title: Chemical composition and size distribution of secondary organic aerosol formed from the photooxidation of isoprene.

Journal: Journal of environmental sciences (China) 20090101

Title: Volatile aldehydes in the mainstream smoke of the narghile waterpipe.

Journal: Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association 20081101

Title: Development of a proton-transfer reaction-linear ion trap mass spectrometer for quantitative determination of volatile organic compounds.

Journal: Analytical chemistry 20081101

Title: [Heterogeneous reactions on the surface of atmospheric particles: a transmission FTIR spectroscopy study].

Journal: Guang pu xue yu guang pu fen xi = Guang pu 20080801

Title: Chiral pyridylamino-ruthenium(II) complexes: synthesis, structure and catalytic properties in Diels-Alder reactions.

Journal: Dalton transactions (Cambridge, England : 2003) 20080707

Title: 6,6'-Substituent effect of BINOL in bis-titanium chiral Lewis acid catalyzed 1,3-dipolar cycloaddition of nitrones.

Journal: Organic & biomolecular chemistry 20080707

Title: A direct route to fluostatin C by a fascinating Diels-Alder reaction.

Journal: Journal of the American Chemical Society 20080305

Title: Release of volatile organic compounds (VOCs) from the lung cancer cell line CALU-1 in vitro.

Journal: Cancer cell international 20080101

Title: Asymmetric 1,3-dipolar cycloadditions of nitrones and methacrolein catalyzed by chiral bis-titanium lewis acid: a dramatic effect of N-substituent on nitrone.

Journal: Organic letters 20071108

Title: Pentamethylcyclopentadienyl-iridium(III) complexes with pyridylamino ligands: synthesis and applications as asymmetric catalysts for Diels-Alder reactions.

Journal: Dalton transactions (Cambridge, England : 2003) 20070521

Title: Overall rate constant measurements of the reaction of hydroxy- and chloroalkylperoxy radicals derived from methacrolein and methyl vinyl ketone with nitric oxide.

Journal: The journal of physical chemistry. A 20070201

Title: Conformational preferences of methacrolein in Diels-Alder and 1,3-dipolar cycloaddition reactions.

Journal: The Journal of organic chemistry 20061222

Title: Ozone's impact on public health: contributions from indoor exposures to ozone and products of ozone-initiated chemistry.

Journal: Environmental health perspectives 20061001

Title: Chemical composition of secondary organic aerosol formed from the photooxidation of isoprene.

Journal: The journal of physical chemistry. A 20060810

Title: Theoretical study on the Diels-Alder reaction between 2-methylacrolein and cyclopentadiene catalyzed by a cationic oxazaborolidine Lewis acid.

Journal: The journal of physical chemistry. A 20060727

Title: Ruthenium complexes of thiocinnamaldehydes: synthesis, structure, and [4+2]-cycloaddition reactions.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060614

Title: Priming of plant defense responses in nature by airborne signaling between Artemisia tridentata and Nicotiana attenuata.

Journal: Oecologia 20060601

Title: Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation.

Journal: Journal of the American Chemical Society 20060503

Title: A sensitive method for the quantification of acrolein and other volatile carbonyls in ambient air.

Journal: Analytical chemistry 20060401

Title: The uptake of methyl vinyl ketone, methacrolein, and 2-methyl-3-butene-2-ol onto sulfuric acid solutions.

Journal: The journal of physical chemistry. A 20060223

Title: Quantitative determination of volatile organic compounds in indoor dust using gas chromatography-UV spectrometry.

Journal: Environment international 20051001

Title: Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (eta5-C5Me5)M{(R)-prophos} containing complexes (M = Rh, Ir; (R)-prophos = 1,2-bis(diphenylphosphino)propane): on the origin of the enantioselectivity.

Journal: Journal of the American Chemical Society 20050928

Title: Pressure dependence in the methyl vinyl ketone + OH and methacrolein + OH oxidation reactions: an electronic structure study.

Journal: Chemphyschem : a European journal of chemical physics and physical chemistry 20050812

Title: Kinetics and products of the OH radical-initiated reaction of 3-methyl-2-butenal.

Journal: Physical chemistry chemical physics : PCCP 20050607

Title: Total synthesis of (+)-tubelactomicin A. 1. Stereoselective synthesis of the lower-half segment by an intramolecular Diels-Alder approach.

Journal: Organic letters 20050526

Title: Measurements of biogenic hydrocarbons and carbonyl compounds emitted by trees from temperate warm Atlantic rainforest, Brazil.

Journal: Journal of environmental monitoring : JEM 20050501

Title: [Ozonolysis of methacrolein and methyl vinyl ketone in aqueous solutions].

Journal: Huan jing ke xue= Huanjing kexue 20050501

Title: Simple diastereoselectivity of the BF3.OEt2-catalyzed vinylogous Mukaiyama aldol reaction of 2-(trimethylsiloxy)furans with aldehydes.

Journal: The Journal of organic chemistry 20050429

Title: The effect on human eye blink frequency of exposure to limonene oxidation products and methacrolein.

Journal: Toxicology letters 20050410

Title: Monitoring OH-initiated oxidation kinetics of isoprene and its products using online mass spectrometry.

Journal: Environmental science & technology 20050215

Title: Optimization of MoVSb oxide catalyst for partial oxidation of isobutane by combinatorial approaches.

Journal: Journal of combinatorial chemistry 20050101

Title: Differentiation of isobaric compounds using chemical ionization reaction mass spectrometry.

Journal: Rapid communications in mass spectrometry : RCM 20050101

Title: Cp*Rh complexes with pyridyloxazolines: synthesis, fluxionality and applications as asymmetric catalysts for Diels-Alder reactions.

Journal: Dalton transactions (Cambridge, England : 2003) 20041107

Title: Synthesis, conformational analysis, and cytotoxicity of conformationally constrained aplidine and tamandarin A analogues incorporating a spirolactam beta-turn mimetic.

Journal: Journal of medicinal chemistry 20041104

Title: Effects of 1,3-butadiene, isoprene, and their photochemical degradation products on human lung cells.

Journal: Environmental health perspectives 20041101

Title: [CpRu((R)-Binop-F)(H2O)][SbF6], a new fluxional chiral Lewis acid catalyst: synthesis, dynamic nmr, asymmetric catalysis, and theoretical studies.

Journal: Journal of the American Chemical Society 20040421

Title: The complete characterization of a rhodium Lewis acid-dipolarophile complex as an intermediate for the enantioselective catalytic 1,3-dipolar cycloaddition of C,N-diphenylnitrone to methacrolein.

Journal: Journal of the American Chemical Society 20040310

Title: Airborne observations of vegetation and implications for biogenic emission characterization.

Journal: Journal of environmental monitoring : JEM 20031201

Title: Description and characterization of an on-line system for long-term measurements of isoprene, methyl vinyl ketone, and methacrolein in ambient air.

Journal: Journal of chromatography. A 20030502

Title: Cycloaldol approach to the isobenzofuran core of eunicellin diterpenes.

Journal: Organic letters 20030403

Title: Highly stereoselective hydroxy-directed Diels-Alder reaction.

Journal: The Journal of organic chemistry 20030321

Title: New bulky chiral Lewis acid catalyst: 3,3'-di(2-mesitylethynyl)binaphthol-titanium(IV) complex.

Journal: Chirality 20030201

Title: Proton transfer reaction ion trap mass spectrometer.

Journal: Rapid communications in mass spectrometry : RCM 20030101

Title: Emission of alcohols and carbonyl compounds from a spark ignition engine. Influence of fuel and air/fuel equivalence ratio.

Journal: Environmental science & technology 20020601

Title: The influence of the solvents DMSO and ethanol on the genotoxicity of alpha,beta-unsaturated aldehydes in the SOS chromotest.

Journal: Mutation research 20020426

Title: Emissions of aldehydes and ketones from a two-stroke engine using ethanol and ethanol-blended gasoline as fuel.

Journal: Environmental science & technology 20020415

Title: Broadly effective enantioselective Diels-Alder reactions of 1-amino-substituted-1,3-butadienes.

Journal: Organic letters 20020404

Title: Airborne carbonyls from motor vehicle emissions in two highway tunnels.

Journal: Research report (Health Effects Institute) 20020101

Title: Enantioselective synthesis of the antiinflammatory agent (-)-acanthoic acid.

Journal: The Journal of organic chemistry 20011228

Title: Formation of strong airway irritants in mixtures of isoprene/ozone and isoprene/ozone/nitrogen dioxide.

Journal: Environmental health perspectives 20010901

Title: Characterization of chemical interferences in the determination of unsaturated aldehydes using aromatic hydrazine reagents and liquid chromatography.

Journal: Journal of environmental monitoring : JEM 20010601

Title: Ozone removal in the sampling of parts per billion levels of terpenoid compounds: an evaluation of different scrubber materials.

Journal: Environmental science & technology 20010401

Title: An application of electronic asymmetry to highly enantioselective catalytic Diels-Alder reactions.

Journal: Journal of the American Chemical Society 20010321

Title: On-road emissions of carbonyls from light-duty and heavy-duty vehicles.

Journal: Environmental science & technology 20010101

Title: Mutagenicity of 2-alkylpropenals in Salmonella typhimurium strain TA 100: structural influences.

Journal: Environmental and molecular mutagenesis 20010101

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