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35231-44-8,MFCD00006869
Catalog No.:AA003K3S

35231-44-8 | 4-Bromomethyl-7-methoxycoumarin

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250mg
98%
in stock  
$13.00   $9.00
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1g
98%
in stock  
$46.00   $32.00
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5g
98%
in stock  
$219.00   $153.00
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10g
98%
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$373.00   $261.00
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25g
98%
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$567.00   $397.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003K3S
Chemical Name:
4-Bromomethyl-7-methoxycoumarin
CAS Number:
35231-44-8
Molecular Formula:
C11H9BrO3
Molecular Weight:
269.0914
MDL Number:
MFCD00006869
SMILES:
COc1ccc2c(c1)oc(=O)cc2CBr
Properties
Properties
 
BP:
385.3°C at 760 mmHg  
Form:
Solid  
MP:
213-215 °C(lit.);  
Solubility:
chloroform: soluble20mg/mL, clear, colorless to faintly yellow  
Storage:
Inert atmosphere;2-8℃;  

Computed Properties
 
Complexity:
288  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
15  
Hydrogen Bond Acceptor Count:
3  
Rotatable Bond Count:
2  
XLogP3:
2.4  

Downstream Synthesis Route

[1]BioorganicandMedicinalChemistry,2010,vol.18,p.3543-3550

[2]JournalOfScientificandIndustrialResearch,1953,vol.12B,p.346,348

[3]IndianJournalofHeterocyclicChemistry,2010,vol.19,p.233-236

[4]BioorganicandMedicinalChemistryLetters,2012,vol.22,p.4807-4809

[1]JournalOfScientificandIndustrialResearch,1952,vol.11B,p.39,43

[1]JournalOfScientificandIndustrialResearch,1953,vol.12B,p.346,348

35231-44-8   
((Ξ)-6-methoxy-benzofuran-3-yliden)-aceticacid 

[1]JournaloftheIndianChemicalSociety,1934,vol.11,p.635,648

62935-72-2    35231-44-8   
bromo-(7-methoxy-2-oxo-2<i>H</i>-chromen-4-yl)-aceticacid 

[1]JournaloftheIndianChemicalSociety,1934,vol.11,p.635,648

Literature

Title: Examining the interactome of huperzine A by magnetic biopanning.

Journal: PloS one 20120101

Title: Determination of tegafur, 5-fluorouracil, gimeracil and oxonic acid in human plasma using liquid chromatography-tandem mass spectrometry.

Journal: Journal of pharmaceutical and biomedical analysis 20100801

Title: Simultaneous determination of 6-methylcoumarin and 7-methoxycoumarin in cosmetics using three-dimensional excitation-emission matrix fluorescence coupled with second-order calibration methods.

Journal: Talanta 20080615

Title: A new method for the HPLC determination of gamma-hydroxybutyric acid (GHB) following derivatization with a coumarin analogue and fluorescence detection: application in the analysis of biological fluids.

Journal: Talanta 20080415

Title: Determination of sodium monofluoroacetate (1080) in biological samples as its 4-bromomethyl-7-methoxycoumarin derivative by RP-HPLC.

Journal: Journal of chromatographic science 20070801

Title: Identification of lipid binders in old oil paintings by separation of 4-bromomethyl-7-methoxycoumarin derivatives of fatty acids by liquid chromatography with fluorescence detection.

Journal: Journal of chromatography. A 20050527

Title: Steviol quantification at the picomole level by high-performance liquid chromatography.

Journal: Journal of agricultural and food chemistry 20040505

Title: Uracil in human DNA from subjects with normal and impaired folate status as determined by high-performance liquid chromatography-tandem mass spectrometry.

Journal: Analytical chemistry 20020101

Title: The validity of two HPLC methods and a colorimetric PP2A assay related to the mouse bioassay in quantification of diarrhetic toxins in blue mussels (Mytilus edulis).

Journal: Toxicon : official journal of the International Society on Toxinology 20010901

Title: The repeatability of two HPLC methods and the PP2A assay in the quantification of diarrhetic toxins in blue mussels (Mytilus edulis).

Journal: Toxicon : official journal of the International Society on Toxinology 20010401

Title: Wolf JH, et al. 4-Bromomethyl-7-methoxycoumarin and analogues as derivatization agents for high-performance liquid chromatography determinations: a review. J Pharm Biomed Anal. 1992 Feb-Mar;10(2-3):99-107.

Title: Wang K, et al. Derivatization of 5-fluorouracil with 4-bromomethyl-7-methoxycoumarin for determination by liquid chromatography-mass spectrometry. J Am Soc Mass Spectrom. 1998 Sep;9(9):970-6.

Title: Hagen V, et al. Synthesis, photochemistry and application of (7-methoxycoumarin-4-yl)methyl-caged 8-bromoadenosine cyclic 3',5'-monophosphate and 8-bromoguanosine cyclic 3',5'-monophosphate photolyzed in the nanosecond time region. J Photochem Photobiol B. 1999 Nov-Dec;53(1-3):91-102.

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SDS
Tags:35231-44-8 Molecular Formula|35231-44-8 MDL|35231-44-8 SMILES|35231-44-8 4-Bromomethyl-7-methoxycoumarin