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77-78-1,MFCD00008416
Catalog No.:AA00IKDC

77-78-1 | Sulfuric acid, dimethyl ester

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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA00IKDC
Chemical Name:
Sulfuric acid, dimethyl ester
CAS Number:
77-78-1
Molecular Formula:
C2H6O4S
Molecular Weight:
126.1316
MDL Number:
MFCD00008416
SMILES:
COS(=O)(=O)OC
NSC Number:
56194
UN Number:
1595
Properties
Computed Properties
 
Complexity:
107  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
4  
Rotatable Bond Count:
2  
XLogP3:
-0.3  

Literature

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Title: A convenient and safe O-methylation of flavonoids with dimethyl carbonate (DMC).

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Title: The inhibitory effect of raloxifene on lipopolysaccharide-induced nitric oxide production in RAW264.7 cells is mediated through a ROS/p38 MAPK/CREB pathway to the up-regulation of heme oxygenase-1 independent of estrogen receptor.

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Title: N-methylpurines are heterogeneously repaired in human mitochondria but not evidently repaired in yeast mitochondria.

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Title: Health-Beneficial Phenolic Aldehyde in Antigonon leptopus Tea.

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Title: Artificial 64-Residue HIV-1 Enhancer-Binding Peptide Is a Potent Inhibitor of Viral Replication in HIV-1-Infected Cells.

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Journal: Cellular and molecular life sciences : CMLS 20101101

Title: Comparisons between chemical mapping and binding to isoenergetic oligonucleotide microarrays reveal unexpected patterns of binding to the Bacillus subtilis RNase P RNA specificity domain.

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Title: In vitro and in vivo pharmacological profile of the 5-benzyl analogue of 14-methoxymetopon, a novel mu opioid analgesic with reduced propensity to alter motor function.

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Title: Base excision repair in a glucocorticoid response element: effect of glucocorticoid receptor binding.

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Title: Determination of haloacetic acids in human urine by headspace gas chromatography-mass spectrometry.

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Title: The influence of chromatin structure on DNA damage induced by nitrogen mustard and cisplatin analogues.

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Title: Protein-facilitated folding of group II intron ribozymes.

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Title: Synthesis and antimicrobial activities of some new thiazole and pyrazole derivatives based on 4,5,6,7-tetrahydrobenzothiophene moiety.

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Title: A study of the interactions that stabilize DNA frayed wires.

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Title: Inhibition of Escherichia coli glycosyltransferase MurG and Mycobacterium tuberculosis Gal transferase by uridine-linked transition state mimics.

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Title: Headspace in-tube extraction gas chromatography-mass spectrometry for the analysis of hydroxylic methyl-derivatized and volatile organic compounds in blood and urine.

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Title: Chemical and enzymatic probing of spatial structure of the omega leader of tobacco mosaic virus RNA.

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Title: (8-Bromo-2,7-dimeth-oxy-1-naphth-yl)(4-chloro-phenyl)methanone.

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Title: 3-Benzoyl-4-hydr-oxy-2-methyl-2H-1,2-benzothia-zine 1,1-dioxide.

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Title: Chronic diseases and early exposure to airborne mixtures: Part III. Potential origin of pre-menopausal breast cancers.

Journal: Journal of exposure science & environmental epidemiology 20100301

Title: Optimisation and comparison of several microextraction/methylation methods for determining haloacetic acids in water using gas chromatography.

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Title: Reactivity of heteropolytungstate and heteropolymolybdate metal transition salts in the synthesis of dimethyl carbonate from methanol and CO₂.

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Title: Regulation of CEACAM1 transcription in human breast epithelial cells.

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Title: Inhalational exposure to dimethyl sulfate vapor followed by reactive airway dysfunction syndrome.

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Title: Determination of low ppm levels of dimethyl sulfate in an aqueous soluble API intermediate using liquid-liquid extraction and GC-MS.

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Title: NMR of a series of novel hydroxyflavothiones.

Journal: Magnetic resonance in chemistry : MRC 20091201

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Title: 4,5-Dichloro-2-methyl-pyridazin-3(2H)-one.

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Journal: DNA repair 20090301

Title: Occupational allergic contact dermatitis due to dimethyl sulfate following sensitization from a severe acute irritant reaction to the reagent.

Journal: Contact dermatitis 20090301

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Title: In cellulo DNA analysis (LMPCR footprinting).

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Journal: PloS one 20090101

Title: Nitrosamine exposure exacerbates high fat diet-mediated type 2 diabetes mellitus, non-alcoholic steatohepatitis, and neurodegeneration with cognitive impairment.

Journal: Molecular neurodegeneration 20090101

Title: Probing RNA structure within living cells.

Journal: Methods in enzymology 20090101

Title: Ethyl 5-amino-3-methyl-sulfan-yl-1H-pyrazole-4-carboxyl-ate.

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Title: Efficient synthesis of alkyl beta-diketimines.

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Title: Simple and rapid method for the determination of ethylenebisdithiocarbamate fungicides in fruits and vegetables using liquid chromatography with tandem mass spectrometry.

Journal: Analytical and bioanalytical chemistry 20081101

Title: Urinary 1-hydroxypyrene and malondialdehyde in male workers in Chinese restaurants.

Journal: Occupational and environmental medicine 20081101

Title: CTCF cis-regulates trinucleotide repeat instability in an epigenetic manner: a novel basis for mutational hot spot determination.

Journal: PLoS genetics 20081101

Title: Simultaneous liquid-liquid microextraction/methylation for the determination of haloacetic acids in drinking waters by headspace gas chromatography.

Journal: Journal of chromatography. A 20081031

Title: 2,2'-Dimethoxy-biphen-yl.

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Title: Ribosome-small-subunit-dependent GTPase interacts with tRNA-binding sites on the ribosome.

Journal: Journal of molecular biology 20080829

Title: Determination of OH groups in humic acids using methylation with dimethylsulfate.

Journal: Talanta 20080815

Title: (E)-6-Meth-oxy-9-methyl-1,2,3,4-tetra-hydro-9H-carbazol-4-one oxime.

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Title: Monitoring of dimethyl sulphate-induced N3-methyladenine, N7-methylguanine and O(6)-methylguanine DNA adducts using reversed-phase high performance liquid chromatography and mass spectrometry.

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Title: Crystal structure of NFAT bound to the HIV-1 LTR tandem kappaB enhancer element.

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Title: 1-(4-Hydr-oxy-2-methyl-1,1-dioxo-2H-1,2-benzothia-zin-3-yl)ethanone.

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Title: The proximal promoter region of the human vascular endothelial growth factor gene has a G-quadruplex structure that can be targeted by G-quadruplex-interactive agents.

Journal: Molecular cancer therapeutics 20080401

Title: Genetic possibilities for altering sunflower oil quality to obtain novel oils.

Journal: Canadian journal of physiology and pharmacology 20080401

Title: High-throughput SHAPE analysis reveals structures in HIV-1 genomic RNA strongly conserved across distinct biological states.

Journal: PLoS biology 20080401

Title: 2-Methyl-1,2-benzisothia-zol-3(2H)-one 1,1-dioxide.

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Title: Determination of anti-inflammatory drugs in water samples, by in situ derivatization, solid phase microextraction and gas chromatography-mass spectrometry.

Journal: Talanta 20080315

Title: [Determination of dimethyl sulphate residual in granisetron hydrochloride by headspace gas chromatography].

Journal: Zhejiang da xue xue bao. Yi xue ban = Journal of Zhejiang University. Medical sciences 20080301

Title: (Z)-Methyl 2-methoxy-imino-3-oxo-butanoate.

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Title: Shape-persistent macrocycles with intraannular alkyl groups: some structural limits of discotic liquid crystals with an inverted structure.

Journal: Beilstein journal of organic chemistry 20080101

Title: Investigation of Zinc bis(1,4-didecylbenzo)-bis(2,3-pyrido) Porphyrazine for Application as Photosensitizer in Photodynamic Therapy of Cancer.

Journal: Metal-based drugs 20080101

Title: Proteome alteration induced by hTERT transfection of human fibroblast cells.

Journal: Proteome science 20080101

Title: Methylation interference assay.

Journal: CSH protocols 20071201

Title: In vivo footprint of a picornavirus internal ribosome entry site reveals differences in accessibility to specific RNA structural elements.

Journal: The Journal of general virology 20071101

Title: A modified host-cell reactivation assay to measure repair of alkylating DNA damage for assessing risk of lung adenocarcinoma.

Journal: Carcinogenesis 20070701

Title: Synthesis and mechanical properties of quaternary salts of chitosan-based films for food application.

Journal: International journal of biological macromolecules 20070701

Title: Optimization of the palindromic order of the TtgR operator enhances binding cooperativity.

Journal: Journal of molecular biology 20070622

Title: The transcriptional repressor TtgV recognizes a complex operator as a tetramer and induces convex DNA bending.

Journal: Journal of molecular biology 20070615

Title: Methylation of sydnone N-oxides: kinetic and thermodynamic control in the alkylation site of an electron-rich heterocycle.

Journal: The Journal of organic chemistry 20070511

Title: Theoretical study on the Br + CH3SCH3 reaction.

Journal: Journal of computational chemistry 20070501

Title: Protein-induced conformational changes of RNA during the assembly of human signal recognition particle.

Journal: Journal of molecular biology 20070316

Title: Group II intron folding under near-physiological conditions: collapsing to the near-native state.

Journal: Journal of molecular biology 20070302

Title: Simplified method for determination of polycarbamate fungicide in water samples by liquid chromatography with tandem mass spectrometry following derivatization with dimethyl sulfate.

Journal: Journal of chromatography. A 20070209

Title: Polyaniline doped with dimethyl sulfate as a nucleophilic dopant and its electrochemical properties as an electrode in a lithium secondary battery and a redox supercapacitor.

Journal: The journal of physical chemistry. B 20070201

Title: [Nasopharyngeal manifestations and outcomes of acute dimethyl sulfate poisoning].

Journal: Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases 20070201

Title: [Clinical observation and treatment of acute severe dimethyl sulfate poisoning].

Journal: Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases 20070201

Title: Seven Golden Rules for heuristic filtering of molecular formulas obtained by accurate mass spectrometry.

Journal: BMC bioinformatics 20070101

Title: Lower-rim substituted calixarenes and their applications.

Journal: Bioinorganic chemistry and applications 20070101

Title: Characterization of a negative transcriptional element in the BRCA1 promoter.

Journal: Breast cancer research : BCR 20070101

Title: Aroylketene dithioacetal chemistry: facile synthesis of 4-aroyl-3-methylsulfanyl-2-tosylpyrroles from aroylketene dithioacetals and TosMIC.

Journal: Beilstein journal of organic chemistry 20070101

Title: Real-time dynamics of ribosome-ligand interaction by time-resolved chemical probing methods.

Journal: Methods in enzymology 20070101

Title: DMS footprinting of structured RNAs and RNA-protein complexes.

Journal: Nature protocols 20070101

Title: Simple fluorescent sensors engineered with catalytic DNA 'MgZ' based on a non-classic allosteric design.

Journal: PloS one 20070101

Title: Synthesis and evaluation of general mechanism-based inhibitors of sulfatases based on (difluoro)methyl phenyl sulfate and cyclic phenyl sulfamate motifs.

Journal: Bioorganic & medicinal chemistry 20061215

Title: Pokeweed antiviral protein depurinates the sarcin/ricin loop of the rRNA prior to binding of aminoacyl-tRNA to the ribosomal A-site.

Journal: RNA (New York, N.Y.) 20060901

Title: Analysis of odorous trichlorobromophenols in water by in-sample derivatization/solid-phase microextraction GC/MS.

Journal: Analytical and bioanalytical chemistry 20060901

Title: rRNA promoter regulation by nonoptimal binding of sigma region 1.2: an additional recognition element for RNA polymerase.

Journal: Cell 20060616

Title: Study of properties of modified silicones at solid-liquid interface: fabric-silicone interactions.

Journal: Journal of colloid and interface science 20060615

Title: Temperature and pressure dependence of the rate constants of the reaction of NO3 radical with CH3SCH3.

Journal: The journal of physical chemistry. A 20060615

Title: Structure determination and phase transition behaviour of dimethyl sulfate.

Journal: Acta crystallographica. Section B, Structural science 20060401

Title: [An accident of acute dimethyl sulfate poisoning].

Journal: Zhonghua lao dong wei sheng zhi ye bing za zhi = Zhonghua laodong weisheng zhiyebing zazhi = Chinese journal of industrial hygiene and occupational diseases 20060401

Title: The GTP-binding protein YlqF participates in the late step of 50 S ribosomal subunit assembly in Bacillus subtilis.

Journal: The Journal of biological chemistry 20060324

Title: Optimized selective N-methylation of peptides on solid support.

Journal: Journal of peptide science : an official publication of the European Peptide Society 20060301

Title: A new protein superfamily includes two novel 3-methyladenine DNA glycosylases from Bacillus cereus, AlkC and AlkD.

Journal: Molecular microbiology 20060301

Title: An industrial process for selective synthesis of 7-methyl guanosine 5'-diphosphate: versatile synthon for synthesis of mRNA cap analogues.

Journal: Nucleosides, nucleotides & nucleic acids 20060301

Title: Bioassay monitoring of waste PCB samples during chemical destruction treatments.

Journal: Water science and technology : a journal of the International Association on Water Pollution Research 20060101

Title: Nine cases of accidental exposure to dimethyl sulphate--a potential chemical weapon.

Journal: Emergency medicine journal : EMJ 20051201

Title: Diabetes alters the occupancy of the hepatic 3-hydroxy-3-methylglutaryl-CoA reductase promoter.

Journal: The Journal of biological chemistry 20051104

Title: Cross-links of quadruplex structures from human telomeric DNA by dinuclear platinum complexes show the flexibility of both structures.

Journal: Biochemistry 20050809

Title: In vivo DNase I-mediated footprinting analysis along the human bradykinin B1 receptor (BDKRB1) gene promoter: evidence for cell-specific regulation.

Journal: The Biochemical journal 20050701

Title: Convenient synthesis of N-methylamino acids compatible with Fmoc solid-phase peptide synthesis.

Journal: The Journal of organic chemistry 20050624

Title: Matrix-isolation FT-IR spectra and theoretical study of dimethyl sulfate.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050501

Title: Telomerase limits the extent of base pairing between template RNA and telomeric DNA.

Journal: EMBO reports 20050401

Title: Structural aspects of RecA-dependent homologous strand exchange involving human telomeric DNA.

Journal: Biochemistry 20050329

Title: Use of 2-mercaptopyridine for the determination of alkylating agents in complex matrices: application to dimethyl sulfate.

Journal: Talanta 20050130

Title: The structure of a rigorously conserved RNA element within the SARS virus genome.

Journal: PLoS biology 20050101

Title: Toward multiplexing the application of solvent accessibility probes for the investigation of RNA three-dimensional structures by electrospray ionization-Fourier transform mass spectrometry.

Journal: Analytical biochemistry 20041115

Title: Upstream stimulatory factors, USF1 and USF2, bind to the human haem oxygenase-1 proximal promoter in vivo and regulate its transcription.

Journal: The Biochemical journal 20041015

Title: Gelsolin gene silencing involving unusual hypersensitivities to dimethylsulfate and KMnO4 in vivo footprinting on its promoter region.

Journal: International journal of cancer 20041010

Title: Interaction of telomestatin with the telomeric single-strand overhang.

Journal: The Journal of biological chemistry 20041001

Title: Architecture of a Diels-Alderase ribozyme with a preformed catalytic pocket.

Journal: Chemistry & biology 20040901

Title: Analysis in vitro and in vivo of the transcriptional regulator CrgA of Neisseria meningitidis upon contact with target cells.

Journal: Molecular microbiology 20040801

Title: Transient adenoviral N-methylpurine DNA glycosylase overexpression imparts chemotherapeutic sensitivity to human breast cancer cells.

Journal: Molecular cancer therapeutics 20040801

Title: DNA methylation, cell proliferation, and histopathology in rats following repeated inhalation exposure to dimethyl sulfate.

Journal: Inhalation toxicology 20040801

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Tags:77-78-1 Molecular Formula|77-78-1 MDL|77-78-1 SMILES|77-78-1 Sulfuric acid, dimethyl ester