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55739-58-7,MFCD06659020
Catalog No.:AA00I9V5

55739-58-7 | (R,R)-Dipamp

Pack Size
Purity
Availability
Price(USD)
Quantity
  
25mg
≥ 98% (31P NMR)
in stock  
$115.00   $80.00
- +
100mg
97%
in stock  
$172.00   $120.00
- +
250mg
97%
in stock  
$315.00   $220.00
- +
1g
97%
in stock  
$979.00   $685.00
- +
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA00I9V5
Chemical Name:
(R,R)-Dipamp
CAS Number:
55739-58-7
Molecular Formula:
C28H28O2P2
Molecular Weight:
458.4682
MDL Number:
MFCD06659020
SMILES:
COc1ccccc1P(c1ccccc1)CCP(c1ccccc1OC)c1ccccc1
Properties
Computed Properties
 
Complexity:
472  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
2  
Heavy Atom Count:
32  
Hydrogen Bond Acceptor Count:
2  
Rotatable Bond Count:
9  
XLogP3:
5.8  

Downstream Synthesis Route
(S,S)-1,1'-(1,2-ethanediyl)bis1-(2-methoxyphenyl)-1-phenylphosphineoxide 
 
(RP,RP)-1,2-bis(o-anisyl)(phenyl)phosphinoethane 
  97858-62-3 

[1]Petit,Christelle;Poli,Evelyne;Favre-Reguillon,Alain;Khrouz,Lhoussain;Denis-Quanquin,Sandrine;Bonneviot,Laurent;Mignani,Gerard;Lemaire,Marc[ACSCatalysis,2013,vol.3,#7,p.1431-1438]

Literature

Title: Investigations into the formation and stability of cationic rhodium diphosphane η6-arene complexes.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20120917

Title: Profiling the tuneable R-SMS-Phos structure in the rhodium(I)-catalyzed hydrogenation of olefins: the last stand?

Journal: Organic & biomolecular chemistry 20110721

Title: Trinuclear rhodium complexes and their relevance for asymmetric hydrogenation.

Journal: Chemistry, an Asian journal 20081113

Title: Synthesis, characterization and reactivity of tetranuclear ruthenium hydrido clusters containing chiral phosphine ligands.

Journal: Dalton transactions (Cambridge, England : 2003) 20060107

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SDS
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