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6283-74-5,MFCD00037918
Catalog No.:AA003BQC

6283-74-5 | (+)-Diacetyl-l-tartaric anhydride

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
95%
in stock  
$26.00   $18.00
- +
5g
97%
in stock  
$29.00   $20.00
- +
25g
97%
in stock  
$59.00   $41.00
- +
100g
97%
in stock  
$170.00   $119.00
- +
500g
97%
in stock  
$793.00   $555.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003BQC
Chemical Name:
(+)-Diacetyl-l-tartaric anhydride
CAS Number:
6283-74-5
Molecular Formula:
C8H8O7
Molecular Weight:
216.1449
MDL Number:
MFCD00037918
SMILES:
CC(=O)O[C@H]1C(=O)OC(=O)[C@@H]1OC(=O)C
Properties
Properties
 
BP:
350.6 °C at 760 mmHg  
Form:
Solid  
MP:
130-135 °C(lit.)  
Refractive Index:
90 ° (C=0.5, CHCl3)  
Stability:
Moisture Sensitive  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
300  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
2  
Heavy Atom Count:
15  
Hydrogen Bond Acceptor Count:
7  
Rotatable Bond Count:
4  
XLogP3:
-0.4  

Downstream Synthesis Route

[1]TetrahedronAsymmetry,1996,vol.7,p.1477-1484

[2]AngewandteChemie-InternationalEdition,2010,vol.49,p.7096-7100

[3]AngewandteChemie-InternationalEdition,2015,vol.54,p.6012-6015    Angew.Chem.,2015,vol.127,p.6110-6113,4

[4]Patent:CN106588773,2017,A.Locationinpatent:Paragraph0130

[5]TetrahedronLetters,2015,vol.56,p.5306-5308

[6]Patent:WO2013/8194,2013,A2.Locationinpatent:Page/Pagecolumn12

[7]Patent:US2015/65704,2015,A1.Locationinpatent:Paragraph0073

[8]OrganicLetters,2009,vol.11,p.645-648

[9]Tetrahedron,1995,vol.51,p.5935-5950

[10]JournaloftheChemicalSocietyofPakistan,2014,vol.36,p.170-176

[11]TetrahedronAsymmetry,1996,vol.7,p.1189-1198

[12]Patent:WO2010/110775,2010,A1.Locationinpatent:Page/Pagecolumn18-19

[13]Patent:EP2116526,2009,A1.Locationinpatent:Page/Pagecolumn10-11

[14]Organicsyntheses.Collectivevolume,1963,vol.IV,p.242

[15]Patent:US2520139,1948,A

[16]JournaloftheAmericanChemicalSociety,1941,vol.63,p.1653,1655

[17]Patent:US2010/331345,2010,A1.Locationinpatent:Page/Pagecolumn7

[18]AsianJournalofChemistry,2013,vol.25,p.745-748

[19]JournalofPhysicalChemistryB,2017,vol.121,p.1629-1639

[20]Patent:WO2017/155875,2017,A1.Locationinpatent:Page/Pagecolumn23-24

[21]Patent:US2019/233363,2019,A1.Locationinpatent:Page/Pagecolumn0068-0071

[22]JournalofRamanSpectroscopy,2022

[1]Patent:US2016/326182,2016,A1.Locationinpatent:Paragraph0669;0670

[2]TetrahedronLetters,2015,vol.56,p.5306-5308

[3]OrganicLetters,2009,vol.11,p.645-648

[4]JournaloftheChemicalSocietyofPakistan,2014,vol.36,p.170-176

[5]JournaloftheAmericanChemicalSociety,1941,vol.63,p.1653,1655

[6]Patent:US2308385,1942,A

[7]AsianJournalofChemistry,2013,vol.25,p.745-748

[1]Patent:US2236516,1938,A

[2]JournalofPhysicalChemistryB,2017,vol.121,p.1629-1639

[3]Patent:US2019/233363,2019,A1.Locationinpatent:Page/Pagecolumn0068-0070

[1]Pressman;Bryden;Pauling[JournaloftheAmericanChemicalSociety,1948,vol.70,p.1354]

108-99-6    6283-74-5   
3-Hydroxy-furan-2,5-dione;compoundwith3-methyl-pyridine 

[1]JournalofOrganicChemistry,1993,vol.58,p.756-758

Literature

Title: Determination of naftopidil enantiomers in rat plasma using chiral solid phases and pre-column derivatization high-performance liquid chromatography.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20121015

Title: L(+) and D(-) lactate are increased in plasma and urine samples of type 2 diabetes as measured by a simultaneous quantification of L(+) and D(-) lactate by reversed-phase liquid chromatography tandem mass spectrometry.

Journal: Experimental diabetes research 20120101

Title: 2-hydroxyglutarate production, but not dominant negative function, is conferred by glioma-derived NADP-dependent isocitrate dehydrogenase mutations.

Journal: PloS one 20110101

Title: Enantioselective determination of trantinterol in rat plasma by ultra performance liquid chromatography-electrospray ionization mass spectrometry after derivatization.

Journal: Talanta 20091015

Title: Measurement of urinary D- and L-2-hydroxyglutarate enantiomers by stable-isotope-dilution liquid chromatography-tandem mass spectrometry after derivatization with diacetyl-L-tartaric anhydride.

Journal: Clinical chemistry 20040801

Title: Stereoselective metabolism of pentoxifylline in vitro and in vivo in humans.

Journal: Chirality 20020801

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Tags:6283-74-5 Molecular Formula|6283-74-5 MDL|6283-74-5 SMILES|6283-74-5 (+)-Diacetyl-l-tartaric anhydride