Home Pyridines 4411-80-7
4411-80-7,MFCD00059776
Catalog No.:AA0035ZZ

4411-80-7 | 6,6'-Dimethyl-2,2'-dipyridyl

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  • Technical Information
  • Properties
  • Literature
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0035ZZ
Chemical Name:
6,6'-Dimethyl-2,2'-dipyridyl
CAS Number:
4411-80-7
Molecular Formula:
C12H12N2
Molecular Weight:
184.2371
MDL Number:
MFCD00059776
SMILES:
Cc1cccc(n1)c1cccc(n1)C
NSC Number:
4705
Properties
Properties
 
BP:
278.6°C at 760 mmHg  
Form:
Solid  
MP:
93-95 °C(lit.);  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
161  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
14  
Hydrogen Bond Acceptor Count:
2  
Rotatable Bond Count:
1  
XLogP3:
2.3  

Literature

Title: Modulation in selectivity and allosteric properties of small-molecule ligands for CC-chemokine receptors.

Journal: Journal of medicinal chemistry 20120927

Title: Dibromido(6,6'-dimethyl-2,2'-bipyridine-κ(2)N,N')cadmium.

Journal: Acta crystallographica. Section E, Structure reports online 20120901

Title: Definition of an intramolecular Eu-to-Eu energy transfer within a discrete [Eu2L] complex in solution.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120625

Title: Pentacoordinate Ni(II) complexes: preparation, magnetic measurements, and ab initio calculations of the magnetic anisotropy terms.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120326

Title: Anti-mycobacterial activities of some cationic and anionic calix[4]arene derivatives.

Journal: Bioorganic & medicinal chemistry 20120315

Title: Diaqua-(5-carb-oxy-benzene-1,3-dicarboxyl-ato-κO,O)(6,6'-dimethyl-2,2'-bipyridine-κN,N')nickel(II) hepta-hydrate.

Journal: Acta crystallographica. Section E, Structure reports online 20110901

Title: (6,6'-Dimethyl-2,2'-bipyridine-κN,N')diiodidomercury(II).

Journal: Acta crystallographica. Section E, Structure reports online 20110301

Title: Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')cobalt(II).

Journal: Acta crystallographica. Section E, Structure reports online 20101001

Title: Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')cadmium(II).

Journal: Acta crystallographica. Section E, Structure reports online 20100801

Title: (2,2'-Bipyridine-κN,N')dibromido(dimethyl sulfoxide-κO)zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20100601

Title: Ferromagnetic coupling and magnetic anisotropy in oxalato-bridged trinuclear chromium(III)-cobalt(II) complexes with aromatic diimine ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20100307

Title: Photochemical stereospecific hydrogenation of a Ru complex with an NAD(+)/NADH-type ligand.

Journal: Inorganic chemistry 20091221

Title: Dibromido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: Dibenzoato-κO;κO,O'-(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II)-benzoic acid (1/1).

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: (6,6'-Dimethyl-2,2'-bipyridine-κN,N')diiodidozinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: Studies on bis(halogeno) dioxomolybdenum(VI)-bipyridine complexes: synthesis and catalytic activity.

Journal: Dalton transactions (Cambridge, England : 2003) 20091028

Title: Dichlorido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Journal: Acta crystallographica. Section E, Structure reports online 20091001

Title: Structural characterization, solution studies, and DFT calculations on a series of binuclear gold(III) oxo complexes: relationships to biological properties.

Journal: Inorganic chemistry 20080407

Title: Iron(II) complexes of sterically bulky alpha-ketocarboxylates. structural models for alpha-ketoacid-dependent nonheme iron halogenases.

Journal: Inorganic chemistry 20080218

Title: Structural and solution chemistry, antiproliferative effects, and DNA and protein binding properties of a series of dinuclear gold(III) compounds with bipyridyl ligands.

Journal: Journal of medicinal chemistry 20060907

Title: Ruthenium-cluster-mediated activation of all bonds of a methyl group of 6,6'-dimethyl-2,2'-bipyridine and 2,9-dimethyl-1,10-phenanthroline: transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenanthroline ligand.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060201

Title: Syntheses, structural analyses and redox kinetics of four-coordinate [CuL2]2+ and five-coordinate [CuL2(solvent)]2+ complexes (L = 6,6'-dimethyl-2,2'-bipyridine or 2,9-dimethyl-1,10-phenanthroline): completely gated reduction reaction of [Cu(dmp)2]2+ in nitromethane.

Journal: Dalton transactions (Cambridge, England : 2003) 20050321

Title: Structure-dependent photophysical properties of singlet and triplet metal-to-ligand charge transfer states in copper(I) bis(diimine) compounds.

Journal: Inorganic chemistry 20031006

Title: Luminescent lanthanide complexes of a bis-bipyridine-phosphine-oxide ligand as tools for anion detection.

Journal: Journal of the American Chemical Society 20020703

Application
6,6'-Dimethyl-2,2'-bipyridyl, also known as 6,6'-Dimethyl-2,2'-dipyridyl, is a compound utilized in organic synthesis for the preparation of novel oligobipyridine ligands. These ligands play essential roles in coordination chemistry, where they coordinate with metal ions to form stable complexes. The introduction of methyl groups at the 6th positions of both pyridine rings enhances the steric and electronic properties of the ligand, thereby influencing its coordination behavior and the properties of the resulting metal complexes. This compound's versatility makes it valuable for designing and synthesizing ligands tailored to specific applications in catalysis, materials science, and coordination chemistry.
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Tags:4411-80-7 Molecular Formula|4411-80-7 MDL|4411-80-7 SMILES|4411-80-7 6,6'-Dimethyl-2,2'-dipyridyl |Organic_Building_Blocks