+1 858-523-8231
Login | Register
AA Blocks, Building Blocks, Catalysts, Inhibitors
Login | Register
Home Other Building Blocks 64896-28-2
64896-28-2,MFCD00009836
Catalog No.:AA003BMA

64896-28-2 | (2S,3S)-(-)-Bis(diphenylphosphino)butane

Pack Size
Purity
Availability
Price(USD)
Quantity
  
100mg
98% 99%ee
in stock  
$29.00   $21.00
- +
250mg
98% 99%ee
in stock  
$36.00   $25.00
- +
1g
98% 99%ee
in stock  
$134.00   $94.00
- +
5g
98% 99%ee
in stock  
$652.00   $457.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003BMA
Chemical Name:
(2S,3S)-(-)-Bis(diphenylphosphino)butane
CAS Number:
64896-28-2
Molecular Formula:
C28H28P2
Molecular Weight:
426.4694
MDL Number:
MFCD00009836
SMILES:
C[C@H](P(c1ccccc1)c1ccccc1)[C@@H](P(c1ccccc1)c1ccccc1)C
Properties
Properties
 
Form:
Solid  
MP:
104-109 °C  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
387  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
2  
Heavy Atom Count:
30  
Rotatable Bond Count:
7  
XLogP3:
6.7  

Downstream Synthesis Route

[1]ChemistryLetters,1984,p.1603-1606

[1]JournaloftheChemicalSociety.Chemicalcommunications,1986,p.202-203

(3S,4S,5R)-3,4-Bis-diphenylphosphanyl-5-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-dihydro-furan-2-one 
  64896-28-2 

[1]TetrahedronAsymmetry,1990,vol.1,p.719-720

[1]JournalofPhysicalChemistry,1991,vol.95,p.9256-9263

[1]JournalofOrganometallicChemistry,1981,vol.221,p.203-222

Literature

Title: Enantioselective synthesis of chiral sulfones by Rh-catalyzed asymmetric addition of boronic acids to alpha,beta-unsaturated 2-pyridyl sulfones.

Journal: The Journal of organic chemistry 20071221

Title: Stereoselective Rh-catalyzed hydrogenation of cyclobutyl chiral enamides: double stereodifferentiation vs catalyst-controlled diastereoselection.

Journal: The Journal of organic chemistry 20041112

Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Related Products of 64896-28-2
1663-45-2

1663-45-2

 14647-23-5

14647-23-5

 7650-84-2

7650-84-2

 67884-32-6

67884-32-6

 1519-45-5

1519-45-5

 18024-34-5

18024-34-5
Building Blocks
More >
Tags:64896-28-2 Molecular Formula|64896-28-2 MDL|64896-28-2 SMILES|64896-28-2 (2S,3S)-(-)-Bis(diphenylphosphino)butane