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1207-12-1,MFCD00216264
Catalog No.:AA003KGZ

1207-12-1 | 4,6-Dimethyldibenzothiophene

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250mg
95%
in stock  
$11.00   $8.00
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1g
97%(GC)
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$29.00   $20.00
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5g
95%
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$44.00   $31.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003KGZ
Chemical Name:
4,6-Dimethyldibenzothiophene
CAS Number:
1207-12-1
Molecular Formula:
C14H12S
Molecular Weight:
212.3101
MDL Number:
MFCD00216264
SMILES:
Cc1cccc2c1sc1c2cccc1C
Properties
Properties
 
BP:
364.9°C at 760 mmHg  
Form:
Solid  
MP:
153-157 °C(lit.);  
Refractive Index:
1.6170 (estimate)  
Storage:
Keep in dry area;Room Temperature;  

Computed Properties
 
Complexity:
214  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
15  
Hydrogen Bond Acceptor Count:
1  
XLogP3:
5  

Upstream Synthesis Route

[1]JournalofCatalysis,2015,vol.330,p.330-343

[1]Tetrahedron,2013,vol.69,#1,p.207-211

[2]HelveticaChimicaActa,2006,vol.89,#8,p.1623-1640

[3]Tetrahedron,1996,vol.52,#27,p.9087-9092

[4]ActaChemicaScandinavica,1997,vol.51,#4,p.492-500

[1]JournalofCatalysis,2014,vol.317,p.144-152

[1]EuropeanJournalofOrganicChemistry,2015,vol.2015,#30,p.6602-6605

[1]Patent:WO2011/56941,2011,A1,.Locationinpatent:Page/Pagecolumn21-22

Downstream Synthesis Route

[1]ChemischeBerichte,1954,vol.87,p.1469,1475

[2]Tetrahedron,1997,vol.53,p.6073-6084

[1]Phosphorus,SulfurandSiliconandtheRelatedElements,1993,vol.79,p.113-122

[1]JournalofHeterocyclicChemistry,1983,vol.20,p.1485-1495

[1]JournalofHeterocyclicChemistry,1980,vol.17,p.771-773

[1]TetrahedronLetters,1998,vol.39,p.8987-8990

[2]JournalofOrganicChemistry,1992,vol.57,p.1986-1990

[3]JournalofCatalysis,2007,vol.250,p.283-293

[4]Tetrahedron,2013,vol.69,p.207-211

[5]ChemCatChem,2015,vol.7,p.3936-3944

[6]ChemCatChem,2016,vol.8,p.2565-2571

[7]Polyhedron,2019,vol.170,p.762-770

[8]PetroleumChemistry,2019,vol.59,p.1293-1299    Neftekhimiya,2019,vol.4,p.104-110,7

Literature

Title: Oxovanadium(IV)-catalysed oxidation of dibenzothiophene and 4,6-dimethyldibenzothiophene.

Journal: Dalton transactions (Cambridge, England : 2003) 20121207

Title: Highly efficient extraction and oxidative desulfurization system using Na7H2LaW10O36⋅32 H2O in [bmim]BF4 at room temperature.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120410

Title: Extraordinarily high activity in the hydrodesulfurization of 4,6-dimethyldibenzothiophene over Pd supported on mesoporous zeolite Y.

Journal: Journal of the American Chemical Society 20111005

Title: Oxidative desulfurization of fuels catalyzed by Fenton-like ionic liquids at room temperature.

Journal: ChemSusChem 20110321

Title: Enhancement in dibenzothiophene reactive adsorption from liquid fuel via incorporation of sulfur heteroatoms into the nanoporous carbon matrix.

Journal: ChemSusChem 20110117

Title: NiWO4 nanoparticles: a promising catalyst for hydrodesulfurization.

Journal: Chemical communications (Cambridge, England) 20101021

Title: Linker-directed vertex desymmetrization for the production of coordination polymers with high porosity.

Journal: Journal of the American Chemical Society 20101006

Title: Hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene over NiMo and CoMo sulfide catalysts: kinetic modeling approach for estimating selectivity.

Journal: Journal of colloid and interface science 20100801

Title: Effect of the incorporation of nitrogen to a carbon matrix on the selectivity and capacity for adsorption of dibenzothiophenes from model diesel fuel.

Journal: Langmuir : the ACS journal of surfaces and colloids 20100105

Title: Covalent anchoring of chloroperoxidase and glucose oxidase on the mesoporous molecular sieve SBA-15.

Journal: International journal of molecular sciences 20100101

Title: Sol gel-derived SBA-16 mesoporous material.

Journal: International journal of molecular sciences 20100101

Title: Enabling cleaner fuels: desulfurization by adsorption to microporous coordination polymers.

Journal: Journal of the American Chemical Society 20091014

Title: Interactions of 4,6-dimethyldibenzothiophene with the surface of activated carbons.

Journal: Langmuir : the ACS journal of surfaces and colloids 20090818

Title: Methoxylation pathway in biodesulfurization of model organosulfur compounds with Mycobacterium sp.

Journal: Bioresource technology 20090301

Title: Fragmentation pathways of some benzothiophene radical cations formed by atmospheric pressure chemical ionisation.

Journal: Rapid communications in mass spectrometry : RCM 20090301

Title: Determination of PASHs by various analytical techniques based on gas chromatography-mass spectrometry: application to a biodesulfurization process.

Journal: Talanta 20080615

Title: Liquid phase adsorption by microporous coordination polymers: removal of organosulfur compounds.

Journal: Journal of the American Chemical Society 20080604

Title: Desulfurization of various organic sulfur compounds and the mixture of DBT + 4,6-DMDBT by Mycobacterium sp. ZD-19.

Journal: Bioresource technology 20080601

Title: Laser photo-oxidative degradation of 4,6-dimethyldibenzothiophene.

Journal: Chemosphere 20080401

Title: Immobilization of chloroperoxidase on mesoporous materials for the oxidation of 4,6-dimethyldibenzothiophene, a recalcitrant organic sulfur compound present in petroleum fractions.

Journal: Biotechnology letters 20080101

Title: Hydrodesulfurization of 4,6-dimethyldibenzothiophene over noble metals supported on mesoporous zeolites.

Journal: Angewandte Chemie (International ed. in English) 20080101

Title: Selective adsorption of refractory sulfur species on active carbons and carbon based CoMo catalyst.

Journal: Journal of colloid and interface science 20070301

Title: Aqueous solubility data for pressurized hot water extraction for solid heterocyclic analogs of anthracene, phenanthrene and fluorene.

Journal: Journal of chromatography. A 20070126

Title: Liquid-phase adsorption of multi-ring thiophenic sulfur compounds on carbon materials with different surface properties.

Journal: The journal of physical chemistry. B 20060316

Title: Prediction of genotoxicity of chemical compounds by statistical learning methods.

Journal: Chemical research in toxicology 20050601

Title: Chloroperoxidase-catalyzed oxidation of 4,6-dimethyldibenzothiophene as dimer complexes: evidence for kinetic cooperativity.

Journal: Archives of biochemistry and biophysics 20050515

Title: Photooxidation of dibenzothiophene and 4,6-dimethyldibenzothiophene sensitized by N-methylquinolinium tetrafluoborate: mechanism and intermediates investigation.

Journal: The journal of physical chemistry. B 20050428

Title: A new type of nonsulfide hydrotreating catalyst: nickel phosphide on carbon.

Journal: Chemical communications (Cambridge, England) 20050307

Title: The effects of dimethylated and alkylated polycyclic aromatic hydrocarbons on the embryonic development of the Japanese medaka.

Journal: Ecotoxicology and environmental safety 20050301

Title: CpRu(CO)2(BF4) and [CpFe(CO)2(THF)]+ on mesoporous silica as adsorbents for the removal of dibenzothiophenes from hydrocarbon solutions.

Journal: Dalton transactions (Cambridge, England : 2003) 20040307

Title: Deep desulfurization by selective adsorption of dibenzothiophenes on Ag+/SBA-15 and Ag+/SiO2.

Journal: Chemical communications (Cambridge, England) 20031021

Title: Synthetic, structural and binding studies of the 4,6-dimethyldibenzothiophene complex [(eta(5)-C(5)Me(5))Ru(CO)(2)(eta(1)(S)-4,6-Me(2)DBT)]BF(4): toward an understanding of deep hydrodesulfurization.

Journal: Journal of the American Chemical Society 20030226

Title: Mass spectrometry of polyaromatic sulfur compounds in the presence of palladium(II).

Journal: Journal of mass spectrometry : JMS 20030201

Title: Sulfur-selective desulfurization of dibenzothiophene and diesel oil by newly isolated Rhodococcus sp. strains.

Journal: FEMS microbiology letters 20020924

Title: Oxorhenium(V) dithiolates catalyze the oxidation by tert-butyl hydroperoxide of sulfoxides and sulfides, including 4,6-dimethyldibenzothiophene.

Journal: Inorganic chemistry 20020311

Title: Estrogenic activities of chemicals in diesel exhaust particles.

Journal: Biological & pharmaceutical bulletin 20020101

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