Title: Polystyrene-supported TBD catalyzed ring-opening of N-tosylaziridines with silylated nucleophiles.
Journal: Organic & biomolecular chemistry 20120707
Title: Synthesis, structure and unique reactivity of the ethylzinc derivative of a bicyclic guanidine.
Journal: Dalton transactions (Cambridge, England : 2003) 20120521
Title: One-pot synthesis of trichloromethyl carbinols from primary alcohols.
Journal: The Journal of organic chemistry 20120518
Title: A hydrogen-bridged adduct 3,4,6,7,8,9-hexa-hydro-2H-pyrimido[1,2-a]pyrimidin-1-ium [1,3-bis-(tert-butyl-dimethyl-sil-yloxy)-1,3-bis-(pyridin-2-yl)propan-2-yl-idene]nitro-nate acetonitrile monosolvate.
Journal: Acta crystallographica. Section E, Structure reports online 20110901
Title: X-ray crystallographic, FT-IR, and density functional theory studies of the salt formed between dipicrylamine and 1,5,7-triazabicyclo[4.4.0]dec-1-ene.
Journal: The journal of physical chemistry. A 20110804
Title: Direct aldol reactions catalyzed by a heterogeneous guanidinium salt/proline system under solvent-free conditions.
Journal: Organic letters 20110617
Title: Theoretical mechanistic study of the TBD-catalyzed intramolecular aldol reaction of ketoaldehydes.
Journal: The Journal of organic chemistry 20100716
Title: Catalytic coupling of CO2 with epoxide over supported and unsupported amines.
Journal: The journal of physical chemistry. A 20100325
Title: Coordination of neutral, methylene bridged bis-guanidyls at palladium.
Journal: Dalton transactions (Cambridge, England : 2003) 20100214
Title: A short, unsupported CuI...CuI interaction, 2.65 A, in a dinuclear guanidine chloride complex.
Journal: Chemical communications (Cambridge, England) 20100107
Title: Proof by EPR spectroscopy that the unpaired electron in an Os(2)(7+) species is in a delta* metal-based molecular orbital.
Journal: Inorganic chemistry 20100104
Title: Cyclic guanidine organic catalysts: what is magic about triazabicyclodecene?
Journal: The Journal of organic chemistry 20091218
Title: Superbasicity of a bis-guanidino compound with a flexible linker: a theoretical and experimental study.
Journal: Journal of the American Chemical Society 20091125
Title: Lanthanide metallocene complexes of the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinato Ligand, (hpp)1-.
Journal: Inorganic chemistry 20081201
Title: A structural, theoretical and coordinative evaluation of the bicyclic guanidinate derived from 1,4,6-triazabicyclo[3.3.0]oct-4-ene.
Journal: Dalton transactions (Cambridge, England : 2003) 20080828
Title: On the performance of ligand field molecular mechanics for model complexes containing the peroxido-bridged [Cu2O2]2+ center.
Journal: Inorganic chemistry 20080407
Title: Structure and vibrational spectrum of the hydrogen-bonded system between 4-tert-butylphenol and N-bases: Ab initio and DFT studies.
Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20080201
Title: A Lewis-basic, dionio-substituted phosphane.
Journal: Chemical communications (Cambridge, England) 20071228
Title: Dinuclear and tetranuclear gold-nitrogen complexes. Solvent influences on oxidation and nuclearity of gold guanidinate derivatives.
Journal: Inorganic chemistry 20071224
Title: Nucleophilic activity of a linked bis{guanidine} leading to formation of a dicationic C4N4-heterocycle.
Journal: Organic & biomolecular chemistry 20071221
Title: The mechanism of TBD-catalyzed ring-opening polymerization of cyclic esters.
Journal: The Journal of organic chemistry 20071207
Title: Theoretical study of the structures and vibrational spectra of the hydrogen-bonded systems of 4-cyanophenol with N-bases.
Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20071101
Title: Triazabicyclodecene: an effective isotope exchange catalyst in CDCl(3).
Journal: The Journal of organic chemistry 20070622
Title: Stepwise nucleophilic substitution of manganocene, syntheses and structures of the dimer [CpMn(hpp)]2 and the unusual manganate cage [LiMn(hpp)3]2 (hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2,a]pyrimidine).
Journal: Dalton transactions (Cambridge, England : 2003) 20070428
Title: Encapsulation of hydride by molecular main group metal clusters: manipulating the source and coordination sphere of the interstitial ion.
Journal: Dalton transactions (Cambridge, England : 2003) 20061221
Title: Grid-based molecular modeling for pharmaceutical salt screening: Case example of 3,4,6,7,8,9-hexahydro-2H-pyrimido (1,2-a) pyrimidinium acetate.
Journal: Journal of pharmaceutical sciences 20061101
Title: Organocatalytic living ring-opening polymerization of cyclic carbosiloxanes.
Journal: Organic letters 20061012
Title: Triazabicyclodecene: a simple bifunctional organocatalyst for acyl transfer and ring-opening polymerization of cyclic esters.
Journal: Journal of the American Chemical Society 20060412
Title: Facilitating access to the most easily ionized molecule: an improved synthesis of the key intermediate, W2(hpp)4Cl2, and related compounds.
Journal: Inorganic chemistry 20060109
Title: Expeditious access to the most easily ionized closed-shell molecule, W2(hpp)4.
Journal: Journal of the American Chemical Society 20050810
Title: Spontaneous assembly of a nine-vertex lithium framework encapsulating the peroxide dianion.
Journal: Chemical communications (Cambridge, England) 20050707
Title: An example where orbital relaxation is an important contribution to the Fukui function.
Journal: The journal of physical chemistry. A 20050217
Title: Multiple coordination geometries supported by methylene-linked guanidines.
Journal: Inorganic chemistry 20041129
Title: The structural characteristics of organozinc complexes incorporating N,N'-bidentate ligands.
Journal: Dalton transactions (Cambridge, England : 2003) 20041107
Title: M2(hpp)4Cl2 and M2(hpp)4, where M = Mo and W: preparations, structure and bonding, and comparisons with C2, C2H2, and C2Cl2 and the hypothetical molecules M2(hpp)4(H)2.
Journal: Journal of the American Chemical Society 20031224
Title: Structural and catalytic properties of bis(guanidine)copper(I) halides.
Journal: Inorganic chemistry 20030519
Title: The first structurally confirmed paddlewheel compound with an M(2)(7+) core: [Os(2)(hpp)(4)Cl(2)](PF(6)).
Journal: Inorganic chemistry 20030210
Title: Closed-shell molecules that ionize more readily than cesium.
Journal: Science (New York, N.Y.) 20021206
Title: The extraordinary ability of guanidinate derivatives to stabilize higher oxidation numbers in dimetal units by modification of redox potentials: structures of Mo(2)(5+) and Mo(2)(6+) compounds.
Journal: Journal of the American Chemical Society 20020807
1,5,7-Triazabicyclo[4.4.0]dec-5-ene serves as a versatile organocatalyst in various chemical transformations. Firstly, it facilitates the aminolysis of esters, enabling the efficient conversion of ester substrates into amine products. Additionally, it acts as a catalyst for the direct addition of P(O)-H bonds (such as dialkyl phosphites and diphenyl phosphonite) across activated alkenes, leading to the formation of valuable phosphorus-containing compounds. Furthermore, polymer-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (PTBD) serves as both a base and a reagent scavenger in the synthesis of aryl ethers from phenols and alkyl or aryl halides, enhancing the efficiency and ease of the reaction process. Overall, 1,5,7-Triazabicyclo[4.4.0]dec-5-ene demonstrates significant utility as a catalyst and reagent in diverse organic transformations, offering opportunities for efficient and selective synthesis of complex molecules.
