Home Other Building Blocks 112068-01-6
112068-01-6,MFCD00075506
Catalog No.:AA003CB8

112068-01-6 | (S)-1,1-Diphenylprolinol

Pack Size
Purity
Availability
Price(USD)
Quantity
  
1g
98%(GC)
in stock  
$24.00   $17.00
- +
5g
98%(GC)
in stock  
$27.00   $19.00
- +
25g
98%
in stock  
$45.00   $32.00
- +
100g
98%
in stock  
$112.00   $78.00
- +
500g
98%
in stock  
$411.00   $288.00
- +
  • Technical Information
  • Properties
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA003CB8
Chemical Name:
(S)-1,1-Diphenylprolinol
CAS Number:
112068-01-6
Molecular Formula:
C17H19NO
Molecular Weight:
253.3389
MDL Number:
MFCD00075506
SMILES:
OC(c1ccccc1)(c1ccccc1)[C@@H]1CCCN1
Properties
Properties
 
BP:
396.54°C (rough estimate)  
Form:
Solid  
MP:
77-80 °C  
Refractive Index:
-66.5 ° (C=3, CHCl3)  
Solubility:
Soluble in chloroform.  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
261  
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
1  
Heavy Atom Count:
19  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
2  
Rotatable Bond Count:
3  
XLogP3:
2.7  

Literature

Title: 2-DPMP (desoxypipradrol, 2-benzhydrylpiperidine, 2-phenylmethylpiperidine) and D2PM (diphenyl-2-pyrrolidin-2-yl-methanol, diphenylprolinol): A preliminary review.

Journal: Progress in neuro-psychopharmacology & biological psychiatry 20121203

Title: Use and acute toxicity associated with the novel psychoactive substances diphenylprolinol (D2PM) and desoxypipradrol (2-DPMP).

Journal: Clinical toxicology (Philadelphia, Pa.) 20120901

Title: 'Legal highs'--novel and emerging psychoactive drugs: a chemical overview for the toxicologist.

Journal: Clinical toxicology (Philadelphia, Pa.) 20120101

Title: Clinical toxicology of newer recreational drugs.

Journal: Clinical toxicology (Philadelphia, Pa.) 20111001

Title: Formation and stability of prolinol and prolinol ether enamines by NMR: delicate selectivity and reactivity balances and parasitic equilibria.

Journal: Journal of the American Chemical Society 20110511

Title: Organocatalytic approach to polysubstituted piperidines and tetrahydropyrans.

Journal: Organic letters 20110401

Title: Recreational drugs, 3,4-Methylenedioxymethamphetamine(MDMA), 3,4-methylenedioxyamphetamine (MDA) and diphenylprolinol, inhibit neurite outgrowth in PC12 cells.

Journal: The Journal of toxicological sciences 20100601

Title: Direct oxidation of beta-aryl substituted aldehydes to alpha,beta-unsaturated aldehydes promoted by an o-anisidine-Pd(OAc)2 co-catalyst.

Journal: Chemistry, an Asian journal 20091102

Title: Spiroborate ester-mediated asymmetric synthesis of beta-hydroxy ethers and its conversion to highly enantiopure beta-amino ethers.

Journal: The Journal of organic chemistry 20090605

Title: Catalytic asymmetric oxa-Michael-Michael cascade for facile construction of chiral chromans via an aminal intermediate.

Journal: Organic letters 20090402

Title: Highly enantio- and diastereoselective organocatalytic cascade aza-Michael-Michael reactions: a direct method for the synthesis of trisubstituted chiral pyrrolidines.

Journal: Chemical communications (Cambridge, England) 20081121

Title: Cardiovascular toxicity associated with recreational use of diphenylprolinol (diphenyl-2-pyrrolidinemethanol [D2PM]).

Journal: Journal of medical toxicology : official journal of the American College of Medical Toxicology 20080901

Title: Synthesis of a new C(2)-symmetric chiral catalyst and its application in the catalytic asymmetric borane reduction of prochiral ketones.

Journal: Chirality 20080201

Title: Organocatalytic enantioselective cascade Michael-alkylation reactions: synthesis of chiral cyclopropanes and investigation of unexpected organocatalyzed stereoselective ring opening of cyclopropanes.

Journal: Journal of the American Chemical Society 20070905

Title: Enantioselective organocatalytic double Michael addition reactions.

Journal: Organic letters 20070426

Title: Chiral Diphenylprolinol TES ether promoted conjugate addition-aldol-dehydration reactions between alpha,beta-unsaturated aldehydes and 2-N-protected amino benzaldehydes.

Journal: Organic letters 20070315

Title: Chiral diphosphites and diphosphoramidites as cheap and efficient ligands in Rh-catalyzed asymmetric olefin hydrogenation.

Journal: Chemical communications (Cambridge, England) 20060604

Title: Enantioselective addition of diethylzinc to aldehydes catalyzed by optically active C2-symmetrical bis-beta-amino alcohols.

Journal: Chirality 20021001

Quotation Request
Company Name:
*
Contact Person:
*
Email:
*
Quantity Required:
*
Country:
Additional Info:
SDS
Tags:112068-01-6 Molecular Formula|112068-01-6 MDL|112068-01-6 SMILES|112068-01-6 (S)-1,1-Diphenylprolinol