Name: Name:D-tert-Leucine
Brand: AABLOCKS
SKU: AA003PTI
Rating: 90 (10 reviews)

Technical Information

Catalog Number: AA003PTI

Chemical Name: D-tert-Leucine

CAS Number: 26782-71-8

Molecular Formula: C6H13NO2

Molecular Weight: 131.1729

MDL Number: MFCD00004265

SMILES: N[C@H](C(C)(C)C)C(=O)O

Properties

Form: Solid

MP: ≥300 °C(lit.)

Refractive Index: 9 ° (C=3, H2O)

Storage: Inert atmosphere;Room Temperature;

Complexity: 115

Covalently-Bonded Unit Count: 1

Defined Atom Stereocenter Count: 1

Defined Bond Stereocenter Count: 0

Formal Charge: 0

Heavy Atom Count: 9

Hydrogen Bond Acceptor Count: 3

Hydrogen Bond Donor Count: 2

Isotope Atom Count: 0

Rotatable Bond Count: 2

Undefined Atom Stereocenter Count: 0

Undefined Bond Stereocenter Count: 0

XLogP3: -1.8

Literature fold

Title: Asymmetric construction of spirocyclohexanonerhodanines catalyzed by simple diamine derived from chiral tert-leucine.

Journal: Chemical communications (Cambridge, England)20120921

Title: Chiral recognition of α-amino acids by an optically active (2S,5S,8S,11S)-2,5,8,11-tetraethyl cyclen cobalt(III) complex.

Journal: Inorganic chemistry20110103

Title: Total synthesis of the large non-ribosomal peptide polytheonamide B.

Journal: Nature chemistry20100401

Title: Scaleable catalytic asymmetric Strecker syntheses of unnatural alpha-amino acids.

Journal: Nature20091015

Title: The tert-butyl group in chemistry and biology.

Journal: Organic & biomolecular chemistry20080807

Title: Effect of organic cosolvent on kinetic resolution of tert-leucine by penicillin G acylase from Kluyvera citrophila.

Journal: Bioprocess and biosystems engineering20060401

Title: Preparation of optically pure tert-leucine by penicillin G acylase-catalyzed resolution.

Journal: Preparative biochemistry & biotechnology20060101

Title: Preferred conformations of peptides containing tert-leucine, a sterically demanding, lipophilic alpha-amino acid with a quaternary side-chain Cbeta atom.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany)20050408

Title: Highly selective asymmetric acetate aldol reactions of an N-acetyl thiazolidinethione reagent.

Journal: Organic letters20040108

Title: An efficient and selective enzymatic oxidation system for the synthesis of enantiomerically pure D-tert-leucine.

Journal: Organic letters20031002

Title: Enzyme-assisted preparation of D-tert.-leucine.

Journal: Bioscience, biotechnology, and biochemistry20010901

26782-71-8 | D-tert-Leucine