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1068-21-9,MFCD00015676
Catalog No.:AA003PED

1068-21-9 | Diethyl phosphoramidate

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Purity
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1g
96%
in stock  
$29.00   $20.00
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5g
>98.0%(GC)
in stock  
$45.00   $32.00
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25g
>98.0%(GC)
in stock  
$148.00   $104.00
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  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA003PED
Chemical Name:
Diethyl phosphoramidate
CAS Number:
1068-21-9
Molecular Formula:
C4H12NO3P
Molecular Weight:
153.1167
MDL Number:
MFCD00015676
SMILES:
CCOP(=O)(OCC)N
NSC Number:
56755
Properties
Properties
 
BP:
140 °C3 mm Hg(lit.)  
Form:
Solid  
MP:
51-53 °C(lit.)  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
106  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
4  
XLogP3:
-0.5  

Downstream Synthesis Route

[1]Grison,Claude;Coutrot,Philippe;Comoy,Corinne;Balas,Laurence;Joliez,Stephane;Lavecchia,Guido;Oliger,Patrick;Penverne,Bernadette;Serre,Valerie;Herve,Guy[EuropeanJournalofMedicinalChemistry,2004,vol.39,#4,p.333-344]

[2]Goehring;Niedenzu[ChemischeBerichte,1956,vol.89,p.1768,1770]

[3]Saundersetal.[JournaloftheChemicalSociety,1948,p.702]

[4]Eiden;Schoenduve[ArchivderPharmazie,1972,vol.305,#7,p.477-485]Cadogan,J.I.G.;Foster,W.R.[JournaloftheChemicalSociety,1961,p.3076-3079]Cadogan,J.I.G.etal.[JournaloftheChemicalSocietyC:Organic,1967,p.1356-1360]

[1]Mielniczak,Grazyna;Lopusinski,Andrzej[SyntheticCommunications,2003,vol.33,#22,p.3851-3859]

[2]Malowan[InorganicSyntheses,1953,vol.4,p.77]Atherton;Openshaw;Todd[JournaloftheChemicalSociety,1945,p.660,662]

[3]Zwierzak,A.;Koziara,A.[Tetrahedron,1970,vol.26,p.3521-3525]

[4]Zhang;Flann[JournalofOrganicChemistry,1998,vol.63,#5,p.1372-1378]

[1]Zwierzak,Andrzej;Pilichowska,Slawomira[Synthesis,1982,#11,p.922-924]

[2]Samarai,L.I.etal.[JournalofgeneralchemistryoftheUSSR,1969,vol.39,p.1480-1482][ZhurnalObshcheiKhimii,1969,vol.39,p.1511-1513]

[3]Ariga,ElaineMiho;CaritaCorrera,Thiago;Matsushima,JullyaneEmi;McIndoe,J.Scott;MoreiraRibeiro,FranciscoWanderson;Omari,Isaac;PapaSpadafora,Bruna;Rodrigues,Alessandro;Soares,PriscilaMachadoArruda;Vinhato,Elisângela;deOliveira-Silva,Diogo[OrganicandBiomolecularChemistry,2021,vol.19,#25,p.5595-5606]

[1]ArchivderPharmazie,1972,vol.305,p.477-485

[2]TetrahedronLetters,1967,p.2119-2121

[1]Zlotin,S.G.;Sharashkina,M.V.;Strelenko,Yu.A.;Luk'yanov,O.A.[Bull.Russ.Acad.Sci.Div.Chem.Sci.(Engl.Transl.),1992,vol.41,#5.2,p.902-913][IzvestiyaAkademiNauk,SeriyaKhimicheskaya,1992,#5,p.1148-1161]

[2]Zawadzki,S.;Zwierzak,A.[Tetrahedron,1973,vol.29,p.315-320]

[3]Zwierzak,A.;Zawadzki,S.[Synthesis,1971,p.323-325]

[4]Pinchuk,A.M.etal.[JournalofgeneralchemistryoftheUSSR,1969,vol.39,p.2094][ZhurnalObshcheiKhimii,1969,vol.39,p.2142-2143]

[5]Osowska-Pacewicka,K.;Zwierzak,A.[Tetrahedron,1985,vol.41,#20,p.4717-4726]

Literature

Title: Highly diastereo- and enantioselective synthesis of α-alkyl norstatine derivatives: catalytic asymmetric Mannich reactions of 5H-oxazol-4-ones.

Journal: Angewandte Chemie (International ed. in English) 20120723

Title: Single-particle aerosol mass spectrometry for the detection and identification of chemical warfare agent simulants.

Journal: Analytical chemistry 20070815

Title: Efficient synthesis of a chiral [4]pseudocatenane and its derivatives: a novel ship's wheel-like interlocked structure.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20060717

Title: Visible light photocatalysis with platinized rutile TiO2 for aqueous organic oxidation.

Journal: Langmuir : the ACS journal of surfaces and colloids 20051122

Title: Visible light Cr(VI) reduction and organic chemical oxidation by TiO2 photocatalysis.

Journal: Environmental science & technology 20050815

Title: Secondary ionization of chemical warfare agent simulants: atmospheric pressure ion mobility time-of-flight mass spectrometry.

Journal: Analytical chemistry 20031115

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